Publications
2018
Contrasting Transient Photocurrent Characteristics for Thin Films of Vacuum-Doped “Grey” TiO2 and “Grey” Nb2O5
Araujo, M., Gromboni, M., Marken, F., Parker, S., Peter, L., Turner, J., . . . Mascaro, L. H. (2018). Contrasting Transient Photocurrent Characteristics for Thin Films of Vacuum-Doped “Grey” TiO2 and “Grey” Nb2O5. Applied Catalysis B: Environmental, 237, 339-352. doi:10.1016/j.apcatb.2018.05.065
2017
Chiral lanthanide complexes in organic synthesis
Aspinall, H. C. (2017). Chiral lanthanide complexes in organic synthesis. In J. Mlynarski (Ed.), Chiral Lewis Acids in Organic Synthesis (pp. 261-298). John Wiley and Sons.
2016
Embedding Outreach into the Undergraduate Science Curriculum – Everyone's a Winner
Aspinall, H., Qualter, A., & Rushworth, E. D. (n.d.). Embedding Outreach into the Undergraduate Science Curriculum – Everyone's a Winner. New Directions in the Teaching of Physical Sciences, (11). doi:10.29311/ndtps.v0i11.562
Titanium oxo-alkoxide clusters as a new source material for high quality TiO<inf>2</inf> structures by inkjet printing
Turner, J., Mehta, D., Aspinall, H. C., Rushworth, S., & Black, K. (2016). Titanium oxo-alkoxide clusters as a new source material for high quality TiO<inf>2</inf> structures by inkjet printing. In International Conference on Digital Printing Technologies (pp. 64-67).
2015
Heteroleptic titanium alkoxides as single-source precursors for MOCVD of micro-structured TiO2
Ashraf, S., Aspinall, H. C., Bacsa, J., Chalker, P. R., Davies, H. O., Jones, A. C., . . . Wrench, J. S. (2015). Heteroleptic titanium alkoxides as single-source precursors for MOCVD of micro-structured TiO2. Polyhedron, 85, 761-769. doi:10.1016/j.poly.2014.10.007
2014
Adding the right (or left) twist to tris-chelate complexes – coordination chemistry of chiral oxazolylphenolates with M3+ ions (M = Al or lanthanide)
Aspinall, H., Bacsa, J., Beckingham, O., Eden, E. G. B., Greeves, N., Hobbs, M. D., . . . Thomas, C. D. (2014). Adding the right (or left) twist to tris-chelate complexes – coordination chemistry of chiral oxazolylphenolates with M3+ ions (M = Al or lanthanide). Dalton Transactions, 43(3), 1434-1442. doi:10.1039/C3DT52366G
2012
Thermal Stability of Neodymium Aluminates High-κ Dielectric Deposited by Liquid Injection MOCVD Using Single-Source Heterometallic Alkoxide Precursors
Taechakumput, P., Zhao, C. Z., Taylor, S., Werner, M., Chalker, P. R., Gaskell, J. M., . . . Chen, S. (2012). Thermal Stability of Neodymium Aluminates High-κ Dielectric Deposited by Liquid Injection MOCVD Using Single-Source Heterometallic Alkoxide Precursors. JOURNAL OF NANOMATERIALS, 2012. doi:10.1155/2012/891079
2011
Ce(IV) Complexes with Donor-Functionalized Alkoxide Ligands: Improved Precursors for Chemical Vapor Deposition of CeO<sub>2</sub>
Aspinall, H. C., Bacsa, J., Jones, A. C., Wrench, J. S., Black, K., Chalker, P. R., . . . Odedra, R. (2011). Ce(IV) Complexes with Donor-Functionalized Alkoxide Ligands: Improved Precursors for Chemical Vapor Deposition of CeO<sub>2</sub>. Inorganic Chemistry, 50(22), 11644-11652. doi:10.1021/ic201593s
