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Laurence Hardwick

Professor Laurence Hardwick

Director of the Stephenson Institute for Renewable Energy
Chemistry

Publications

Selected publications

  1. Oxygen reactions on Pt{hkl} in a non-aqueous Na+ electrolyte: site selective stabilisation of a sodium peroxy species (Journal article - 2019)
  2. Mechanistic Insight into the Superoxide Induced Ring Opening in Propylene Carbonate Based Electrolytes using in Situ Surface-Enhanced Infrared Spectroscopy (Journal article - 2016)
  3. Solvent‐Mediated Control of the Electrochemical Discharge Products of Non‐Aqueous Sodium–Oxygen Electrochemistry (Journal article - 2016)
  4. Utilizing in Situ Electrochemical SHINERS for Oxygen Reduction Reaction Studies in Aprotic Electrolytes (Journal article - 2016)
  5. Three-dimensional Protonic Conductivity in Porous Organic Cage Solids (Journal article - 2016)
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2025

2024

Single Versus Blended Electrolyte Additives: Impact of a Sulfur‐Based Electrolyte Additive on Electrode Cross‐Talk and Electrochemical Performance of LiNiO<sub>2</sub>||Graphite Cells

Wölke, C., Benayad, A., Lai, T., Hanke, F., Baraldi, G., Echeverría, M., . . . Cekic‐Laskovic, I. (n.d.). Single Versus Blended Electrolyte Additives: Impact of a Sulfur‐Based Electrolyte Additive on Electrode Cross‐Talk and Electrochemical Performance of LiNiO<sub>2</sub>||Graphite Cells. Advanced Energy Materials. doi:10.1002/aenm.202402152

DOI
10.1002/aenm.202402152
Journal article

Understanding the electrochemical behaviour of reduced graphene oxide cathodes in all-carbon Na-ion batteries

Orzech, M. W., Mazzali, F., Adomkevicius, A., Coduri, M., Niu, Y., McGettrick, J. D., . . . Margadonna, S. (n.d.). Understanding the electrochemical behaviour of reduced graphene oxide cathodes in all-carbon Na-ion batteries. Materials Advances, 5(20), 8132-8144. doi:10.1039/d4ma00605d

DOI
10.1039/d4ma00605d
Journal article

Effect of alkali-metal cation on oxygen adsorption at Pt single-crystal electrodes in non-aqueous electrolytes

Fernandez-Vidal, J., Hardwick, L. J., Cabello, G., & Attard, G. A. (2023). Effect of alkali-metal cation on oxygen adsorption at Pt single-crystal electrodes in non-aqueous electrolytes. FARADAY DISCUSSIONS. doi:10.1039/d3fd00084

DOI
10.1039/d3fd00084
Journal article

Materials for stable metal-oxygen battery cathodes: general discussion.

Attard, G. A., Calvo, E. J., Curtiss, L. A., Dewar, D., Ellison, J. H. J., Gao, X., . . . Ye, S. (2024). Materials for stable metal-oxygen battery cathodes: general discussion.. Faraday discussions, 248(0), 75-88. doi:10.1039/d3fd90059b

DOI
10.1039/d3fd90059b
Journal article

Mechanism of ORR and OER in non-aqueous electrolytes: general discussion.

Attard, G. A., Bruce, P. G., Calvo, E. J., Chen, Y., Curtiss, L. A., Dewar, D., . . . Ye, S. (2024). Mechanism of ORR and OER in non-aqueous electrolytes: general discussion.. Faraday discussions, 248(0), 210-249. doi:10.1039/d3fd90060f

DOI
10.1039/d3fd90060f
Journal article

Metal anodes and protected interfaces: general discussion.

Gao, X., Grey, C. P., Hardwick, L. J., Horwitz, G., Johnson, L. R., Matsuda, S., . . . Wu, Y. (2024). Metal anodes and protected interfaces: general discussion.. Faraday discussions, 248(0), 298-304. doi:10.1039/d3fd90061d

DOI
10.1039/d3fd90061d
Journal article

Towards practical metal-oxygen batteries: general discussion.

Archer, L. A., Bruce, P. G., Calvo, E. J., Dewar, D., Ellison, J. H. J., Freunberger, S. A., . . . Ye, S. (2024). Towards practical metal-oxygen batteries: general discussion.. Faraday discussions, 248(0), 392-411. doi:10.1039/d3fd90062b

DOI
10.1039/d3fd90062b
Journal article

2023

Shell-isolated nanoparticle-enhanced Raman spectroscopy

Zhang, Y. -J., Ze, H., Fang, P. -P., Huang, Y. -F., Kudelski, A., Fernandez-Vidal, J., . . . Li, J. -F. (2023). Shell-isolated nanoparticle-enhanced Raman spectroscopy. NATURE REVIEWS METHODS PRIMERS, 3(1). doi:10.1038/s43586-023-00217-y

DOI
10.1038/s43586-023-00217-y
Journal article

2022

Band Alignments, Electronic Structure, and Core-Level Spectra of Bulk Molybdenum Dichalcogenides (MoS2, MoSe2, and MoTe2)

Jones, L., Xing, Z., Swallow, J., Shiel, H., Featherstone, T., Smiles, M., . . . Dhanak, V. (2022). Band Alignments, Electronic Structure, and Core-Level Spectra of Bulk Molybdenum Dichalcogenides (MoS2, MoSe2, and MoTe2). The Journal of Physical Chemistry C: Energy Conversion and Storage, Optical and Electronic Devices, Interfaces, Nanomaterials, and Hard Matter. doi:10.1021/acs.jpcc.2c05100

