Publications
2015
Comment on "The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh<sub>4</sub>(CO)<sub>12</sub>] and [Rh<sub>6</sub>(CO)<sub>16</sub>]" by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D
Heaton, B. T., Grachova, E. V., Tunik, S. P., & Podkorytov, I. S. (2015). Comment on "The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh<sub>4</sub>(CO)<sub>12</sub>] and [Rh<sub>6</sub>(CO)<sub>16</sub>]" by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D. DALTON TRANSACTIONS, 44(37), 16611-16613. doi:10.1039/c5dt01099c
2012
High-Pressure In Situ NMR Methods for the Study of Reaction Kinetics in Homogeneous Catalysis
Torres, A., Perez, N. M., Overend, G., Hodge, N., Heaton, B. T., Iggo, J. A., . . . Gobby, D. (2012). High-Pressure In Situ NMR Methods for the Study of Reaction Kinetics in Homogeneous Catalysis. ACS CATALYSIS, 2(11), 2281-2289. doi:10.1021/cs300439n
2011
The inter-conversions of platinum carbonyl dianions [Pt3(CO)6]n2- (n = 2-5) in THF and acetonitrile. A combined in situ FTIR specstrocopic and BTEM study leading to the characterization of the new [H4-xPt15(CO)19]x- (x = 3, 4) cluster
Heaton, B. T., Gao, F., Li, C., Zachini, S., Zarra, S., Longoni, G., & Garland, M. (2011). The inter-conversions of platinum carbonyl dianions [Pt3(CO)6]n2- (n = 2-5) in THF and acetonitrile. A combined in situ FTIR specstrocopic and BTEM study leading to the characterization of the new [H4-xPt15(CO)19]x- (x = 3, 4) cluster. Dalton Transactions, (40), 5002-5008.
2010
The synthesis of, and characterization of the dynamic processes occurring in Pd(II) chelate complexes of 2-pyridyldiphenylphosphine
Liu, J., Jacob, C., Sheridan, K. J., Al-Mosule, F., Heaton, B. T., Iggo, J. A., . . . Steiner, A. (2010). The synthesis of, and characterization of the dynamic processes occurring in Pd(II) chelate complexes of 2-pyridyldiphenylphosphine. DALTON TRANSACTIONS, 39(34), 7921-7935. doi:10.1039/b918162h
A rare example of a di-cationic hydrido carbonyl tetra-nuclear cluster, [H<sub>2</sub>Rh<sub>2</sub>Pt<sub>2</sub>(CO)<sub>7</sub>(PPh<sub>3</sub>)<sub>3</sub>]<SUP>2+</SUP>
Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Ponomarenko, V. I., Selivanov, S. I., & Tunik, S. P. (2010). A rare example of a di-cationic hydrido carbonyl tetra-nuclear cluster, [H<sub>2</sub>Rh<sub>2</sub>Pt<sub>2</sub>(CO)<sub>7</sub>(PPh<sub>3</sub>)<sub>3</sub>]<SUP>2+</SUP>. INORGANICA CHIMICA ACTA, 363(3), 549-554. doi:10.1016/j.ica.2009.03.045
2009
The loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anionsThe loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anions
Heaton, B. T., Iggo, J. A., Femoni, C., Iapalucci, M. C., Longoni, G., Tiozzo, C., . . . Li, C. (2009). The loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anionsThe loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anions. Dalton Transactions, 2217-2223.
2008
Multinuclear NMR studies of the products resulting from the reaction of pyridine or 2,2′-bipyridine with [Rh<sub>4</sub>(CO)<sub>12</sub>]
Bradd, K. J., Heaton, B. T., Iggo, J. A., Jacob, C., Sampanthar, J. T., & Zacchini, S. (2008). Multinuclear NMR studies of the products resulting from the reaction of pyridine or 2,2′-bipyridine with [Rh<sub>4</sub>(CO)<sub>12</sub>]. DALTON TRANSACTIONS, (5), 685-690. doi:10.1039/b715139j
The reaction of mixtures of [Rh<sub>4</sub>(CO)<sub>12</sub>] and triphenylphosphite with carbon monoxide or syngas as studied by high-resolution, high-pressure NMR spectroscopy
Overend, G., Iggo, J. A., Heaton, B. T., & Whyman, R. (2008). The reaction of mixtures of [Rh<sub>4</sub>(CO)<sub>12</sub>] and triphenylphosphite with carbon monoxide or syngas as studied by high-resolution, high-pressure NMR spectroscopy. MAGNETIC RESONANCE IN CHEMISTRY, 46, S100-S106. doi:10.1002/mrc.2314
2007
Sn-centred icosahedral Rh carbonyl clusters:: synthesis and structural characterization and <SUP>13</SUP>C-{<SUP>103</SUP>Rh} HMQC NMR studies
Femoni, C., Iapalucci, M. C., Longoni, G., Tiozzo, C., Zacchini, S., Heaton, B. T., & Iggo, J. A. (2007). Sn-centred icosahedral Rh carbonyl clusters:: synthesis and structural characterization and <SUP>13</SUP>C-{<SUP>103</SUP>Rh} HMQC NMR studies. DALTON TRANSACTIONS, (35), 3914-3923. doi:10.1039/b708469b
