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Luke Daniels

Dr Luke Daniels
BSc, PhD

Research Co-ordinator (Rosseinsky Group)
Chemistry

Publications

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2024

Navigation through high-dimensional chemical space: discovery of Ba<sub>5</sub>Y<sub>13</sub>[SiO<sub>4</sub>]<sub>8</sub>O<sub>8.5</sub> and Ba<sub>3</sub>Y<sub>2</sub>[Si<sub>2</sub>O<sub>7</sub>]<sub>2</sub>.

Gulay, N. L., Zanella, M., Robertson, C. M., Ritchie, D., Sonni, M., Wright, M. A., . . . Rosseinsky, M. J. (2024). Navigation through high-dimensional chemical space: discovery of Ba<sub>5</sub>Y<sub>13</sub>[SiO<sub>4</sub>]<sub>8</sub>O<sub>8.5</sub> and Ba<sub>3</sub>Y<sub>2</sub>[Si<sub>2</sub>O<sub>7</sub>]<sub>2</sub>.. Chemical science. doi:10.1039/d4sc04440a

DOI
10.1039/d4sc04440a
Journal article

Enhancement of Low Temperature Superionic Conductivity by Suppression of Li Site Ordering in Li<sub>7</sub>Si<sub>2-x</sub>Ge<sub>x</sub>S<sub>7</sub>I.

Han, G., Daniels, L. M., Vasylenko, A., Morrison, K. A., Corti, L., Collins, C. M., . . . Rosseinsky, M. J. (2024). Enhancement of Low Temperature Superionic Conductivity by Suppression of Li Site Ordering in Li<sub>7</sub>Si<sub>2-x</sub>Ge<sub>x</sub>S<sub>7</sub>I.. Angewandte Chemie (International ed. in English), 63(37), e202409372. doi:10.1002/anie.202409372

DOI
10.1002/anie.202409372
Journal article

Enhancement of Low Temperature Superionic Conductivity by Suppression of Li Site Ordering in Li<sub>7</sub>Si<sub>2–x</sub>Ge<sub>x</sub>S<sub>7</sub>I

Han, G., Daniels, L. M., Vasylenko, A., Morrison, K. A., Corti, L., Collins, C. M., . . . Rosseinsky, M. J. (2024). Enhancement of Low Temperature Superionic Conductivity by Suppression of Li Site Ordering in Li<sub>7</sub>Si<sub>2–x</sub>Ge<sub>x</sub>S<sub>7</sub>I. Angewandte Chemie, 136(37). doi:10.1002/ange.202409372

DOI
10.1002/ange.202409372
Journal article

Control of Polarity in Kagome-NiAs Bismuthides.

Gibson, Q. D., Wen, D., Lin, H., Zanella, M., Daniels, L. M., Robertson, C. M., . . . Rosseinsky, M. J. (2024). Control of Polarity in Kagome-NiAs Bismuthides.. Angewandte Chemie (International ed. in English), 63(23), e202403670. doi:10.1002/anie.202403670

DOI
10.1002/anie.202403670
Journal article

Synthesis, Structure, and Properties of CuBiSeCl<sub>2</sub>: A Chalcohalide Material with Low Thermal Conductivity.

Hawkins, C. J., Newnham, J. A., Almoussawi, B., Gulay, N. L., Goodwin, S. L., Zanella, M., . . . Rosseinsky, M. J. (2024). Synthesis, Structure, and Properties of CuBiSeCl<sub>2</sub>: A Chalcohalide Material with Low Thermal Conductivity.. Chemistry of materials : a publication of the American Chemical Society, 36(9), 4530-4541. doi:10.1021/acs.chemmater.4c00188

DOI
10.1021/acs.chemmater.4c00188
Journal article

Synthesis, Structure &amp;amp; Properties of CuBiSeCl2: A Chalcohalide Material with Low Thermal Conductivity

DOI
10.26434/chemrxiv-2023-vkqh1-v2
Preprint

2023

Synthesis, Structure &amp;amp; Properties of CuBiSeCl2: A Chalcohalide Material with Low Thermal Conductivity

DOI
10.26434/chemrxiv-2023-vkqh1
Preprint

Toward Understanding of the Li-Ion Migration Pathways in the Lithium Aluminum Sulfides Li3AlS3 and Li4.3AlS3.3Cl0.7 via 6,7Li Solid- State Nuclear Magnetic Resonance Spectroscopy

Duff, B. B., Elliott, S. J., Gamon, J., Daniels, L. M., Rosseinsky, M. J., & Blanc, F. (2023). Toward Understanding of the Li-Ion Migration Pathways in the Lithium Aluminum Sulfides Li3AlS3 and Li4.3AlS3.3Cl0.7 via 6,7Li Solid- State Nuclear Magnetic Resonance Spectroscopy. CHEMISTRY OF MATERIALS, 35(1), 27-40. doi:10.1021/acs.chemmater.2c02101