DOI
10.1021/acs.jpcc.2c05100
Journal article

Corrosion suppression of aluminium current collectors within Li-ion cells using 3-methoxypropionitrile-based electrolytes

Yen, C. -H., Neale, A. R., Lim, J., Bresser, D., Hardwick, L. J., & Hu, C. -C. (2022). Corrosion suppression of aluminium current collectors within Li-ion cells using 3-methoxypropionitrile-based electrolytes. ELECTROCHIMICA ACTA, 431. doi:10.1016/j.electacta.2022.141105

DOI
10.1016/j.electacta.2022.141105
Journal article

Fluorine-Rich Oxyfluoride Spinel Li1.25Ni0.625Mn1.125O3F Utilizing Redox-Active Ni and Mn for High Capacity and Improved Cyclability

DOI
10.26434/chemrxiv-2022-8f3fk
Preprint

Gas Evolution from Sulfide-Based All-Solid-State Batteries

Lim, J., Powell, R., & Hardwick, L. J. (2022). Gas Evolution from Sulfide-Based All-Solid-State Batteries. ECS Meeting Abstracts, MA2022-01(2), 231. doi:10.1149/ma2022-012231mtgabs

DOI
10.1149/ma2022-012231mtgabs
Journal article

Multi-Functional Polyimide Separators for Electrochemical Capacitor and Lithium-Ion Cell Applications

Pai, J. -Y., Hardwick, L. J., & Hu, C. -C. (2022). Multi-Functional Polyimide Separators for Electrochemical Capacitor and Lithium-Ion Cell Applications. ECS Meeting Abstracts, MA2022-01(4), 550. doi:10.1149/ma2022-014550mtgabs

DOI
10.1149/ma2022-014550mtgabs
Journal article

Operando Surface Enhanced Infrared Spectroscopic Investigations of Interfacial Restructuring and Oxygen Electrochemistry in Ionic Liquid Electrolytes for Metal-Air Batteries

Walters, L. J., Neale, A. R., Nichols, R. J., & Hardwick, L. J. (2022). Operando Surface Enhanced Infrared Spectroscopic Investigations of Interfacial Restructuring and Oxygen Electrochemistry in Ionic Liquid Electrolytes for Metal-Air Batteries. ECS Meeting Abstracts, MA2022-01(4), 569. doi:10.1149/ma2022-014569mtgabs

DOI
10.1149/ma2022-014569mtgabs
Journal article

Operando electrochemical Kerr Gated Raman Spectroscopy to Probe the High States of Charge in Graphite Electrodes for Li-Ion Batteries

Neale, A. R., Milan, D. C., Braga, F., Sazanovich, I., & Hardwick, L. J. (2022). Operando electrochemical Kerr Gated Raman Spectroscopy to Probe the High States of Charge in Graphite Electrodes for Li-Ion Batteries. In ECS Meeting Abstracts Vol. MA2022-01 (pp. 2475). The Electrochemical Society. doi:10.1149/ma2022-0162475mtgabs

DOI
10.1149/ma2022-0162475mtgabs
Conference Paper

Stable Formulations for the Lithium and Sodium Metal Interfaces in Alkali Metal-Oxygen Batteries

Neale, A. R., & Hardwick, L. J. (2022). Stable Formulations for the Lithium and Sodium Metal Interfaces in Alkali Metal-Oxygen Batteries. In ECS Meeting Abstracts Vol. MA2022-01 (pp. 496). The Electrochemical Society. doi:10.1149/ma2022-013496mtgabs

DOI
10.1149/ma2022-013496mtgabs
Conference Paper

2021

Ordered Oxygen Vacancies in the Lithium-Rich Oxide Li<sub>4</sub>CuSbO<sub>5.5</sub>, a Triclinic Structure Type Derived from the Cubic Rocksalt Structure

Perez, A. J., Vasylenko, A., Surta, T. W., Niu, H., Daniels, L. M., Hardwick, L. J., . . . Rosseinsky, M. J. (2021). Ordered Oxygen Vacancies in the Lithium-Rich Oxide Li<sub>4</sub>CuSbO<sub>5.5</sub>, a Triclinic Structure Type Derived from the Cubic Rocksalt Structure. INORGANIC CHEMISTRY, 60(24), 19022-19034. doi:10.1021/acs.inorgchem.1c02882

DOI
10.1021/acs.inorgchem.1c02882
Journal article

Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability

Han, G., Vasylenko, A., Neale, A. R., Duff, B. B., Chen, R., Dyer, M. S., . . . Rosseinsky, M. J. (2021). Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(43), 18216-18232. doi:10.1021/jacs.1c07874

DOI
10.1021/jacs.1c07874
Journal article

Design Parameters for Ionic Liquid-Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li-O<sub>2</sub> Batteries

Neale, A. R., Sharpe, R., Yeandel, S. R., Yen, C. -H., Luzyanin, K. V., Goddard, P., . . . Hardwick, L. J. (2021). Design Parameters for Ionic Liquid-Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li-O<sub>2</sub> Batteries. ADVANCED FUNCTIONAL MATERIALS, 31(27). doi:10.1002/adfm.202010627

DOI
10.1002/adfm.202010627
Journal article

2020

(Invited) Design of Electrospun Polyimide-Based Separators for Electrical Double-Layer Capacitors and Lithium-Ion Batteries

Hu, C. -C., Pai, J. -Y., & Hardwick, L. J. (2020). (Invited) Design of Electrospun Polyimide-Based Separators for Electrical Double-Layer Capacitors and Lithium-Ion Batteries. ECS Meeting Abstracts, MA2020-02(3), 604. doi:10.1149/ma2020-023604mtgabs