A novel heterobidentate chiral phosphine and its coordination chemistry in transition metal clusters
Tomashevskaya, M. M., Tunik, S. P., Podkorytov, I. S., Heaton, B. T., Iggo, J. A., Haukka, M., . . . Pursiainen, J. (2007). A novel heterobidentate chiral phosphine and its coordination chemistry in transition metal clusters. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(14), 2911-2923. doi:10.1016/j.jorganchem.2007.03.008
2006
CO fluxionality in Rh4(CO)12 and Rh6(CO)16
Heaton, B. T., Jacob, C., Podkorytov, I. S., & Tunik, S. P. (2006). CO fluxionality in Rh4(CO)12 and Rh6(CO)16. Inorganica Chimica Acta, 359(11), 3557-3564. doi:10.1016/j.ica.2005.12.002
The mechanism of the hydroalkoxycarbonylation of ethene and alkene-CO copolymerization catalyzed by Pd<SUP>II</SUP>-diphosphine cations
Liu, J., Heaton, B. T., Iggo, J. A., Whyman, R., Bickley, J. F., & Steiner, A. (2006). The mechanism of the hydroalkoxycarbonylation of ethene and alkene-CO copolymerization catalyzed by Pd<SUP>II</SUP>-diphosphine cations. CHEMISTRY-A EUROPEAN JOURNAL, 12(16), 4417-4430. doi:10.1002/chem.200501398
2005
'Comparison of theoretical studies and experimental results in the oxidative addition of alkyl or aryl halides to metal complexes'
Heaton, B. T., Iggo, J. A., Jacob, C., Skylaris, C. K., & Whyman, R. (2005). 'Comparison of theoretical studies and experimental results in the oxidative addition of alkyl or aryl halides to metal complexes'. In ¿, 34th Inorganic Reaction Mechanisms Group Annual Meeting (pp. lecture). Liverpool: RSC.
Catalytic mechanisms from spectroscopic measurements
Heaton, B. T. (Ed.) (2005). Catalytic mechanisms from spectroscopic measurements. Weinheim, Germany: Wiley-VCH.
2004
The complete delineation of the initiation, propagation, and termination steps of the carbomethoxy cycle for the carboalkoxylation of ethene by Pd-diphosphane catalysts
Liu, J. K., Heaton, B. T., Iggo, J. A., & Whyman, R. (2004). The complete delineation of the initiation, propagation, and termination steps of the carbomethoxy cycle for the carboalkoxylation of ethene by Pd-diphosphane catalysts. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43(1), 90-94. doi:10.1002/anie.200352369
Synthesis and structural characterization of two novel heterometallic clusters:: [Rh<sub>4</sub>Pt<sub>2</sub>(CO)<sub>11</sub>(dppm)<sub>2</sub>] and [Ru<sub>2</sub>Rh<sub>2</sub>Pt<sub>2</sub>(CO)<sub>12</sub>(dppm)<sub>2</sub>]
Koshevoy, I. O., Grachova, E. V., Tunik, S. P., Haukka, M., Pakkanen, T. A., Heaton, B. T., . . . Podkorytov, I. S. (2004). Synthesis and structural characterization of two novel heterometallic clusters:: [Rh<sub>4</sub>Pt<sub>2</sub>(CO)<sub>11</sub>(dppm)<sub>2</sub>] and [Ru<sub>2</sub>Rh<sub>2</sub>Pt<sub>2</sub>(CO)<sub>12</sub>(dppm)<sub>2</sub>]. DALTON TRANSACTIONS, (22), 3893-3899. doi:10.1039/b410216a
Methanolysis of acyl-Pd(II) complexes relevant to CO/ethene coupling reactions
Liu, J. K., Heaton, B. T., Iggo, J. A., & Whyman, R. (2004). Methanolysis of acyl-Pd(II) complexes relevant to CO/ethene coupling reactions. CHEMICAL COMMUNICATIONS, (11), 1326-1327. doi:10.1039/b402275k
“An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.”
Sheridan, K. J., Heaton, B. T., Iggo, J. A., Jacob, C., & Whyman, R. (2004). “An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.”. In A-DCOCC (Ed.), 5th Anglo-Dutch Conference on Organometallic Chemistry and Catalysis (pp. Pzz). Cardiff: A-DCOCC.
"Methanolysis of Acylpalladium (II) complexes relevant to CO/Ethene coupling reaction"
Liu, J., Heaton, B. T., Iggo, J. A., & Whyman, R. (2004). "Methanolysis of Acylpalladium (II) complexes relevant to CO/Ethene coupling reaction". In A-DCOCC (Ed.), 5th Anglo-Dutch Conference on Organometallic Chemistry and Catalysis (pp. Pyy). Cardiff: A-DCOCC.
174."The Application of HMQC Spectroscopy to the Observation of the Metal resonance in polymetallic Compounds; the Effect of Multiple-Metal Spin Transitions"
Heaton, B. T., Iggo, J. A., Podkorytov, I., & Tunik, S. P. (2004). 174."The Application of HMQC Spectroscopy to the Observation of the Metal resonance in polymetallic Compounds; the Effect of Multiple-Metal Spin Transitions". Magnetic Resonance in Chemistry, 769-775.