Ce(IV) Complexes with Donor-Functionalized Alkoxide Ligands: Improved Precursors for Chemical Vapor Deposition of CeO<sub>2</sub>
Aspinall, H. C., Bacsa, J., Jones, A. C., Wrench, J. S., Black, K., Chalker, P. R., . . . Odedra, R. (2011). Ce(IV) Complexes with Donor-Functionalized Alkoxide Ligands: Improved Precursors for Chemical Vapor Deposition of CeO<sub>2</sub>. INORGANIC CHEMISTRY, 50(22), 11644-11652. doi:10.1021/ic201593s
A general and convenient route to oxazolyl ligands
Aspinall, H. C., Beckingham, O., Farrar, M. D., Greeves, N., & Thomas, C. D. (2011). A general and convenient route to oxazolyl ligands. TETRAHEDRON LETTERS, 52(40), 5120-5123. doi:10.1016/j.tetlet.2011.07.070
Atomic layer deposition of TaN and Ta<sub>3</sub>N<sub>5</sub> using pentakis(dimethylamino) tantalum and either ammonia or monomethylhydrazine
Fang, Z., Aspinall, H. C., Odedra, R., & Potter, R. J. (2011). Atomic layer deposition of TaN and Ta<sub>3</sub>N<sub>5</sub> using pentakis(dimethylamino) tantalum and either ammonia or monomethylhydrazine. JOURNAL OF CRYSTAL GROWTH, 331(1), 33-39. doi:10.1016/j.jcrysgro.2011.07.012
Effect of deposition temperature on the properties of CeO<sub>2</sub> films grown by atomic layer deposition
King, P. J., Werner, M., Chalker, P. R., Jones, A. C., Aspinall, H. C., Basca, J., . . . Heys, P. N. (2011). Effect of deposition temperature on the properties of CeO<sub>2</sub> films grown by atomic layer deposition. THIN SOLID FILMS, 519(13), 4192-4195. doi:10.1016/j.tsf.2011.02.025
Providing Recordings of Chemistry Teaching
Berry, N., Greeves, N., Aspinall, H., Bunyan, N., Barnes, K., Bradford, M., & Chin, P. (2011). Providing Recordings of Chemistry Teaching. Wavelength, 7(1), 6-9.
2010
A new Yb<SUP>3+</SUP>-catalyzed pinacol and imine-coupling reaction
Aspinall, H. C., Greeves, N., & Hin, S. L. F. (2010). A new Yb<SUP>3+</SUP>-catalyzed pinacol and imine-coupling reaction. TETRAHEDRON LETTERS, 51(12), 1558-1561. doi:10.1016/j.tetlet.2010.01.057
2009
MOCVD and ALD of CeO<sub>2</sub> Thin Films using a Novel Monomeric Ce<SUP>IV</SUP> Alkoxide Precursor
Wrench, J. S., Black, K., Aspinall, H. C., Jones, A. C., Bacsa, J., Chalker, P. R., . . . Heys, P. N. (2009). MOCVD and ALD of CeO<sub>2</sub> Thin Films using a Novel Monomeric Ce<SUP>IV</SUP> Alkoxide Precursor. CHEMICAL VAPOR DEPOSITION, 15(10-12), 259-+. doi:10.1002/cvde.200904279
Chapter 8. Chemical Vapour Deposition of Metal Oxides for Microelectronics Applications
Jones, A. C., Aspinall, H. C., & Chalker, P. R. (2009). Chapter 8. Chemical Vapour Deposition of Metal Oxides for Microelectronics Applications. In L. M. Hitchman, & A. C. Jones (Eds.), Chemical Vapour Deposition: Precursors and Processes (pp. 357-412). London: Royal Society of Chemistry.
MOCVD and ALD of CeO2 Thin Films using a Novel Monomeric CeIV Alkoxide Precursor
Wrench, J. S., Black, K., Aspinall, H. C., Jones, A. C., Bacsa, J., Chalker, P. R., . . . Heys, P. N. (2009). MOCVD and ALD of CeO2 Thin Films using a Novel Monomeric CeIV Alkoxide Precursor. Chemical Vapour Deposition, 15, 1-3.