DOI
10.1021/acs.chemmater.2c02101
Journal article

2022

Control of Ionic Conductivity by Lithium Distribution in Cubic Oxide Argyrodites Li<sub>6+<i>X</i></sub>P<sub>1-<i>X</i></sub>Si<i><sub>X</sub></i>O<sub>5</sub>Cl

Morscher, A., Duff, B. B., Han, G., Daniels, L. M., Dang, Y., Zanella, M., . . . Rosseinsky, M. J. (2022). Control of Ionic Conductivity by Lithium Distribution in Cubic Oxide Argyrodites Li<sub>6+<i>X</i></sub>P<sub>1-<i>X</i></sub>Si<i><sub>X</sub></i>O<sub>5</sub>Cl. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 144(48), 22178-22192. doi:10.1021/jacs.2c09863

DOI
10.1021/jacs.2c09863
Journal article

Single crystal growth and properties of the polar ferromagnet Mn 1.05 Bi with Kagome layers, huge magnetic anisotropy and slow spin dynamics

Gibson, Q. D., Robertson, C. M., Dyer, M. S., Zanella, M., Surta, T. W., Daniels, L. M., . . . Rosseinsky, M. J. (n.d.). Single crystal growth and properties of the polar ferromagnet Mn1.05Bi with Kagome layers, huge magnetic anisotropy and slow spin dynamics. Physical Review Materials, 6(11). doi:10.1103/physrevmaterials.6.114405

DOI
10.1103/physrevmaterials.6.114405
Journal article

Fluorine-Rich Oxyfluoride Spinel Li1.25Ni0.625Mn1.125O3F Utilizing Redox-Active Ni and Mn for High Capacity and Improved Cyclability

DOI
10.26434/chemrxiv-2022-8f3fk
Preprint

Expanding multiple anion superlattice chemistry: Synthesis, structure and properties of Bi<sub>4</sub>O<sub>4</sub>SeBr<sub>2</sub> and Bi<sub>6</sub>O<sub>6</sub>Se<sub>2</sub>Cl<sub>2</sub>

Gibson, Q. D., Newnham, J. A., Dyer, M. S., Robertson, C. M., Zanella, M., Surta, T. W., . . . Rosseinsky, M. J. (2022). Expanding multiple anion superlattice chemistry: Synthesis, structure and properties of Bi<sub>4</sub>O<sub>4</sub>SeBr<sub>2</sub> and Bi<sub>6</sub>O<sub>6</sub>Se<sub>2</sub>Cl<sub>2</sub>. JOURNAL OF SOLID STATE CHEMISTRY, 312. doi:10.1016/j.jssc.2022.123246

DOI
10.1016/j.jssc.2022.123246
Journal article

2021

High-Throughput Discovery of a Rhombohedral Twelve-Connected Zirconium-Based Metal-Organic Framework with Ordered Terephthalate and Fumarate Linkers

Tollitt, A. M., Vismara, R., Daniels, L. M., Antypov, D., Gaultois, M. W., Katsoulidis, A. P., & Rosseinsky, M. J. (2021). High-Throughput Discovery of a Rhombohedral Twelve-Connected Zirconium-Based Metal-Organic Framework with Ordered Terephthalate and Fumarate Linkers. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 60(52), 26939-26946. doi:10.1002/anie.202108150

DOI
10.1002/anie.202108150
Journal article

High‐Throughput Discovery of a Rhombohedral Twelve‐Connected Zirconium‐Based Metal‐Organic Framework with Ordered Terephthalate and Fumarate Linkers

Tollitt, A. M., Vismara, R., Daniels, L. M., Antypov, D., Gaultois, M. W., Katsoulidis, A. P., & Rosseinsky, M. J. (2021). High‐Throughput Discovery of a Rhombohedral Twelve‐Connected Zirconium‐Based Metal‐Organic Framework with Ordered Terephthalate and Fumarate Linkers. Angewandte Chemie, 133(52), 27145-27152. doi:10.1002/ange.202108150

DOI
10.1002/ange.202108150
Journal article

Ordered Oxygen Vacancies in the Lithium-Rich Oxide Li<sub>4</sub>CuSbO<sub>5.5</sub>, a Triclinic Structure Type Derived from the Cubic Rocksalt Structure

Perez, A. J., Vasylenko, A., Surta, T. W., Niu, H., Daniels, L. M., Hardwick, L. J., . . . Rosseinsky, M. J. (2021). Ordered Oxygen Vacancies in the Lithium-Rich Oxide Li<sub>4</sub>CuSbO<sub>5.5</sub>, a Triclinic Structure Type Derived from the Cubic Rocksalt Structure. INORGANIC CHEMISTRY, 60(24), 19022-19034. doi:10.1021/acs.inorgchem.1c02882