2003
The structure and dynamic behaviour of disubstituted derivatives of [Rh<sub>6</sub>(CO)<sub>16</sub>] containing bidentate phosphorus ligands
Farrar, D. H., Grachova, E. V., Haukka, M., Heaton, B. T., Iggo, J. A., Pakkanen, T. A., . . . Tunik, S. P. (2003). The structure and dynamic behaviour of disubstituted derivatives of [Rh<sub>6</sub>(CO)<sub>16</sub>] containing bidentate phosphorus ligands. INORGANICA CHIMICA ACTA, 354, 11-20. doi:10.1016/S0020-1693(03)00315-3
Promotional effects of water and N-containing bases on Co-catalysed methoxycarbonylation of oct-1-ene
Jacob, C., Heaton, B. T., Iggo, J. A., & Whyman, R. (2003). Promotional effects of water and N-containing bases on Co-catalysed methoxycarbonylation of oct-1-ene. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 204, 149-155. doi:10.1016/S1381-1169(03)00294-2
Palladium(II)/β-diketonate complexes containing the enolates of <i>N</i>-acetyl-3-acyltetramic acids -: Crystal structure of the Lewis base adduct, [Pd(py)<sub>4</sub>](abta)<sub>2</sub>
Gavrielatos, E., Athanasellis, G., Heaton, B. T., Steiner, A., Bickley, J. F., Igglessi-Markopoulou, O., & Markopoulos, J. (2003). Palladium(II)/β-diketonate complexes containing the enolates of <i>N</i>-acetyl-3-acyltetramic acids -: Crystal structure of the Lewis base adduct, [Pd(py)<sub>4</sub>](abta)<sub>2</sub>. INORGANICA CHIMICA ACTA, 351, 21-26. doi:10.1016/S0020-1693(03)00196-8
Rhodium complexes containing the hybrid P,O ligand PPh2NHC(O)Me or its anion, [PPh2NC(O)Me]–Dedicated to Dr Jean-Marie Basset on the occasion of his 60th birthday, with our congratulations and best wishes.
Braunstein, P., Heaton, B. T., Jacob, C., Manzi, L., & Morise, X. (2003). Rhodium complexes containing the hybrid P,O ligand PPh2NHC(O)Me or its anion, [PPh2NC(O)Me]–Dedicated to Dr Jean-Marie Basset on the occasion of his 60th birthday, with our congratulations and best wishes.. Dalton Transactions, (7), 1396-1401. doi:10.1039/b208735a
“Spectroscopic studies on catalytic intermediates involved in the methoxycarbonylation of ethylene.”
Pepin, A., Eastham, G. R., Heaton, B. T., Iggo, J. A., & Whyman, R. (2003). “Spectroscopic studies on catalytic intermediates involved in the methoxycarbonylation of ethylene.”. In RSC (Ed.), Dalton Discussion 6: Organometallic Chemistry and Catalysis (pp. Pxx). York: RSC.
"Elucidation of palladium carbomethoxy catalytic cycle in the Pd-catalysed CO/ ethylene reaction"
Liu, J., Heaton, B. T., Iggo, J. A., & Whyman, R. (2003). "Elucidation of palladium carbomethoxy catalytic cycle in the Pd-catalysed CO/ ethylene reaction". In RSC (Ed.), Dalton Discussion 6: Organometallic Chemistry and Catalysis (pp. Pxx). York: RSC.
"NMR, X-ray Crystallographic Studies and DFT Calculations on Products resulting from the Oxidative Addition of Rhodium(I)/beta-diketonate Complexes with Methyl Iodide."
Bickley, J., Davis, J., Gray, J., Heaton, B. T., Iggo, J. A., Jacob, J., . . . Whyman, R. (2003). "NMR, X-ray Crystallographic Studies and DFT Calculations on Products resulting from the Oxidative Addition of Rhodium(I)/beta-diketonate Complexes with Methyl Iodide.". In A. L. Petrou (Ed.), Inorganic Mechanisms 2003 (pp. L 29). Athens, Greece: RSC/University oif Athens.
"The Structure and dynamic behaviour of disubstituted derivatives Rh6(CO)16 containing bidentate phosphorus ligands. Structure and dynamic behaviour"
Farrar, D. H., Grachova, E. V., Haukka, M., Heaton, B. T., Iggo, J. A., Nordlander, E., . . . Tunik, S. P. (2003). "The Structure and dynamic behaviour of disubstituted derivatives Rh6(CO)16 containing bidentate phosphorus ligands. Structure and dynamic behaviour". Inorganica Chimica Acta, 354, 11-20.
Elucidation of Catalytic Mechanisms from NMR measurements under ambient and high pressures of gas
Heaton, B. T. (2003). Elucidation of Catalytic Mechanisms from NMR measurements under ambient and high pressures of gas. In R. Society of Chemistry (Ed.), Royal Society of Chemistry, Dalton Division (pp. 1-4). Nottingham: Royal Society of Chemistry, Dalton Division.