2008
Permittivity enhancement of hafnium dioxide high-κ films by cerium doping
Chalker, P. R., Werner, M., Romani, S., Potter, R. J., Black, K., Aspinall, H. C., . . . Heys, P. N. (2008). Permittivity enhancement of hafnium dioxide high-κ films by cerium doping. APPLIED PHYSICS LETTERS, 93(18). doi:10.1063/1.3023059
Deposition of ZrO<sub>2</sub> and HfO<sub>2</sub> thin films by liquid injection MOCVD and ALD using <i>ansa</i>-metallocene zirconium and hafnium precursors
Black, K., Aspinall, H. C., Jones, A. C., Przybylak, K., Bacsa, J., Chalker, P. R., . . . Heys, P. N. (2008). Deposition of ZrO<sub>2</sub> and HfO<sub>2</sub> thin films by liquid injection MOCVD and ALD using <i>ansa</i>-metallocene zirconium and hafnium precursors. JOURNAL OF MATERIALS CHEMISTRY, 18(38), 4561-4571. doi:10.1039/b807205a
2007
Deposition of Lanthanum Zirconium Oxide High-<i>k</i> Films by Liquid Injection ALD and MOCVD
Gaskell, J. M., Jones, A. C., Chalker, P. R., Werner, M., Aspinall, H. C., Taylor, S., . . . Heys, P. N. (2007). Deposition of Lanthanum Zirconium Oxide High-<i>k</i> Films by Liquid Injection ALD and MOCVD. CHEMICAL VAPOR DEPOSITION, 13(12), 684-690. doi:10.1002/cvde.200706637
Growth of HfO<sub>2</sub> by Liquid Injection MOCVD and ALD Using New Hafnium‐Cyclopentadienyl Precursors
O'Kane, R., Gaskell, J., Jones, A. C., Chalker, P. R., Black, K., Werner, M., . . . Odedra, R. (2007). Growth of HfO<sub>2</sub> by Liquid Injection MOCVD and ALD Using New Hafnium‐Cyclopentadienyl Precursors. Chemical Vapor Deposition, 13(11), 609-617. doi:10.1002/cvde.200706589
Molecular design of improved precursors for the MOCVD of oxides used in microelectronics
Jones, A. C., Aspinall, H. C., & Chalker, P. R. (2007). Molecular design of improved precursors for the MOCVD of oxides used in microelectronics. SURFACE & COATINGS TECHNOLOGY, 201(22-23), 9046-9054. doi:10.1016/j.surfcoat.2007.04.118
Deposition of lanthanum zirconium oxide high-κ films by liquid injection atomic layer deposition
Gaskell, J. M., Jones, A. C., Aspinall, H. C., Taylor, S., Taechakumput, P., Chalker, P. R., . . . Odedra, R. (2007). Deposition of lanthanum zirconium oxide high-κ films by liquid injection atomic layer deposition. APPLIED PHYSICS LETTERS, 91(11). doi:10.1063/1.2784956
Deposition of Pr- and Nd-aluminate by liquid injection MOCVD and ALD using single-source heterometallic alkoxide precursors
Gaskell, J. M., Przybylak, S., Jones, A. C., Aspinall, H. C., Chalker, P. R., Black, K., . . . Taylor, S. (2007). Deposition of Pr- and Nd-aluminate by liquid injection MOCVD and ALD using single-source heterometallic alkoxide precursors. CHEMISTRY OF MATERIALS, 19(19), 4796-4803. doi:10.1021/cm0707556
Precursors for MOCVD and ALD of rare earth oxides-complexes of the early lanthanides with a donor-functionalized alkoxide ligand
Aspinall, H. C., Bickley, J. F., Gaskell, J. M., Jones, A. C., Labat, G., Chalker, P. R., & Williams, P. A. (2007). Precursors for MOCVD and ALD of rare earth oxides-complexes of the early lanthanides with a donor-functionalized alkoxide ligand. INORGANIC CHEMISTRY, 46(15), 5852-5860. doi:10.1021/ic061382y
Deposition of lanthanum zirconium oxide high-kappa films by liquid injection atomic layer deposition
Gaskell, J. M., Jones, A. C., Aspinall, H. C., Taylor, S., Taechakumput, P., Chalker, P. R., . . . Odedra, R. (2007). Deposition of lanthanum zirconium oxide high-kappa films by liquid injection atomic layer deposition. Applied Physics Letters, 91(11), 112912.