DOI
10.1149/ma2020-023604mtgabs
Journal article

Observation of Interfacial Degradation of Solid Electrolytes Against Lithium Metal and Layered Transition Metal Oxides Via in Situ Electrochemical Raman Microscopy

Zhou, Y., & Hardwick, L. J. (2020). Observation of Interfacial Degradation of Solid Electrolytes Against Lithium Metal and Layered Transition Metal Oxides Via in Situ Electrochemical Raman Microscopy. ECS Meeting Abstracts, MA2020-02(5), 889. doi:10.1149/ma2020-025889mtgabs

DOI
10.1149/ma2020-025889mtgabs
Journal article

Sn 5 s 2 lone pairs and the electronic structure of tin sulphides: A photoreflectance, high-energy photoemission, and theoretical investigation

Jones, L., Linhart, W., Fleck, N., Swallow, J., Murgatroyd, P., Shiel, H., . . . Dhanak, V. (n.d.). Sn 5s2 lone pairs and the electronic structure of tin sulphides: A photoreflectance, high-energy photoemission, and theoretical investigation. Physical Review Materials, 4. doi:10.1103/PhysRevMaterials.4.074602

DOI
10.1103/PhysRevMaterials.4.074602
Journal article

(Invited) Kerr Gated Raman Spectroscopy to Investigate Aging Processes on Lithium-Ion Electrode Interfaces

Hardwick, L. J., Cabo-Fernandez, L., Neale, A. R., Braga, F., Kostecki, R., & Sazanovich, I. (2020). (Invited) Kerr Gated Raman Spectroscopy to Investigate Aging Processes on Lithium-Ion Electrode Interfaces. In ECS Meeting Abstracts Vol. MA2020-01 (pp. 190). The Electrochemical Society. doi:10.1149/ma2020-012190mtgabs

DOI
10.1149/ma2020-012190mtgabs
Conference Paper

Achieving Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries: Optimizing Solvation Environment in Ionic Liquid/Solvent Blend Formulations

Neale, A. R., Sharpe, R., Yeandel, S., Luzyanin, K., Iggo, J. A., Goddard, P., . . . Hardwick, L. J. (2020). Achieving Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries: Optimizing Solvation Environment in Ionic Liquid/Solvent Blend Formulations. In ECS Meeting Abstracts Vol. MA2020-01 (pp. 441). The Electrochemical Society. doi:10.1149/ma2020-012441mtgabs

DOI
10.1149/ma2020-012441mtgabs
Conference Paper

Quantitative Resolution of Complex Stoichiometric Changes during Electrochemical Cycling by Density Functional Theory-Assisted Electrochemical Quartz Crystal Microbalance

Wu, T. -H., Scivetti, I., Chen, J. -C., Wang, J. -A., Teobaldi, G., Hu, C. -C., & Hardwick, L. J. (n.d.). Quantitative Resolution of Complex Stoichiometric Changes during Electrochemical Cycling by Density Functional Theory-Assisted Electrochemical Quartz Crystal Microbalance. ACS Applied Energy Materials. doi:10.1021/acsaem.9b02386

DOI
10.1021/acsaem.9b02386
Journal article

2019

Enhanced oxygen evolution performance of spinel Fe<sub>0.1</sub>Ni<sub>0.9</sub>Co<sub>2</sub>O<sub>4</sub>/Activated carbon composites

Lu, Y. -T., Wu, J., Lin, Z. -X., You, T. -H., Lin, S. -C., Chen, H. -Y. T., . . . Hu, C. -C. (2019). Enhanced oxygen evolution performance of spinel Fe<sub>0.1</sub>Ni<sub>0.9</sub>Co<sub>2</sub>O<sub>4</sub>/Activated carbon composites. ELECTROCHIMICA ACTA, 326. doi:10.1016/j.electacta.2019.134986

DOI
10.1016/j.electacta.2019.134986
Journal article

Intercalation behaviour of Li and Na into 3-layer and multilayer MoS2 flakes

Zou, J., Li, F., Bissett, M. A., Kim, F., & Hardwick, L. J. (2019). Intercalation behaviour of Li and Na into 3-layer and multilayer MoS2 flakes. Electrochimica Acta, 135284. doi:10.1016/j.electacta.2019.135284

DOI
10.1016/j.electacta.2019.135284
Journal article

Kerr gated Raman spectroscopy of LiPF<sub>6</sub> salt and LiPF<sub>6</sub>-based organic carbonate electrolyte for Li-ion batteries

Cabo-Fernandez, L., Neale, A. R., Braga, F., Sazanovich, I. V., Kostecki, R., & Hardwick, L. J. (2019). Kerr gated Raman spectroscopy of LiPF<sub>6</sub> salt and LiPF<sub>6</sub>-based organic carbonate electrolyte for Li-ion batteries. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 21(43), 23833-23842. doi:10.1039/c9cp02430a

DOI
10.1039/c9cp02430a
Journal article

Exploring Ionic Liquid-Solvent Blend Formulations for the Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries

Neale, A. R., Sharpe, R., Yeandel, S., Goddard, P., Petrucco, E., & Hardwick, L. J. (2019). Exploring Ionic Liquid-Solvent Blend Formulations for the Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries. In ECS Meeting Abstracts Vol. MA2019-02 (pp. 521). The Electrochemical Society. doi:10.1149/ma2019-02/6/521

DOI
10.1149/ma2019-02/6/521
Conference Paper

Oxygen Reduction at Pt{Hkl} Electrodes in an Alkali Metal Ion Containing Aprotic Solvent

Hardwick, L. J., Galloway, T., Attard, G., Li, J. -F., & Dong, J. -C. (2019). Oxygen Reduction at Pt{Hkl} Electrodes in an Alkali Metal Ion Containing Aprotic Solvent. ECS Meeting Abstracts, MA2019-04(2), 109. doi:10.1149/ma2019-04/2/109