Elucidation of Transition Metal Catalysed Reactions from in situ NMR measurements
Heaton, B. T. (2003). Elucidation of Transition Metal Catalysed Reactions from in situ NMR measurements. In F. of European Chemical Society (Ed.), XVth Conference on Organometallic Chemistry (pp. PL 06). Zurich: Federation of European Chemical Society.
The structure and dynamic behaviour of disubstituted derivatives of [Rh6(CO)16] containing heterobidentate bridging phosphine ligands
Grachova, E. V., Haukka, M., Heaton, B. T., Nordlander, E., Pakkanen, T. A., Podkorytov, I. S., & Tunik, S. P. (2003). The structure and dynamic behaviour of disubstituted derivatives of [Rh6(CO)16] containing heterobidentate bridging phosphine ligands. Dalton Transactions, (12), 2468. doi:10.1039/b211790h
¿An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.¿
Sheridan, K. J., Heaton, B. T., Iggo, J. A., Jacob, C., & Whyman, R. (2003). ¿An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.¿. In RSC (Ed.), Dalton Discussion 6: Organometallic Chemistry and Catalysis (pp. Pxx). York: RSC.
2002
The effect of mechanistic pathway on activity in the Pd and Pt catalysed methoxycarbonylation of ethene
Wolowska, J., Eastham, G. R., Heaton, B. T., Iggo, J. A., Jacob, C., & Whyman, R. (2002). The effect of mechanistic pathway on activity in the Pd and Pt catalysed methoxycarbonylation of ethene. CHEMICAL COMMUNICATIONS, (23), 2784-2785. doi:10.1039/b208450c
Polymeric anionic networks using dibromine as a crosslinker; the preparation and crystal structure of [(C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N]<sub>2</sub>[Pt<sub>2</sub>Br<sub>10</sub>]•(Br<sub>2</sub>)<sub>7</sub> and [(C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N]<sub>2</sub>[PtBr<sub>4</sub>Cl<sub>2</sub>]•(Br<sub>2</sub>)<sub>6</sub>
Berkei, M., Bickley, J. F., Heaton, B. T., & Steiner, A. (2002). Polymeric anionic networks using dibromine as a crosslinker; the preparation and crystal structure of [(C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N]<sub>2</sub>[Pt<sub>2</sub>Br<sub>10</sub>]•(Br<sub>2</sub>)<sub>7</sub> and [(C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N]<sub>2</sub>[PtBr<sub>4</sub>Cl<sub>2</sub>]•(Br<sub>2</sub>)<sub>6</sub>. CHEMICAL COMMUNICATIONS, (18), 2180-2181. doi:10.1039/b205712n
Synthesis and reactivity of palladium hydrido-solvento complexes, including a key intermediate in the catalytic methoxycarbonylation of ethene to methyl propanoate
Clegg, W., Eastham, G. R., Elsegood, M. R. J., Heaton, B. T., Iggo, J. A., Tooze, R. P., . . . Zacchini, S. (2002). Synthesis and reactivity of palladium hydrido-solvento complexes, including a key intermediate in the catalytic methoxycarbonylation of ethene to methyl propanoate. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (17), 3300-3308. doi:10.1039/b202372p
Characterization and dynamics of [Pd(L-L)H(solv)]<SUP>+</SUP>, [Pd(L-L)(CH<sub>2</sub>CH<sub>3</sub>)]<SUP>+</SUP>, and [Pd(L-L)(C(O)Et)(THF)]<SUP>+</SUP> (L-L=1,2-(CH<sub>2</sub>PBu<SUP>t</SUP><sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>):: Key intermediates in the catalytic methoxycarbonylation of ethene to methylpropanoate
Clegg, W., Eastham, G. R., Elsegood, M. R. J., Heaton, B. T., Iggo, J. A., Tooze, R. P., . . . Zacchini, S. (2002). Characterization and dynamics of [Pd(L-L)H(solv)]<SUP>+</SUP>, [Pd(L-L)(CH<sub>2</sub>CH<sub>3</sub>)]<SUP>+</SUP>, and [Pd(L-L)(C(O)Et)(THF)]<SUP>+</SUP> (L-L=1,2-(CH<sub>2</sub>PBu<SUP>t</SUP><sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub>):: Key intermediates in the catalytic methoxycarbonylation of ethene to methylpropanoate. ORGANOMETALLICS, 21(9), 1832-1840. doi:10.1021/om010938g
Carbon monoxide activation in homogeneously catalysed reactions: the nature and roles of catalytic promoters
Whyman, R., Wright, A. P., Iggo, J. A., & Heaton, B. T. (2002). Carbon monoxide activation in homogeneously catalysed reactions: the nature and roles of catalytic promoters. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (5), 771-777. doi:10.1039/b107940a
"Carbon Monoxide Activation in Homogeneously Catalysed Reactions: the Nature and the Roles of the Catalytic Promoters"
Whyman, R., Wright, A. P., Iggo, J. A., & Heaton, B. T. (2002). "Carbon Monoxide Activation in Homogeneously Catalysed Reactions: the Nature and the Roles of the Catalytic Promoters". Journal of the Chemical Society, Dalton Transactions, 771-777.