Requirements of precursors for MOCVD and ALD of rare earth oxides
Aspinall, H. C. (2007). Requirements of precursors for MOCVD and ALD of rare earth oxides. Topics in Applied Physics, 106, 53-72.
2006
Liquid injection ALD and MOCVD of lanthanum aluminate using a bimetallic alkoxide precursor
Gaskell, J. M., Jones, A. C., Aspinall, H. C., Przybylak, S., Chalker, P. R., Black, K., . . . Critchlow, G. W. (2006). Liquid injection ALD and MOCVD of lanthanum aluminate using a bimetallic alkoxide precursor. JOURNAL OF MATERIALS CHEMISTRY, 16(39), 3854-3860. doi:10.1039/b609129f
Atomic Layer Deposition and Properties of Lanthanum Oxide and Lanthanum‐Aluminum Oxide Films
Kukli, K., Ritala, M., Pore, V., Leskelä, M., Sajavaara, T., Hegde, R. I., . . . Aspinall, H. C. (2006). Atomic Layer Deposition and Properties of Lanthanum Oxide and Lanthanum‐Aluminum Oxide Films. Chemical Vapor Deposition, 12(2-3), 158-164. doi:10.1002/cvde.200506388
MOCVD and ALD of high-<i>κ</i> dielectric oxides using alkoxide precursors
Jones, A. C., Aspinall, H. C., Chalker, P. R., Potter, R. J., Manning, T. D., Loo, Y. F., . . . Smith, L. M. (2006). MOCVD and ALD of high-<i>κ</i> dielectric oxides using alkoxide precursors. CHEMICAL VAPOR DEPOSITION, 12(2-3), 83-98. doi:10.1002/cvde.200500023
2005
Deposition of LaAlO<sub>3</sub> films by liquid injection MOCVD using a new [La-Al] single source alkoxide precursor
Manning, T. D., Loo, Y. F., Jones, A. C., Aspinall, H. C., Chalker, P. R., Bickley, J. F., . . . Critchlow, G. W. (2005). Deposition of LaAlO<sub>3</sub> films by liquid injection MOCVD using a new [La-Al] single source alkoxide precursor. JOURNAL OF MATERIALS CHEMISTRY, 15(33), 3384-3387. doi:10.1039/b507004j
doi:10.1021/om050197
Deposition of HfO<sub>2</sub> films by liquid injection MOCVD using a new monomeric alkoxide precursor, [Hf(dmop)<sub>4</sub>]
Loo, Y. F., O'Kane, R., Jones, A. C., Aspinall, H. C., Potter, R. J., Chalker, P. R., . . . Smith, L. M. (2005). Deposition of HfO<sub>2</sub> films by liquid injection MOCVD using a new monomeric alkoxide precursor, [Hf(dmop)<sub>4</sub>]. CHEMICAL VAPOR DEPOSITION, 11(6-7), 299-305. doi:10.1002/cvde.200506384
Lanthanide pybox complexes as catalysts for enantioselective silylcyanation of aldehydes
Aspinall, H. C., Bickley, J. F., Greeves, N., Kelly, R. V., & Smith, P. M. (2005). Lanthanide pybox complexes as catalysts for enantioselective silylcyanation of aldehydes. ORGANOMETALLICS, 24(14), 3458-3467. doi:10.1021/om050197+
Deposition of HfO<sub>2</sub> and ZrO<sub>2</sub> films by liquid injection MOCVD using new monomeric alkoxide precursors
Loo, Y. F., O'Kane, R., Jones, A. C., Aspinall, H. C., Potter, R. J., Chalker, P. R., . . . Smith, L. M. (2005). Deposition of HfO<sub>2</sub> and ZrO<sub>2</sub> films by liquid injection MOCVD using new monomeric alkoxide precursors. JOURNAL OF MATERIALS CHEMISTRY, 15(19), 1896-1902. doi:10.1039/b417389a
Samarium diiodide-catalyzed diastereoselective pinacol couplings
Aspinall, H. C., Greeves, N., & Valla, C. (2005). Samarium diiodide-catalyzed diastereoselective pinacol couplings. ORGANIC LETTERS, 7(10), 1919-1922. doi:10.1021/ol050256f
Recent developments in the MOCVD and ALD of rare earth oxides and silicates
Jones, A. C., Aspinall, H. C., Chalker, P. R., Potter, R. J., Kukli, K., Rahtu, A., . . . Leskelä, M. (2005). Recent developments in the MOCVD and ALD of rare earth oxides and silicates. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 118(1-3), 97-104. doi:10.1016/j.mseb.2004.12.081