DOI
10.1149/ma2019-04/2/109
Journal article

Advanced Spectroelectrochemical Techniques to Study Electrode InterfacesWithin Lithium-Ion and Lithium-Oxygen Batteries

Cowan, A. J., & Hardwick, L. J. (2019). Advanced Spectroelectrochemical Techniques to Study Electrode InterfacesWithin Lithium-Ion and Lithium-Oxygen Batteries. ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 12, 12, 323-346. doi:10.1146/annurev-anchem-061318-115303

DOI
10.1146/annurev-anchem-061318-115303
Journal article

Stabilization of O-O Bonds by d(0) Cations in Li4+xNi1-xWO6 (0 <= x <= 0.25) Rock Salt Oxides as the Origin of Large Voltage Hysteresis

Taylor, Z. N., Perez, A. J., Coca-Clemente, J. A., Braga, F., Drewett, N. E., Pitcher, M. J., . . . Rosseinsky, M. J. (2019). Stabilization of O-O Bonds by d(0) Cations in Li4+xNi1-xWO6 (0 <= x <= 0.25) Rock Salt Oxides as the Origin of Large Voltage Hysteresis. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 141(18), 7333-7346. doi:10.1021/jacs.8b13633

DOI
10.1021/jacs.8b13633
Journal article

Anionic Redox in Li-Rich Rocksalt Oxides Studied Via X-Ray Photoelectron Spectroscopy

Coca Clemente, J. A., Hardwick, L. J., & Dhanak, V. R. (2019). Anionic Redox in Li-Rich Rocksalt Oxides Studied Via X-Ray Photoelectron Spectroscopy. ECS Meeting Abstracts, MA2019-01(4), 481. doi:10.1149/ma2019-01/4/481

DOI
10.1149/ma2019-01/4/481
Journal article

Binder Degradation in Sodium- and Potassium-Oxygen Batteries

Braga, F., & Hardwick, L. J. (2019). Binder Degradation in Sodium- and Potassium-Oxygen Batteries. ECS Meeting Abstracts, MA2019-01(2), 119. doi:10.1149/ma2019-01/2/119

DOI
10.1149/ma2019-01/2/119
Journal article

Kerr Gated Raman Spectroscopy to Investigate Lithium-Ion Battery Interfaces

Hardwick, L. J., Cabo-Fernandez, L., Kostecki, R., & Sazanovich, I. (2019). Kerr Gated Raman Spectroscopy to Investigate Lithium-Ion Battery Interfaces. ECS Meeting Abstracts, MA2019-01(5), 524. doi:10.1149/ma2019-01/5/524

DOI
10.1149/ma2019-01/5/524
Journal article

In-Situ Electrochemical SHINERS Investigation of SEI Composition on Carbon-Coated Zn<sub>0.9</sub>Fe<sub>0.1</sub>O Anode for Lithium-Ion Batteries

Cabo-Fernandez, L., Bresser, D., Braga, F., Passerini, S., & Hardwick, L. J. (2019). In-Situ Electrochemical SHINERS Investigation of SEI Composition on Carbon-Coated Zn<sub>0.9</sub>Fe<sub>0.1</sub>O Anode for Lithium-Ion Batteries. BATTERIES & SUPERCAPS, 2(2), 168-177. doi:10.1002/batt.201800063

DOI
10.1002/batt.201800063
Journal article

2018

Lithium Transport in Li<sub>4.4</sub><i>M</i><sub>0.4</sub><i>M</i>′<sub>0.6</sub>S<sub>4</sub> (M = Al<SUP>3+</SUP>, Ga<SUP>3+</SUP>, and <i>M</i>′ = Ge<SUP>4+</SUP>, Sn<SUP>4+</SUP>): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies

Leube, B. T., Inglis, K. K., Carrington, E. J., Sharp, P. M., Shin, J. F., Neale, A. R., . . . Rosseinsky, M. J. (2018). Lithium Transport in Li<sub>4.4</sub><i>M</i><sub>0.4</sub><i>M</i>′<sub>0.6</sub>S<sub>4</sub> (M = Al<SUP>3+</SUP>, Ga<SUP>3+</SUP>, and <i>M</i>′ = Ge<SUP>4+</SUP>, Sn<SUP>4+</SUP>): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies. CHEMISTRY OF MATERIALS, 30(20), 7183-7200. doi:10.1021/acs.chemmater.8b03175

DOI
10.1021/acs.chemmater.8b03175
Journal article

(Invited) Oxygen Reactions at Poly and Single Crystalline Electrodes in a Sodium-Ion Containing Aprotic Solvent

Hardwick, L. J., Nichols, R., Attard, G., Galloway, T., Berry, N., Padmanabhan, V., . . . Dong, J. -C. (2018). (Invited) Oxygen Reactions at Poly and Single Crystalline Electrodes in a Sodium-Ion Containing Aprotic Solvent. ECS Meeting Abstracts, MA2018-01(37), 2182. doi:10.1149/ma2018-01/37/2182

DOI
10.1149/ma2018-01/37/2182
Journal article

Electrochemistry: general discussion

Abbott, A., Aldous, L., Borisenko, N., Coles, S., Fontaine, O., Garcia, J. D. G., . . . Wishart, J. (2018). Electrochemistry: general discussion. FARADAY DISCUSSIONS, 206, 405-426. doi:10.1039/C7FD90093G