"Crystal Structure of Tetrabutylammonium Carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)]"
Berkei, M., Bickley, J. F., & Heaton, B. T. (2002). "Crystal Structure of Tetrabutylammonium Carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)]". Zeitschrift fur natuforschung, 57 b(6), 610-614.
"NMR Studies of Metal-Carbonyl/PhosphineComplexes/Clusters"
Heaton, B. T. (2002). "NMR Studies of Metal-Carbonyl/PhosphineComplexes/Clusters". In G. J. Leigh, & N. Winterton (Eds.), Modern Coordination Chemistry-the Legacy of Joseph Chatt (pp. 89-100). Cambridge: Royal Society of Chemistry.
Elucidation of Catalytic Mechanisms from NMR measurements under pressures of gas
Eastham, G. R., Heaton, B. T., Iggo, J. A., Tooze, R. P., Whyman, R., & Zacchini, S. (2002). Elucidation of Catalytic Mechanisms from NMR measurements under pressures of gas. In I. Conference on Coordination Chemistry (Ed.), XXXV International Conference on Coordination Chemistry (pp. 78). Heidelberg: University of Heidelberg/GDCh.
¿Characterisation of new platinum complexes as possible intermediates in the methoxycarbonylation of ethane¿
Eastham, G. R., Heaton, B. T., Iggo, J. A., Whyman, R., & Wolowska, J. (2002). ¿Characterisation of new platinum complexes as possible intermediates in the methoxycarbonylation of ethane¿. In ISHC (Ed.), 13th International Symposium on Homogeneous Catalysis (pp. P246). Tarragona: ISHC.
¿Elucidation of the mechanism of Pd catalyzed methoxycarbonylation¿
Eastham, G. R., Heaton, B. T., Iggo, J. A., Liu, J., Tooze, R. P., Whyman, R., & Zacchini, S. (2002). ¿Elucidation of the mechanism of Pd catalyzed methoxycarbonylation¿. In ISHC (Ed.), 13th International Symposium on Homogeneous Catalysis (pp. P219). Tarragona: ISHC.
¿Toward integrating kinetic and structural NMR studies in homogeneous catalysis¿
Heaton, B. T., Iggo, J. A., Molina Perez, N., Muir, M., & Whyman, R. (2002). ¿Toward integrating kinetic and structural NMR studies in homogeneous catalysis¿. In ISHC (Ed.), 13th International Symposium on Homogeneous Catalysis (pp. P215). Tarragona: ISHC.
2001
Stereochemical nonrigidity of [Rh<sub>6</sub>(CO)<sub>15</sub>L] clusters in solution
Grachova, E. V., Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (2001). Stereochemical nonrigidity of [Rh<sub>6</sub>(CO)<sub>15</sub>L] clusters in solution. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (22), 3303-3311. doi:10.1039/b101962g
Copper(II), cobalt(II), nickel(II) and zinc(II) complexes containing the enolate of <i>N</i>-acetyl-3-butanoyltetramic acid (Habta) and its phenylhydrazone derivative analogues.: Crystal structure of [Cu(abta)<sub>2</sub>(py)<sub>2</sub>]•2H<sub>2</sub>O
Gavrielatos, E., Mitsos, C., Athanasellis, G., Heaton, B. T., Steiner, A., Bickley, J. F., . . . Markopoulos, J. (2001). Copper(II), cobalt(II), nickel(II) and zinc(II) complexes containing the enolate of <i>N</i>-acetyl-3-butanoyltetramic acid (Habta) and its phenylhydrazone derivative analogues.: Crystal structure of [Cu(abta)<sub>2</sub>(py)<sub>2</sub>]•2H<sub>2</sub>O. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (5), 639-644. doi:10.1039/b007252o
1-and 2-D NMR studies on [Rh<sub>6</sub>C(CO)<sub>14</sub>(PPh<sub>3</sub>)]<SUP>2-1</SUP>
Sabounchei, J. S. Z., Heaton, B. T., Iggo, J. A., Jacob, C., & Podkorytov, I. S. (2001). 1-and 2-D NMR studies on [Rh<sub>6</sub>C(CO)<sub>14</sub>(PPh<sub>3</sub>)]<SUP>2-1</SUP>. JOURNAL OF CLUSTER SCIENCE, 12(1), 339-348. doi:10.1023/A:1016651819071
Mechanistic studies of the hydroformylation of 1-alkenes using a monodentate phosphorus diamide ligand
van der Slot, S. C., Kamer, P. C. J., van Leeuwen, P. W. N. M., Iggo, J. A., & Heaton, B. T. (2001). Mechanistic studies of the hydroformylation of 1-alkenes using a monodentate phosphorus diamide ligand. ORGANOMETALLICS, 20(3), 430-441. doi:10.1021/om000785h
"Rhodium Complexes Containing O-bonded NHxMe2-xCHO (x = 0, 1, 2); X-ray Structure of [Rh(PPh3)3(OCHNHMe)]ClO4"
Sabounchei, J. S., Heaton, B. T., Jacob, C., Jones, C., Olsson, A., Smith, A. K., & Kloo, L. (2001). "Rhodium Complexes Containing O-bonded NHxMe2-xCHO (x = 0, 1, 2); X-ray Structure of [Rh(PPh3)3(OCHNHMe)]ClO4". Helvetica Chimica Aca, 84(10), 3075-3084.