Deposition of HfO<sub>2</sub>, Gd<sub>2</sub>O<sub>3</sub> and PrO<i><sub>x</sub></i> by liquid injection ALD techniques
Potter, R. J., Chalker, P. R., Manning, T. D., Aspinall, H. C., Loo, Y. F., Jones, A. C., . . . Schumacher, M. (2005). Deposition of HfO<sub>2</sub>, Gd<sub>2</sub>O<sub>3</sub> and PrO<i><sub>x</sub></i> by liquid injection ALD techniques. CHEMICAL VAPOR DEPOSITION, 11(3), 159-169. doi:10.1002/cvde.200406348
2004
Growth of gadolinium oxide thin films by liquid injection MOCVD using a new gadolinium alkoxide precursor
Aspinall, H. C., Gaskell, J. M., Loo, Y. F., Jones, A. C., Chalker, P. R., Potter, R. J., . . . Critchlow, G. W. (2004). Growth of gadolinium oxide thin films by liquid injection MOCVD using a new gadolinium alkoxide precursor. CHEMICAL VAPOR DEPOSITION, 10(6), 301-305. doi:10.1002/cvde.200306310
Growth of neodymium oxide thin films by liquid-injection MOCVD using a new neodymium alkoxide precursor
Loo, Y. F., Potter, R. L., Jones, A. C., Aspinall, H. C., Gaskell, J. M., Chalker, P. R., . . . Critchlow, G. W. (2004). Growth of neodymium oxide thin films by liquid-injection MOCVD using a new neodymium alkoxide precursor. CHEMICAL VAPOR DEPOSITION, 10(6), 306-310. doi:10.1002/cvde.200406313
Some recent developments in the MOCVD and ALD of high-κ dielectric oxides
Jones, A. C., Aspinall, H. C., Chalker, P. R., Potter, R. J., Kukli, K., Rahtu, A., . . . Leskelä, M. (2004). Some recent developments in the MOCVD and ALD of high-κ dielectric oxides. JOURNAL OF MATERIALS CHEMISTRY, 14(21), 3101-3112. doi:10.1039/b405525j
Evaluation of a Praseodymium Precursor for Atomic Layer Deposition of Oxide Dielectric Films
Kukli, K., Ritala, M., Pilvi, T., Sajavaara, T., Leskelä, M., Jones, A. C., . . . Tobin, P. J. (2004). Evaluation of a Praseodymium Precursor for Atomic Layer Deposition of Oxide Dielectric Films. Chemistry of Materials, 16(24), 5162-5168. doi:10.1021/cm0401793
Growth of praseodymium oxide and praseodymium silicate thin films by liquid injection MOCVD
Aspinall, H. C., Gaskell, J., Williams, P. A., Jones, A. C., Chalker, P. R., Marshall, P. A., . . . Critchlow, G. W. (2004). Growth of praseodymium oxide and praseodymium silicate thin films by liquid injection MOCVD. CHEMICAL VAPOR DEPOSITION, 10(2), 83-89. doi:10.1002/cvde.200306282
Growth of lanthanum oxide thin films by liquid injection MOCVD using a novel lanthanum alkoxide precursor
Aspinall, H. C., Gaskell, J., Williams, P. A., Jones, A. C., Chalker, P. R., Marshall, P. A., . . . Critchlow, G. W. (2004). Growth of lanthanum oxide thin films by liquid injection MOCVD using a novel lanthanum alkoxide precursor. CHEMICAL VAPOR DEPOSITION, 10(1), 13-+. doi:10.1002/cvde.200304164
2003
Modular chiral polyether podands and their lanthanide complexes
Aspinall, H. C., Greeves, N., & McIver, E. G. (2003). Modular chiral polyether podands and their lanthanide complexes. TETRAHEDRON, 59(52), 10453-10463. doi:10.1016/j.tet.2003.06.008
Growth of Praseodymium Oxide Thin Films by Liquid Injection MOCVD using a Novel Praseodymium Alkoxide Precursor
Aspinall, H. C., Gaskell, J., Williams, P. A., Jones, A. C., Chalker, P. R., Marshall, P. A., . . . Critchlow, G. W. (2003). Growth of Praseodymium Oxide Thin Films by Liquid Injection MOCVD using a Novel Praseodymium Alkoxide Precursor. Advanced Materials, 15(20), 235-238.