DOI
10.1039/C7FD90093G
Journal article

2017

Analytical SERS: general discussion

Aitchison, H., Aizpurua, J., Arnolds, H., Baumberg, J., Bell, S., Bonifacio, A., . . . Vikesland, P. (2017). Analytical SERS: general discussion. FARADAY DISCUSSIONS, 205, 561-600. doi:10.1039/C7FD90096A

DOI
10.1039/C7FD90096A
Journal article

Structure and dynamics of ionic liquids: general discussion

Addicoat, M., Atkin, R., Lopes, J. N. C., Gomes, M. C., Firestone, M., Gardas, R., . . . Wishart, J. (2017). Structure and dynamics of ionic liquids: general discussion. FARADAY DISCUSSIONS, 206, 291-337. doi:10.1039/C7FD90092A

DOI
10.1039/C7FD90092A
Journal article

2016

Solvent‐Mediated Control of the Electrochemical Discharge Products of Non‐Aqueous Sodium–Oxygen Electrochemistry

Aldous, I. M., & Hardwick, L. J. (2016). Solvent‐Mediated Control of the Electrochemical Discharge Products of Non‐Aqueous Sodium–Oxygen Electrochemistry. Angewandte Chemie, 128(29), 8394-8397. doi:10.1002/ange.201601615

DOI
10.1002/ange.201601615
Journal article

Utilizing in Situ Electrochemical SHINERS for Oxygen Reduction Reaction Studies in Aprotic Electrolytes

Galloway, T. A., & Hardwick, L. J. (2016). Utilizing in Situ Electrochemical SHINERS for Oxygen Reduction Reaction Studies in Aprotic Electrolytes. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 7(11), 2119-2124. doi:10.1021/acs.jpclett.6b00730

DOI
10.1021/acs.jpclett.6b00730
Journal article

Mechanistic Insight into the Superoxide Induced Ring Opening in Propylene Carbonate Based Electrolytes using in Situ Surface-Enhanced Infrared Spectroscopy

Vivek, J. P., Berry, N., Papageorgiou, G., Nichols, R. J., & Hardwick, L. J. (2016). Mechanistic Insight into the Superoxide Induced Ring Opening in Propylene Carbonate Based Electrolytes using in Situ Surface-Enhanced Infrared Spectroscopy. Journal of the American Chemical Society, 138(11), 3745-3751. doi:10.1021/jacs.5b12494

DOI
10.1021/jacs.5b12494
Journal article

2015

The role of re-aggregation on the performance of electrochemically exfoliated many-layer graphene for Li-ion batteries

Sole, C., Drewett, N. E., Liu, F., Abdelkader, A. M., Kinloch, I. A., & Hardwick, L. J. (2015). The role of re-aggregation on the performance of electrochemically exfoliated many-layer graphene for Li-ion batteries. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 753, 35-41. doi:10.1016/j.jelechem.2015.05.011

DOI
10.1016/j.jelechem.2015.05.011
Journal article

Charge Storage Mechanism of Activated Manganese Oxide Composites for Pseudocapacitors

Wu, T., Hesp, D., Dhanak, V., Collins, C., Braga, F., Hardwick, L., & Hu, C. (2015). Charge Storage Mechanism of Activated Manganese Oxide Composites for Pseudocapacitors. Journal of Materials Chemistry A, 3, 12786-12795. doi:10.1039/C5TA03334A

DOI
10.1039/C5TA03334A
Journal article

Scaling up "Nano" Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> for High-Power Lithium-Ion Anodes Using Large Scale Flame Spray Pyrolysis

Birrozzi, A., Copley, M., von Zamory, J., Pasqualini, M., Calcaterra, S., Nobili, F., . . . Passerini, S. (2015). Scaling up "Nano" Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> for High-Power Lithium-Ion Anodes Using Large Scale Flame Spray Pyrolysis. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 162(12), A2331-A2338. doi:10.1149/2.0711512jes

DOI
10.1149/2.0711512jes
Journal article

2014

Carbon electrodes for energy storage: general discussion

Gogotsi, Y., Guldi, D., McCreery, R., Hu, C. -C., Merlet, C., Beguin, F., . . . Noofeli, A. (2014). Carbon electrodes for energy storage: general discussion. FARADAY DISCUSSIONS, 172, 239-260. doi:10.1039/C4FD90026J

DOI
10.1039/C4FD90026J
Journal article

In Situ Raman Study of Lithium-Ion Intercalation into Microcrystalline Graphite

Sole, C., Drewett, N. E., & Hardwick, L. J. (2014). In Situ Raman Study of Lithium-Ion Intercalation into Microcrystalline Graphite. Faraday Discussions, 172, 223-237. doi:10.1039/C4FD00079J

DOI
10.1039/C4FD00079J
Journal article

The many faces of carbon in electrochemistry: general discussion

Dryfe, R., Chen, G. Z., Bayer, D., Jonsson-Niedziolka, M., McCreery, R., Macpherson, J., . . . Bergonzo, P. (2014). The many faces of carbon in electrochemistry: general discussion. FARADAY DISCUSSIONS, 172, 117-137. doi:10.1039/C4FD90025A

DOI
10.1039/C4FD90025A
Journal article

Influence of Tetraalkylammonium Cation Chain Length on Gold and Glassy Carbon Electrode Interfaces for Alkali Metal–Oxygen Batteries

Aldous, I., & Hardwick, L. (2014). Influence of Tetraalkylammonium Cation Chain Length on Gold and Glassy Carbon Electrode Interfaces for Alkali Metal–Oxygen Batteries. Journal of Physical Chemistry Letters, 5(21), 3924-3930. doi:10.1021/jz501850u

DOI
10.1021/jz501850u
Journal article

Characterization of Aluminum Doped Lithium-Manganese Rich Composites for Higher Rate Lithium-Ion Cathodes