"Stereochemical nonrigidity of [Rh6(CO)15L] clusters in solution"
Grachova, E. V., Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (2001). "Stereochemical nonrigidity of [Rh6(CO)15L] clusters in solution". Journal of the Chemical Society, Dalton Transactions, (22), 3303-3311.
1-and 2-D NMR studies on [Rh6C(CO)14(PPh3)]2-
Sabounchei, J. S. Z., Heaton, B. T., Iggo, J. A., Jacob, C., & Podkorytov, I. S. (2001). 1-and 2-D NMR studies on [Rh6C(CO)14(PPh3)]2-. Journal of Cluster Science, 12(1), 339-348.
Acetic acid via methanol carbonylation: Ruthenium promotion of the iridium catalyzed CATIVA process
Heaton, B. T., Iggo, J. A., Whyman, R., & Wright, A. P. (2001). Acetic acid via methanol carbonylation: Ruthenium promotion of the iridium catalyzed CATIVA process. Abstracts of Papers of the American Chemical Society, 222, 44-CATL.
2000
Hexacarbonyldiplatinum(I). Synthesis, Spectroscopy, and Density Functional Calculation of the First Homoleptic, Dinuclear Platinum(I) Carbonyl Cation, [{Pt(CO)<sub>3</sub>}<sub>2</sub>]<sup>2+</sup>, Formed in Concentrated Sulfuric Acid
Xu, Q., Heaton, B. T., Jacob, C., Mogi, K., Ichihashi, Y., Souma, Y., . . . Eguchi, T. (2000). Hexacarbonyldiplatinum(I). Synthesis, Spectroscopy, and Density Functional Calculation of the First Homoleptic, Dinuclear Platinum(I) Carbonyl Cation, [{Pt(CO)<sub>3</sub>}<sub>2</sub>]<sup>2+</sup>, Formed in Concentrated Sulfuric Acid. Journal of the American Chemical Society, 122(29), 6862-6870. doi:10.1021/ja000716u
Synthesis and spectroscopic characterisation of <i>all</i> the intermediates in the Pd-catalysed methoxycarbonylation of ethene
Eastham, G. R., Heaton, B. T., Iggo, J. A., Tooze, R. P., Whyman, R., & Zacchini, S. (2000). Synthesis and spectroscopic characterisation of <i>all</i> the intermediates in the Pd-catalysed methoxycarbonylation of ethene. CHEMICAL COMMUNICATIONS, (7), 609-610. doi:10.1039/b001110j
"Spectroscopic Characterisation of the First Homoleptic, Dinuclear, Cationic Platinum(I) Carbonyl Complex [{Pt(CO)3}2]2+, Formed in Concentrated Sulfuric Acid"
Xu, Q., Souma, Y., Heaton, B. T., Jacob, C., & Kanamori, K. (2000). "Spectroscopic Characterisation of the First Homoleptic, Dinuclear, Cationic Platinum(I) Carbonyl Complex [{Pt(CO)3}2]2+, Formed in Concentrated Sulfuric Acid". Angewandte Chemie, International Edition, 39(1), 208-209.
"Synthesis and Spectroscopic Characterisation of all the Intermediates in the Pd-catalysed Methoxyarbonylation of Ethene"
Eastham, G. R., Heaton, B. T., Iggo, J. A., Tooze, R. P., Whyman, R., & Zacchini, S. (2000). "Synthesis and Spectroscopic Characterisation of all the Intermediates in the Pd-catalysed Methoxyarbonylation of Ethene". Journal of the Chemical Society, Chemical Communications, (7), 609-610.