Growth of praseodymium oxide thin films by liquid injection MOCVD using a novel praseodymium alkoxide precursor
Aspinall, H. C., Gaskell, J., Williams, P. A., Jones, A. C., Chalker, P. R., Marshall, P. A., . . . Critchlow, G. W. (2003). Growth of praseodymium oxide thin films by liquid injection MOCVD using a novel praseodymium alkoxide precursor. CHEMICAL VAPOR DEPOSITION, 9(5), 235-+. doi:10.1002/cvde.200304160
Growth of lanthanum silicate thin films by liquid injection MOCVD using tris[bis(trimethyisilyl)amido]lanthanum
Aspinall, H. C., Williams, P. A., Gaskell, J., Jones, A. C., Roberts, J. L., Smith, L. M., . . . Critchlow, G. W. (2003). Growth of lanthanum silicate thin films by liquid injection MOCVD using tris[bis(trimethyisilyl)amido]lanthanum. Advanced Materials, 15(1), 7-10.
Growth of lanthanum silicate thin films by liquid injection MOCVD using tris[bis(trimethylsilyl)amido]lanthanum
Aspinall, H. C., Williams, P. A., Gaskell, J., Jones, A. C., Roberts, J. L., Smith, L. M., . . . Critchlow, G. W. (2003). Growth of lanthanum silicate thin films by liquid injection MOCVD using tris[bis(trimethylsilyl)amido]lanthanum. CHEMICAL VAPOR DEPOSITION, 9(1), 7-+. doi:10.1002/cvde.200290009
2002
Chiral lanthanide complexes: coordination chemistry and applications.
Aspinall, H. C. (2002). Chiral lanthanide complexes: coordination chemistry and applications.. Chemical reviews, 102(6), 1807-1850. doi:10.1021/cr010288q
Defining effective chiral binding sites at lanthanides - highly enantioselective reagents and catalysts from binaphtholate and pybox ligands
Aspinall, H. C., & Greeves, N. (2002). Defining effective chiral binding sites at lanthanides - highly enantioselective reagents and catalysts from binaphtholate and pybox ligands. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 647(1-2), 151-157. doi:10.1016/S0022-328X(01)01370-5
Lanthanum triflate-catalysed allylation of aldehydes: crucial activation by benzoic acid
Aspinall, H. C., Bissett, J. S., Greeves, N., & Levin, D. (2002). Lanthanum triflate-catalysed allylation of aldehydes: crucial activation by benzoic acid. TETRAHEDRON LETTERS, 43(2), 319-321. doi:10.1016/S0040-4039(01)02115-3
Three component synthesis of homoallylic amines. Efficient catalysis by lanthanum triflate/benzoic acid
Aspinall, H. C., Bissett, J. S., Greeves, N., & Levin, D. (2002). Three component synthesis of homoallylic amines. Efficient catalysis by lanthanum triflate/benzoic acid. TETRAHEDRON LETTERS, 43(2), 323-325. doi:10.1016/S0040-4039(01)02116-5
2001
'Chemistry of the f-block elements'
Aspinall, H. C. (2001). 'Chemistry of the f-block elements'. D. Phillips, P. O'Brien, & S. M. Roberts (Eds.), Amsterdam: Gordon and Breach.