Iftekhar, M., Drewett, N. E., Armstrong, A. R., Hesp, D., Braga, F., Ahmed, S., & Hardwick, L. J. (2014). Characterization of Aluminum Doped Lithium-Manganese Rich Composites for Higher Rate Lithium-Ion Cathodes. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 161(14), A2109-A2116. doi:10.1149/2.0441414jes

DOI
10.1149/2.0441414jes
Journal article

2013

Important parameters affecting the cell voltage of aqueous electrical double-layer capacitors

Wu, T. -H., Hsu, C. -T., Hu, C. -C., & Hardwick, L. J. (2013). Important parameters affecting the cell voltage of aqueous electrical double-layer capacitors. JOURNAL OF POWER SOURCES, 242, 289-298. doi:10.1016/j.jpowsour.2013.05.080

DOI
10.1016/j.jpowsour.2013.05.080
Journal article

Criteria appointing the highest acceptable cell voltage of asymmetric supercapacitors

Wu, T. -H., Chu, Y. -H., Hu, C. -C., & Hardwick, L. J. (2013). Criteria appointing the highest acceptable cell voltage of asymmetric supercapacitors. ELECTROCHEMISTRY COMMUNICATIONS, 27, 81-84. doi:10.1016/j.elecom.2012.10.033

DOI
10.1016/j.elecom.2012.10.033
Journal article

2012

Lithium Insertion into Anatase Nanotubes

Gentili, V., Brutti, S., Hardwick, L. J., Armstrong, A. R., Panero, S., & Bruce, P. G. (2012). Lithium Insertion into Anatase Nanotubes. CHEMISTRY OF MATERIALS, 24(22), 4468-4476. doi:10.1021/cm302912f

DOI
10.1021/cm302912f
Journal article

Direct Detection of Discharge Products in Lithium-Oxygen Batteries by Solid-State NMR Spectroscopy

Leskes, M., Drewett, N. E., Hardwick, L. J., Bruce, P. G., Goward, G. R., & Grey, C. P. (2012). Direct Detection of Discharge Products in Lithium-Oxygen Batteries by Solid-State NMR Spectroscopy. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 51(34), 8560-8563. doi:10.1002/anie.201202183

DOI
10.1002/anie.201202183
Journal article

The pursuit of rechargeable non-aqueous lithium-oxygen battery cathodes

Hardwick, L. J., & Bruce, P. G. (2012). The pursuit of rechargeable non-aqueous lithium-oxygen battery cathodes. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 16(4), 178-185. doi:10.1016/j.cossms.2012.04.001

DOI
10.1016/j.cossms.2012.04.001
Journal article

Li-O<sub>2</sub> and Li-S batteries with high energy storage (vol 11, pg 19, 2012)

Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J. -M. (2012). Li-O<sub>2</sub> and Li-S batteries with high energy storage (vol 11, pg 19, 2012). NATURE MATERIALS, 11(2). doi:10.1038/NMAT3237

DOI
10.1038/NMAT3237
Journal article

2011

Li-O<sub>2</sub> and Li-S batteries with high energy storage

Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J. -M. (2012). Li-O<sub>2</sub> and Li-S batteries with high energy storage. NATURE MATERIALS, 11(1), 19-29. doi:10.1038/nmat3191

DOI
10.1038/nmat3191
Journal article

The Lithium-Oxygen Battery with Ether-Based Electrolytes

Freunberger, S. A., Chen, Y., Drewett, N. E., Hardwick, L. J., Barde, F., & Bruce, P. G. (2011). The Lithium-Oxygen Battery with Ether-Based Electrolytes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 50(37), 8609-8613. doi:10.1002/anie.201102357

DOI
10.1002/anie.201102357
Journal article

Oxygen Reactions in a Non-Aqueous Li<SUP>+</SUP> Electrolyte

Peng, Z., Freunberger, S. A., Hardwick, L. J., Chen, Y., Giordani, V., Barde, F., . . . Bruce, P. G. (2011). Oxygen Reactions in a Non-Aqueous Li<SUP>+</SUP> Electrolyte. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 50(28), 6351-6355. doi:10.1002/anie.201100879

DOI
10.1002/anie.201100879
Journal article

Lithium-air and lithium-sulfur batteries

Bruce, P. G., Hardwick, L. J., & Abraham, K. M. (2011). Lithium-air and lithium-sulfur batteries. MRS BULLETIN, 36(7), 506-512. doi:10.1557/mrs.2011.157

DOI
10.1557/mrs.2011.157
Journal article

Reactions in the Rechargeable Lithium-O<sub>2</sub> Battery with Alkyl Carbonate Electrolytes

Freunberger, S. A., Chen, Y., Peng, Z., Griffin, J. M., Hardwick, L. J., Barde, F., . . . Bruce, P. G. (2011). Reactions in the Rechargeable Lithium-O<sub>2</sub> Battery with Alkyl Carbonate Electrolytes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(20), 8040-8047. doi:10.1021/ja2021747

DOI
10.1021/ja2021747
Journal article

Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li-O<sub>2</sub> Cells

Trahey, L., Johnson, C. S., Vaughey, J. T., Kang, S. -H., Hardwick, L. J., Freunberger, S. A., . . . Thackeray, M. M. (2011). Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li-O<sub>2</sub> Cells. ELECTROCHEMICAL AND SOLID STATE LETTERS, 14(5), A64-A66. doi:10.1149/1.3555366

DOI
10.1149/1.3555366
Journal article

2010

Lithium-air battery

Bruce, P. G., Freunberger, S. A., Hardwick, L. J., Peng, Z. Q., & Chen, Y. (2010). Lithium-air battery. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 240. Retrieved from https://www.webofscience.com/