1999
Multinuclear NMR Studies on Homo‐and Heterometallic Rhodium Clusters Containing 6 or More Metal Atoms
Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., & Tunik, S. P. (1999). Multinuclear NMR Studies on Homo‐and Heterometallic Rhodium Clusters Containing 6 or More Metal Atoms. In Unknown Book (pp. 960-1000). Wiley. doi:10.1002/9783527618316.ch3c
Observation of triple-quantum effects in the HMQC spectra of substituted derivatives of Rh<sub>6</sub>(CO)<sub>16</sub>
Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (1999). Observation of triple-quantum effects in the HMQC spectra of substituted derivatives of Rh<sub>6</sub>(CO)<sub>16</sub>. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (12), 1917-1919. doi:10.1039/a903513c
Synthesis and structural characterisation of the mixed metal clusters [Rh<sub>2</sub>Pt<sub>3</sub>(μ-CO)<sub>5</sub>(CO)<sub>4</sub>(PPh<sub>3</sub>)<sub>3</sub>] and [Rh<sub>2</sub>Pt<sub>2</sub>(μ-CO)<sub>3</sub>-(CO)<sub>4</sub>(PPh<sub>3</sub>)<sub>3</sub>];: crystal structure of [Rh<sub>2</sub>Pt<sub>3</sub>(μ-CO)<sub>5</sub>(CO)<sub>4</sub>(PPh<sub>3</sub>)<sub>3</sub>]
Dolgushin, F. M., Grachova, E. V., Heaton, B. T., Iggo, J. A., Koshevoy, I. O., Podkorytov, I. S., . . . Yanovskii, A. I. (1999). Synthesis and structural characterisation of the mixed metal clusters [Rh<sub>2</sub>Pt<sub>3</sub>(μ-CO)<sub>5</sub>(CO)<sub>4</sub>(PPh<sub>3</sub>)<sub>3</sub>] and [Rh<sub>2</sub>Pt<sub>2</sub>(μ-CO)<sub>3</sub>-(CO)<sub>4</sub>(PPh<sub>3</sub>)<sub>3</sub>];: crystal structure of [Rh<sub>2</sub>Pt<sub>3</sub>(μ-CO)<sub>5</sub>(CO)<sub>4</sub>(PPh<sub>3</sub>)<sub>3</sub>]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (10), 1609-1614. doi:10.1039/a809118h
Oxidative addition of chlorinated solvents (<i>eg</i> CH<sub>2</sub>Cl<sub>2</sub> and CHCl<sub>3</sub>) with rhodium(I) complexes;: crystal structure of <i>mer</i>-[Rh(py)<sub>3</sub>(CH<sub>2</sub>Cl)Cl<sub>2</sub>]
Bradd, K. J., Heaton, B. T., Jacob, C., Sampanthar, J. T., & Steiner, A. (1999). Oxidative addition of chlorinated solvents (<i>eg</i> CH<sub>2</sub>Cl<sub>2</sub> and CHCl<sub>3</sub>) with rhodium(I) complexes;: crystal structure of <i>mer</i>-[Rh(py)<sub>3</sub>(CH<sub>2</sub>Cl)Cl<sub>2</sub>]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (7), 1109-1112. doi:10.1039/a809652j
Solid state studies (X-ray and <SUP>1</SUP>H-, <SUP>13</SUP>C-NMR) on (NMe<sub>4</sub>)<sub>4-<i>x</sub></i>[H<i><sub>x</sub></i>Ni<sub>12</sub>(CO)<sub>21</sub>]•S (<i>x</i> = 1, S = Me<sub>2</sub>CO; <i>x</i> = 2, S = 2THF)
Barkley, J. V., Eguchi, T., Harding, R. A., Heaton, B. T., Longoni, G., Manzi, L., . . . Steiner, A. (1999). Solid state studies (X-ray and <SUP>1</SUP>H-, <SUP>13</SUP>C-NMR) on (NMe<sub>4</sub>)<sub>4-<i>x</sub></i>[H<i><sub>x</sub></i>Ni<sub>12</sub>(CO)<sub>21</sub>]•S (<i>x</i> = 1, S = Me<sub>2</sub>CO; <i>x</i> = 2, S = 2THF). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 573(1-2), 254-260. doi:10.1016/S0022-328X(98)00766-9
"Observation of Triple Quantum Effects in HMQC Spectra in [Rh6(CO)15{P(o-FC6H4)3}]"
Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (1999). "Observation of Triple Quantum Effects in HMQC Spectra in [Rh6(CO)15{P(o-FC6H4)3}]". Journal of the Chemical Society, Dalton Transactions, (12), 1917-1919.
Comparative solid state and solution NMR structural and dynamic studies on tetra- and higher-nuclearity transition metal carbonyl clusters
Eguchi, T., & Heaton, B. T. (1999). Comparative solid state and solution NMR structural and dynamic studies on tetra- and higher-nuclearity transition metal carbonyl clusters. Journal of the Chemical Society, Dalton Transactions, (20), 3523-3530. doi:10.1039/a810025j
Synthesis and structural characterisation of the mixed metal clusters Rh2Pt3(m-CO)5(CO)4(PPh3)3 and Rh2Pt2(m-CO)3(CO)4(PPh3)3 ; crystal structure of Rh2Pt3(m-CO)5(CO)4(PPh3)3
Dolgushin, F. M., Grachova, E. V., Heaton, B. T., Iggo, J. A., Koshevoy, I. O., Podkorytov, I. S., . . . Yanovskii, A. I. (1999). Synthesis and structural characterisation of the mixed metal clusters Rh2Pt3(m-CO)5(CO)4(PPh3)3 and Rh2Pt2(m-CO)3(CO)4(PPh3)3 ; crystal structure of Rh2Pt3(m-CO)5(CO)4(PPh3)3. Journal of the Chemical Society-Dalton Transactions, (10), 1609-1614.
1998
'Structural elucidation of rhodium clusters using modern NMR technique'
Grachova, E. V., Heaton, B. T., Iggo, J., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (1998). 'Structural elucidation of rhodium clusters using modern NMR technique'. In ICCC (Ed.), 33rd International Conference on Coordination Chemistry (pp. 1). Florence: ICCC.