2000
Pinwheel-shaped heterobimetallic lanthanide alkali metal binaphtholates: Ionic size matters!
Aspinall, H. C., Bickley, J. F., Dwyer, J. L. M., Greeves, N., Kelly, R. V., & Steiner, A. (2000). Pinwheel-shaped heterobimetallic lanthanide alkali metal binaphtholates: Ionic size matters!. ORGANOMETALLICS, 19(25), 5416-5423. doi:10.1021/om0006256
Lithium binaphtholates: Chiral chains and clusters
Aspinall, H. C., Bickley, J. F., Dwyer, J. L. M., Greeves, N., & Steiner, A. (2000). Lithium binaphtholates: Chiral chains and clusters. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 39(16), 2858-2861. doi:3.0.CO;2-T">10.1002/1521-3773(20000818)39:16<2858::AID-ANIE2858>3.0.CO;2-T
Lanthanide complexes with C<sub>2</sub> symmetric ligands for use in enantioselective organic synthesis
Aspinall, H. C., Dwyer, J. L. M., Greeves, N., & Smith, P. M. (2000). Lanthanide complexes with C<sub>2</sub> symmetric ligands for use in enantioselective organic synthesis. JOURNAL OF ALLOYS AND COMPOUNDS, 303, 173-177. doi:10.1016/S0925-8388(00)00661-7
'Lanthanide silsesquioxanes: Monomeric and functionalised complexes'
Annand, J., & Aspinall, H. C. (2000). 'Lanthanide silsesquioxanes: Monomeric and functionalised complexes'. Journal of the Chemical Society Dalton Transactions, (12), 1867-1871.
1999
Novel heterometallic lanthanide silsesquioxane
Annand, J., Aspinall, H. C., & Steiner, A. (1999). Novel heterometallic lanthanide silsesquioxane. INORGANIC CHEMISTRY, 38(17), 3941-+. doi:10.1021/ic990208p
Li<sub>3</sub>[Ln(binol)<sub>3</sub>]•6THF:: New anhydrous lithium lanthanide binaphtholates and their use in enantioselective alkyl addition to aldehydes
Aspinall, H. C., Dwyer, J. L. M., Greeves, N., & Steiner, A. (1999). Li<sub>3</sub>[Ln(binol)<sub>3</sub>]•6THF:: New anhydrous lithium lanthanide binaphtholates and their use in enantioselective alkyl addition to aldehydes. ORGANOMETALLICS, 18(8), 1366-1368. doi:10.1021/om981011s
Catalytic, asymmetric cyanohydrin synthesis mediated by lanthanide(III) chloride pybox complexes
Aspinall, H. C., Greeves, N., & Smith, P. M. (1999). Catalytic, asymmetric cyanohydrin synthesis mediated by lanthanide(III) chloride pybox complexes. TETRAHEDRON LETTERS, 40(9), 1763-1766. doi:10.1016/S0040-4039(98)02685-9
'Lighter flints and lminescence: Some chemistry of the not so rare earths'
Aspinall, H. C. (1999). 'Lighter flints and lminescence: Some chemistry of the not so rare earths'. Chemistry Review, 8(5), 2-6.