Journal article

Surface structural disordering in graphite upon lithium intercalation/deintercalation

Sethuraman, V. A., Hardwick, L. J., Srinivasan, V., & Kostecki, R. (2010). Surface structural disordering in graphite upon lithium intercalation/deintercalation. JOURNAL OF POWER SOURCES, 195(11), 3655-3660. doi:10.1016/j.jpowsour.2009.12.034

DOI
10.1016/j.jpowsour.2009.12.034
Journal article

Lithium Diffusion in Graphitic Carbon

Persson, K., Sethuraman, V. A., Hardwick, L. J., Hinuma, Y., Meng, Y. S., van der Ven, A., . . . Ceder, G. (2010). Lithium Diffusion in Graphitic Carbon. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 1(8), 1176-1180. doi:10.1021/jz100188d

DOI
10.1021/jz100188d
Journal article

Microwave plasma chemical vapor deposition of graphitic carbon thin films

Marcinek, M., Hardwick, L. J., Zukowska, G. Z., & Kostecki, R. (2010). Microwave plasma chemical vapor deposition of graphitic carbon thin films. CARBON, 48(5), 1552-1557. doi:10.1016/j.carbon.2009.12.052

DOI
10.1016/j.carbon.2009.12.052
Journal article

Lithium Intercalation into Mesoporous Anatase with an Ordered 3D Pore Structure

Ren, Y., Hardwick, L. J., & Bruce, P. G. (2010). Lithium Intercalation into Mesoporous Anatase with an Ordered 3D Pore Structure. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 49(14), 2570-2574. doi:10.1002/anie.200907099

DOI
10.1002/anie.200907099
Journal article

Lithium Intercalation into Mesoporous Anatase with an Ordered 3D Pore Structure

Ren, Y., Hardwick, L. J., & Bruce, P. G. (2010). Lithium Intercalation into Mesoporous Anatase with an Ordered 3D Pore Structure. Angewandte Chemie, 122(14), 2624-2628. doi:10.1002/ange.200907099

DOI
10.1002/ange.200907099
Journal article

2009

Electrochemical doping of single-walled carbon nanotubes in double layer capacitors studied by <i>in situ</i> Raman spectroscopy

Ruch, P. W., Hardwick, L. J., Hahn, M., Foelske, A., Koetz, R., & Wokaun, A. (2009). Electrochemical doping of single-walled carbon nanotubes in double layer capacitors studied by <i>in situ</i> Raman spectroscopy. CARBON, 47(1), 38-52. doi:10.1016/j.carbon.2008.08.023

DOI
10.1016/j.carbon.2008.08.023
Journal article

FTIR and Raman Study of the Li<sub>x</sub>Ti<sub>y</sub>Mn<sub>1-y</sub>O<sub>2</sub> (y=0, 0.11) Cathodes in Methylpropyl Pyrrolidinium Bis(fluoro-sulfonyl)imide, LiTFSI Electrolyte

Hardwick, L. J., Saint, J. A., Lucas, I. T., Doeff, M. M., & Kostecki, R. (2009). FTIR and Raman Study of the Li<sub>x</sub>Ti<sub>y</sub>Mn<sub>1-y</sub>O<sub>2</sub> (y=0, 0.11) Cathodes in Methylpropyl Pyrrolidinium Bis(fluoro-sulfonyl)imide, LiTFSI Electrolyte. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 156(2), A120-A127. doi:10.1149/1.3040210

DOI
10.1149/1.3040210
Journal article

2008

Studying the Origin and Mechanism of Irreversible Capacity in Lithium-Ion Cells

Hardwick, L. J., Marcinek, M., & Kostecki, R. (2008). Studying the Origin and Mechanism of Irreversible Capacity in Lithium-Ion Cells. In ECS Transactions Vol. 11 (pp. 139-148). The Electrochemical Society. doi:10.1149/1.2938917

DOI
10.1149/1.2938917
Conference Paper

An investigation of the effect of graphite degradation on irreversible capacity in lithium-ion cells

Hardwick, L. J., Marcinek, M., Beer, L., Kerr, J. B., & Kostecki, R. (2008). An investigation of the effect of graphite degradation on irreversible capacity in lithium-ion cells. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 155(6), A442-A447. doi:10.1149/1.2903882

DOI
10.1149/1.2903882
Journal article

<i>In situ</i> Raman spectroscopy of insertion electrodes for lithium-ion batteries and supercapacitors:: First cycle effects

Hardwick, L. J., Ruch, P. W., Hahn, M., Scheifele, W., Koetz, R., & Novak, P. (2008). <i>In situ</i> Raman spectroscopy of insertion electrodes for lithium-ion batteries and supercapacitors:: First cycle effects. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 69(5-6), 1232-1237. doi:10.1016/j.jpcs.2007.10.017

DOI
10.1016/j.jpcs.2007.10.017
Journal article

2007

Microwave plasma chemical vapor deposition of nano-structured Sn/C composite thin-film anodes for Li-ion batteries

Marcinek, A., Hardwick, L. J., Richardson, T. J., Song, X., & Kostecki, R. (2007). Microwave plasma chemical vapor deposition of nano-structured Sn/C composite thin-film anodes for Li-ion batteries. JOURNAL OF POWER SOURCES, 173(2), 965-971. doi:10.1016/j.jpowsour.2007.08.084

DOI
10.1016/j.jpowsour.2007.08.084
Journal article

Application of In Situ Techniques for Investigations in Lithium-Ion Battery Materials