Multinuclear NMR studies on substituted derivatives of Rh<sub>6</sub>(CO)<sub>16</sub> in solution
Tunik, S. P., Podkorytov, I. S., Heaton, B. T., Iggo, J. A., & Sampanthar, J. (1998). Multinuclear NMR studies on substituted derivatives of Rh<sub>6</sub>(CO)<sub>16</sub> in solution. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 550(1-2), 221-231. doi:10.1016/S0022-328X(97)00189-7
1995
SOLUTION AND SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE STUDIES ON INTERSTITIAL ATOMS WITHIN TRANSITION-METAL CARBONYL CLUSTERS
HEATON, B. T., IGGO, J. A., LONGONI, G., & MULLEY, S. (1995). SOLUTION AND SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE STUDIES ON INTERSTITIAL ATOMS WITHIN TRANSITION-METAL CARBONYL CLUSTERS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (12), 1985-1989. doi:10.1039/dt9950001985
1994
ADDUCTS OF TRIGONAL-PRISMATIC AND OCTAHEDRAL METAL-CLUSTERS CONTAINING INTERSTITIAL ATOMS (NITROGEN OR CARBON) WITH [AU(PPH(3))](+)
BLUM, T., HEATON, B. T., IGGO, J. A., SABOUNCHEI, J., & SMITH, A. K. (1994). ADDUCTS OF TRIGONAL-PRISMATIC AND OCTAHEDRAL METAL-CLUSTERS CONTAINING INTERSTITIAL ATOMS (NITROGEN OR CARBON) WITH [AU(PPH(3))](+). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (3), 333-337. doi:10.1039/dt9940000333
KINETICS OF LIGAND EXCHANGES IN RHODIUM-(I) AND RHODIUM-(III) COMPLEXES FROM MAGNETIZATION-TRANSFER MEASUREMENTS - THE CRYSTAL-STRUCTURE OF [RH(NH3)(PPH3)3]CLO4 (VOL 22, PG 1857, 1994)
BENGTSSON, L. A., HEATON, B. T., IGGO, J. A., JACOB, C., MONKS, G. L., RATNAM, J., & SMITH, A. K. (1994). KINETICS OF LIGAND EXCHANGES IN RHODIUM-(I) AND RHODIUM-(III) COMPLEXES FROM MAGNETIZATION-TRANSFER MEASUREMENTS - THE CRYSTAL-STRUCTURE OF [RH(NH3)(PPH3)3]CLO4 (VOL 22, PG 1857, 1994). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (22), 3335. doi:10.1039/dt9940003335
KINETICS OF LIGAND-EXCHANGE IN RHODIUM-(I) AND RHODIUM-(III) COMPLEXES FROM MAGNETIZATION-TRANSFER MEASUREMENTS - THE CRYSTAL-STRUCTURE OF [RH(NH3)(PPH3)3]CLO4
BENGTSSON, L. A., HEATON, B. T., IGGO, J. A., JACOB, C., MONKS, G. L., RATNAM, J., & SMITH, A. K. (1994). KINETICS OF LIGAND-EXCHANGE IN RHODIUM-(I) AND RHODIUM-(III) COMPLEXES FROM MAGNETIZATION-TRANSFER MEASUREMENTS - THE CRYSTAL-STRUCTURE OF [RH(NH3)(PPH3)3]CLO4. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (13), 1857-1865. doi:10.1039/dt9940001857
PHOSPHINE-SUBSTITUTED TRIGONAL-PRISMATIC AND OCTAHEDRAL CLUSTERS
BLUM, T., BROWN, M. P., HEATON, B. T., HOR, A. S., IGGO, J. A., SABOUNCHEI, J. S. Z., & SMITH, A. K. (1994). PHOSPHINE-SUBSTITUTED TRIGONAL-PRISMATIC AND OCTAHEDRAL CLUSTERS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (4), 513-520. doi:10.1039/dt9940000513
REACTIONS OF WILKINSON CATALYST WITH PYRIDINE - OBSERVATION OF RHODIUM COMPLEXES CONTAINING BOTH PYRIDINE AND PHOSPHINE-LIGANDS
HEATON, B. T., IGGO, J. A., JACOB, C., NADARAJAH, J., FONTAINE, M. A., MESSERE, R., & NOELS, A. F. (1994). REACTIONS OF WILKINSON CATALYST WITH PYRIDINE - OBSERVATION OF RHODIUM COMPLEXES CONTAINING BOTH PYRIDINE AND PHOSPHINE-LIGANDS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (19), 2875-2880. doi:10.1039/dt9940002875
1993
CHARACTERIZATION OF HYDRIDOPALLADIUM COMPLEXES
HEATON, B. T., HEBERT, S. P. A., IGGO, J. A., METZ, F., & WHYMAN, R. (1993). CHARACTERIZATION OF HYDRIDOPALLADIUM COMPLEXES. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (20), 3081-3084. doi:10.1039/dt9930003081
1991
HIGH-PRESSURE SPECTROSCOPIC STUDIES OF REACTIONS OF THE CLUSTERS [RH4(CO)12-X(P(OPH)3)X] (X=1-4) WITH CARBON-MONOXIDE OR SYNGAS
BROWN, D. T., EGUCHI, T., HEATON, B. T., IGGO, J. A., & WHYMAN, R. (1991). HIGH-PRESSURE SPECTROSCOPIC STUDIES OF REACTIONS OF THE CLUSTERS [RH4(CO)12-X(P(OPH)3)X] (X=1-4) WITH CARBON-MONOXIDE OR SYNGAS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 677-683. doi:10.1039/dt9910000677