DOI
10.1021/acs.inorgchem.1c02882
Journal article

Li<sub>4.3</sub>AlS<sub>3.3</sub>Cl<sub>0.7</sub>: A Sulfide-Chloride Lithium Ion Conductor with Highly Disordered Structure and Increased Conductivity

Gamon, J., Dyer, M. S., Duff, B. B., Vasylenko, A., Daniels, L. M., Zanella, M., . . . Rosseinsky, M. J. (2021). Li<sub>4.3</sub>AlS<sub>3.3</sub>Cl<sub>0.7</sub>: A Sulfide-Chloride Lithium Ion Conductor with Highly Disordered Structure and Increased Conductivity. CHEMISTRY OF MATERIALS, 33(22), 8733-8744. doi:10.1021/acs.chemmater.1c02751

DOI
10.1021/acs.chemmater.1c02751
Journal article

Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability

Han, G., Vasylenko, A., Neale, A. R., Duff, B. B., Chen, R., Dyer, M. S., . . . Rosseinsky, M. J. (2021). Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(43), 18216-18232. doi:10.1021/jacs.1c07874

DOI
10.1021/jacs.1c07874
Journal article

Li4.3AlS3.3Cl0.7: A Sulfide-Chloride Lithium Ion Conductor with a Highly Disordered Structure

DOI
10.26434/chemrxiv.14454627
Preprint

2020

Vegard Relation and Raman Band Reference Data Generated from Bulk Crystals of Kesterite-Phase Composition Series Cu2ZnSnS4xSe4–4x (CZTSSe, 0 ≤ x ≤ 1)

Hobson, T. D. C., Hutter, O. S., Fleck, N., Daniels, L. M., Major, J. D., Ng, T. M., & Durose, K. (2020). Vegard Relation and Raman Band Reference Data Generated from Bulk Crystals of Kesterite-Phase Composition Series Cu2ZnSnS4xSe4–4x (CZTSSe, 0 ≤ x ≤ 1). Crystal Growth & Design, 20(4), 2164-2173. doi:10.1021/acs.cgd.9b00911

DOI
10.1021/acs.cgd.9b00911
Journal article

2019

Computationally Guided Discovery of the Sulfide Li<sub>3</sub>AlS<sub>3</sub> in the Li-Al-S Phase Field: Structure and Lithium Conductivity

Gamon, J., Duff, B. B., Dyer, M. S., Collins, C., Daniels, L. M., Surta, T. W., . . . Rosseinsky, M. J. (2019). Computationally Guided Discovery of the Sulfide Li<sub>3</sub>AlS<sub>3</sub> in the Li-Al-S Phase Field: Structure and Lithium Conductivity. CHEMISTRY OF MATERIALS, 31(23), 9699-9714. doi:10.1021/acs.chemmater.9b03230

DOI
10.1021/acs.chemmater.9b03230
Journal article

2018

Bi<sub>2+2<i>n</i></sub>O<sub>2+2<i>n</i></sub>Cu<sub>2-δ</sub>Se<sub>2+<i>n</i>-δ</sub>X<sub>δ</sub> (X = CI, Br): A Three-Anion Homologous Series

Gibson, Q. D., Dyer, M. S., Robertson, C., Delacotte, C., Manning, T. D., Pitcher, M. J., . . . Rosseinsky, M. J. (2018). Bi<sub>2+2<i>n</i></sub>O<sub>2+2<i>n</i></sub>Cu<sub>2-δ</sub>Se<sub>2+<i>n</i>-δ</sub>X<sub>δ</sub> (X = CI, Br): A Three-Anion Homologous Series. INORGANIC CHEMISTRY, 57(20), 12489-12500. doi:10.1021/acs.inorgchem.8b01126

DOI
10.1021/acs.inorgchem.8b01126
Journal article

A and B site doping of a phonon-glass perovskite oxide thermoelectric

Daniels, L. M., Ling, S., Savvin, S. N., Pitcher, M. J., Dyer, M. S., Claridge, J. B., . . . Rosseinsky, M. J. (2018). A and B site doping of a phonon-glass perovskite oxide thermoelectric. JOURNAL OF MATERIALS CHEMISTRY A, 6(32), 15640-15652. doi:10.1039/c8ta03739f

DOI
10.1039/c8ta03739f
Journal article

2017

Structural Disorder in (Bi, M)<sub>2</sub>(Fe, Mn, Bi)<sub>2</sub>O<sub>6+x</sub> (M = Na or K) Pyrochlores Seen from Reverse Monte Carlo Analysis of Neutron Total Scattering