Vetter, J., Hardwick, L. J., Würsig, A., Holzapfel, M., Schneider, O. D., Ufheil, J., & Novák, P. (2007). Application of In Situ Techniques for Investigations in Lithium-Ion Battery Materials. In ECS Transactions Vol. 3 (pp. 29-43). The Electrochemical Society. doi:10.1149/1.2793576

DOI
10.1149/1.2793576
Conference Paper

Electrochemical lithium insertion into anatase-type TiO<sub>2</sub>:: An <i>in situ</i> Raman microscopy investigation

Hardwick, L. J., Holzapfel, M., Novak, P., Dupont, L., & Baudrin, E. (2007). Electrochemical lithium insertion into anatase-type TiO<sub>2</sub>:: An <i>in situ</i> Raman microscopy investigation. ELECTROCHIMICA ACTA, 52(17), 5357-5367. doi:10.1016/j.electacta.2007.02.050

DOI
10.1016/j.electacta.2007.02.050
Journal article

Behaviour of highly crystalline graphitic materials in lithium-ion cells with propylene carbonate containing electrolytes:: An <i>in situ</i> Raman and SEM study

Hardwick, L. J., Buqa, H., Holzapfel, M., Scheifele, W., Krumeich, F., & Novak, P. (2007). Behaviour of highly crystalline graphitic materials in lithium-ion cells with propylene carbonate containing electrolytes:: An <i>in situ</i> Raman and SEM study. ELECTROCHIMICA ACTA, 52(15), 4884-4891. doi:10.1016/j.electacta.2006.12.081

DOI
10.1016/j.electacta.2006.12.081
Journal article

Raman study of lithium coordination in EMI-TFSI additive systems as lithium-ion battery ionic liquid electrolytes

Hardwick, L. J., Holzapfel, M., Wokaun, A., & Novak, P. (2007). Raman study of lithium coordination in EMI-TFSI additive systems as lithium-ion battery ionic liquid electrolytes. JOURNAL OF RAMAN SPECTROSCOPY, 38(1), 110-112. doi:10.1002/jrs.1632

DOI
10.1002/jrs.1632
Journal article

2006

Nano silicon for lithium-ion batteries

Holzapfel, M., Buqa, H., Hardwick, L. J., Hahn, M., Wuersig, A., Scheifele, W., . . . Petrat, F. -M. (2006). Nano silicon for lithium-ion batteries. ELECTROCHIMICA ACTA, 52(3), 973-978. doi:10.1016/j.electacta.2006.06.034

DOI
10.1016/j.electacta.2006.06.034
Journal article

Graphite surface disorder detection using in situ Raman microscopy

Hardwick, L. J., Buqa, H., & Novak, P. (2006). Graphite surface disorder detection using in situ Raman microscopy. SOLID STATE IONICS, 177(26-32), 2801-2806. doi:10.1016/j.ssi.2006.03.032

DOI
10.1016/j.ssi.2006.03.032
Journal article

An <i>in situ</i> Raman study of the intercalation of supercapacitor-type electrolyte into microcrystalline graphite

Hardwick, L. J., Hahn, M., Ruch, P., Holzapfel, M., Scheifele, W., Buqa, H., . . . Koetz, R. (2006). An <i>in situ</i> Raman study of the intercalation of supercapacitor-type electrolyte into microcrystalline graphite. ELECTROCHIMICA ACTA, 52(2), 675-680. doi:10.1016/j.electacta.2006.05.053

DOI
10.1016/j.electacta.2006.05.053
Journal article

Surface reactivity of graphite materials and their surface passivation during the first electrochemical lithium insertion

Spahr, M. E., Buqa, H., Würsig, A., Goers, D., Hardwick, L., Novák, P., . . . Vix-Guterl, C. (2006). Surface reactivity of graphite materials and their surface passivation during the first electrochemical lithium insertion. JOURNAL OF POWER SOURCES, 153(2), 300-311. doi:10.1016/j.jpowsour.2005.05.032

DOI
10.1016/j.jpowsour.2005.05.032
Journal article

2005

Advanced in situ characterization methods applied to carbonaceous materials

Novák, P., Goers, D., Hardwick, L., Holzapfel, M., Scheifele, W., Ufhiel, J., & Würsig, A. (2005). Advanced in situ characterization methods applied to carbonaceous materials. JOURNAL OF POWER SOURCES, 146(1-2), 15-20. doi:10.1016/j.jpowsour.2005.03.129

DOI
10.1016/j.jpowsour.2005.03.129
Journal article

Behaviour of highly crystalline graphites in lithium-ion cells with propylene carbonate containing electrolytes

Buqa, H., Würsig, A., Goers, A., Hardwick, L. J., Holzapfel, M., Novák, P., . . . Spahr, M. E. (2005). Behaviour of highly crystalline graphites in lithium-ion cells with propylene carbonate containing electrolytes. JOURNAL OF POWER SOURCES, 146(1-2), 134-141. doi:10.1016/j.jpowsour.2005.03.106

DOI
10.1016/j.jpowsour.2005.03.106
Journal article

2003

In situ Raman studies of phenolic resin based hard carbon

Goers, D., Baertsch, M. C., Wuersig, A., Hardwick, L., & Novák, P. (2003). In situ Raman studies of phenolic resin based hard carbon. In Proceedings - Electrochemical Society Vol. 20 (pp. 107-114).

Conference Paper

Raman spectroscopic and structural studies of heat-treated graphites for lithium-ion batteries

Goers, D., Buqa, H., Hardwick, L., Wursig, A., & Novák, P. (2003). Raman spectroscopic and structural studies of heat-treated graphites for lithium-ion batteries. IONICS, 9(3-4), 258-265. doi:10.1007/BF02375977

DOI
10.1007/BF02375977
Journal article