1998
Ytterbium triflate catalysed allylation of aldehydes: An unusual benzoic acid induced acceleration
Aspinall, H. C., Greeves, N., & McIver, E. G. (1998). Ytterbium triflate catalysed allylation of aldehydes: An unusual benzoic acid induced acceleration. TETRAHEDRON LETTERS, 39(50), 9283-9286. doi:10.1016/S0040-4039(98)02086-3
Lanthanide Tris(<i>tert</i>-butylthiolates) and the Crystal Structure of [Yb(SBu<sup>t</sup>)<sub>2</sub>(μ<sub>2</sub>-SBu<sup>t</sup>)(Bipy)]<sub>2</sub>
Aspinall, H. C., Cunningham, S. A., Maestro, P., & Macaudiere, P. (1998). Lanthanide Tris(<i>tert</i>-butylthiolates) and the Crystal Structure of [Yb(SBu<sup>t</sup>)<sub>2</sub>(μ<sub>2</sub>-SBu<sup>t</sup>)(Bipy)]<sub>2</sub>. Inorganic Chemistry, 37(20), 5396-5398. doi:10.1021/ic9800684
New homochiral lanthanide(III) triflates in Lewis acid catalysis
Aspinall, H. C., Greeves, N., & McIver, E. G. (1998). New homochiral lanthanide(III) triflates in Lewis acid catalysis. JOURNAL OF ALLOYS AND COMPOUNDS, 275, 773-776. doi:10.1016/S0925-8388(98)00438-1
Solubilized lanthanide triflates:: Lewis acid catalysis by polyether and poly(ethylene glycol) complexes of Ln(OTf)<sub>3</sub>
Aspinall, H. C., Dwyer, J. L. M., Greeves, N., McIver, E. G., & Woolley, J. C. (1998). Solubilized lanthanide triflates:: Lewis acid catalysis by polyether and poly(ethylene glycol) complexes of Ln(OTf)<sub>3</sub>. ORGANOMETALLICS, 17(9), 1884-1888. doi:10.1021/om9709087
1997
An improved Williamson etherification of hindered alcohols promoted by 15-crown-5 and sodium hydride
Aspinall, H. C., Greeves, N., Lee, W. M., McIver, E. G., & Smith, P. M. (1997). An improved Williamson etherification of hindered alcohols promoted by 15-crown-5 and sodium hydride. TETRAHEDRON LETTERS, 38(26), 4679-4682. doi:10.1016/S0040-4039(97)00965-9
1996
Rare Earth Azatrane Chemistry: Facile Cleavage of THF To Give a Y(2)Li(3)O Cluster.
Aspinall, H. C., & Tillotson, M. R. (1996). Rare Earth Azatrane Chemistry: Facile Cleavage of THF To Give a Y(2)Li(3)O Cluster.. Inorganic chemistry, 35(8), 2163-2164. doi:10.1021/ic950674o
Convenient Preparation of Lanthanide Aryloxides from Lanthanide Nitrate Polyether Complexes and the Crystal Structure of [La(OC(6)H(3)Me(2)-2,6)(3)(MeO(CH(2)CH(2)O)(4)Me)].
Aspinall, H. C., & Williams, M. (1996). Convenient Preparation of Lanthanide Aryloxides from Lanthanide Nitrate Polyether Complexes and the Crystal Structure of [La(OC(6)H(3)Me(2)-2,6)(3)(MeO(CH(2)CH(2)O)(4)Me)].. Inorganic chemistry, 35(1), 255-257. doi:10.1021/ic9507629
1994
Four-coordinate lanthanide di-isopropylamides: [Li(THF)Ln(NiPr2)4] (Ln = La, Y, Yb)
Aspinall, H. C., & Tillotson, M. R. (1994). Four-coordinate lanthanide di-isopropylamides: [Li(THF)Ln(NiPr2)4] (Ln = La, Y, Yb). Polyhedron, 13(23), 3229-3234. doi:10.1016/s0277-5387(00)83385-9
YTTERBIUM TRIFLUOROMETHANESULFONATE [YB(OTF)(3)] AS A NOVEL CATALYST FOR THE ALLYLATION OF ALDEHYDES
ASPINALL, H. C., BROWNING, A. F., GREEVES, N., & RAVENSCROFT, P. (1994). YTTERBIUM TRIFLUOROMETHANESULFONATE [YB(OTF)(3)] AS A NOVEL CATALYST FOR THE ALLYLATION OF ALDEHYDES. TETRAHEDRON LETTERS, 35(26), 4639-4640. doi:10.1016/S0040-4039(00)60750-5