Daniels, L. M., Playford, H. Y., Hannon, A. C., & Walton, R. I. (2017). Structural Disorder in (Bi, M)<sub>2</sub>(Fe, Mn, Bi)<sub>2</sub>O<sub>6+x</sub> (M = Na or K) Pyrochlores Seen from Reverse Monte Carlo Analysis of Neutron Total Scattering. JOURNAL OF PHYSICAL CHEMISTRY C, 121(33), 18120-18128. doi:10.1021/acs.jpcc.7b04972

DOI
10.1021/acs.jpcc.7b04972
Journal article

2016

La<sub>3</sub>Li<sub>3</sub>W<sub>2</sub>O<sub>12</sub>: Ionic Diffusion in a Perovskite with Lithium on both A- and 6-Sites

Santibanez-Mendieta, A. B., Didier, C., Inglis, K. K., Corkett, A. J., Pitcher, M. J., Zanella, M., . . . Rosseinsky, M. J. (2016). La<sub>3</sub>Li<sub>3</sub>W<sub>2</sub>O<sub>12</sub>: Ionic Diffusion in a Perovskite with Lithium on both A- and 6-Sites. CHEMISTRY OF MATERIALS, 28(21), 7833-7851. doi:10.1021/acs.chemmater.6b03220

DOI
10.1021/acs.chemmater.6b03220
Journal article

2015

Metal Organic Frameworks from Divalent Metals and 1,4-Benzenedicarboxylate with Bidentate Pyridine-<i>N</i>-oxide Co-ligands

Munn, A. S., Amabilino, S., Stevens, T. W., Daniels, L. M., Clarkson, G. J., Millange, F., . . . Walton, R. I. (2015). Metal Organic Frameworks from Divalent Metals and 1,4-Benzenedicarboxylate with Bidentate Pyridine-<i>N</i>-oxide Co-ligands. CRYSTAL GROWTH & DESIGN, 15(2), 891-899. doi:10.1021/cg501690b

DOI
10.1021/cg501690b
Journal article

2014

Metastable (Bi, M)<sub>2</sub>(Fe, Mn, Bi)<sub>2</sub>O<sub>6+x</sub> (M = Na or K) Pyrochlores from Hydrothermal Synthesis

Daniels, L. M., Playford, H. Y., Greneche, J. -M., Hannon, A. C., & Walton, R. I. (2014). Metastable (Bi, M)<sub>2</sub>(Fe, Mn, Bi)<sub>2</sub>O<sub>6+x</sub> (M = Na or K) Pyrochlores from Hydrothermal Synthesis. INORGANIC CHEMISTRY, 53(24), 13197-13206. doi:10.1021/ic502411z

DOI
10.1021/ic502411z
Journal article

Mixed-Metal MIL-100(Sc,M) (M=Al, Cr, Fe) for Lewis Acid Catalysis and Tandem C-C Bond Formation and Alcohol Oxidation

Mitchell, L., Williamson, P., Ehrlichova, B., Anderson, A. E., Seymour, V. R., Ashbrook, S. E., . . . Wright, P. A. (2014). Mixed-Metal MIL-100(Sc,M) (M=Al, Cr, Fe) for Lewis Acid Catalysis and Tandem C-C Bond Formation and Alcohol Oxidation. CHEMISTRY-A EUROPEAN JOURNAL, 20(51), 17185-17197. doi:10.1002/chem.201404377

DOI
10.1002/chem.201404377
Journal article

Synthesis, characterization and properties of a family of lead(II)-organic frameworks based on a multi-functional ligand 2-amino-4-sulfobenzoic acid exhibiting auxiliary ligand-dependent dehydration rehydration behaviours

Zhang, K. -L., Zhong, Z. -Y., Zhang, L., Jing, C. -Y., Daniels, L. M., & Walton, R. I. (2014). Synthesis, characterization and properties of a family of lead(II)-organic frameworks based on a multi-functional ligand 2-amino-4-sulfobenzoic acid exhibiting auxiliary ligand-dependent dehydration rehydration behaviours. DALTON TRANSACTIONS, 43(30), 11597-11610. doi:10.1039/c4dt00659c

DOI
10.1039/c4dt00659c
Journal article

2013

Structures and Magnetism of the Rare-Earth Orthochromite Perovskite Solid Solution La<i><sub>x</sub></i>Sm<sub>1-<i>x</i></sub>CrO<sub>3</sub>

Daniels, L. M., Weber, M. C., Lees, M. R., Guennou, M., Kashtiban, R. J., Sloan, J., . . . Walton, R. I. (2013). Structures and Magnetism of the Rare-Earth Orthochromite Perovskite Solid Solution La<i><sub>x</sub></i>Sm<sub>1-<i>x</i></sub>CrO<sub>3</sub>. INORGANIC CHEMISTRY, 52(20), 12161-12169. doi:10.1021/ic402029u

DOI
10.1021/ic402029u
Journal article