Publications
2022
Selective <i>ortho</i>-C-H Activation in Arenes without Functional Groups
Chan, A. P. Y., Jakoobi, M., Wang, C., O'Neill, R. T., Aydin, G. S. S., Halcovitch, N., . . . Sergeev, A. G. (2022). Selective <i>ortho</i>-C-H Activation in Arenes without Functional Groups. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 144(26), 11564-11568. doi:10.1021/jacs.2c04621
2021
Selective, radical-free activation of benzylic C-H bonds in methylarenes
Chan, A. P. Y., Jakoobi, M., Wang, C., Tian, Y., Halcovitch, N., Boulatov, R., & Sergeev, A. G. (2021). Selective, radical-free activation of benzylic C-H bonds in methylarenes. CHEMICAL COMMUNICATIONS, 57(64), 7894-7897. doi:10.1039/d1cc03445f
Selective cleavage of unactivated arene ring C-C bonds by iridium: key roles of benzylic C-H activation and metal-metal cooperativity
Tian, Y., Jakoobi, M., Boulatov, R., & Sergeev, A. G. (2021). Selective cleavage of unactivated arene ring C-C bonds by iridium: key roles of benzylic C-H activation and metal-metal cooperativity. CHEMICAL SCIENCE, 12(10), 3568-3579. doi:10.1039/d0sc05900e
2020
Advances in Cross-Coupling Reactions
Neumann, H., Sergeev, A. G., Spannenberg, A., & Beller, M. (2020). Advances in Cross-Coupling Reactions. L. A. Sarandeses, & J. P. Sestelo (Eds.), Basel: MDPI.
Efficient Palladium-Catalyzed Synthesis of 2-Aryl Propionic Acids
Neumann, H., Sergeev, A., Spannenberg, A., & Beller, M. (2020). Efficient Palladium-Catalyzed Synthesis of 2-Aryl Propionic Acids. Molecules, 25(15). doi:10.3390/molecules25153421
Metal-mediated cleavage of unsaturated C-C bonds
Chan, A. P. Y., & Sergeev, A. G. (2020). Metal-mediated cleavage of unsaturated C-C bonds. COORDINATION CHEMISTRY REVIEWS, 413. doi:10.1016/j.ccr.2020.213213
2019
Transition-Metal-Mediated Cleavage of C-C Bonds in Aromatic Rings
Jakoobi, M., & Sergeev, A. G. (2019). Transition-Metal-Mediated Cleavage of C-C Bonds in Aromatic Rings. CHEMISTRY-AN ASIAN JOURNAL, 14(13), 2181-2192. doi:10.1002/asia.201900443
Reversible insertion of Ir into arene ring C-C bonds with improved regioselectivity at a higher reaction temperature
Jakoobi, M., Tian, Y., Boulatov, R., & Sergeev, A. (2019). Reversible insertion of Ir into arene ring C-C bonds with improved regioselectivity at a higher reaction temperature. Journal of the American Chemical Society, 141(14), 6048-6053. doi:10.1021/jacs.9b01562
2017
Selective Arene Cleavage by Direct Insertion of Iridium into the Aromatic Ring
Jakoobi, M., Halcovitch, N., Whitehead, G. F. S., & Sergeev, A. G. (2017). Selective Arene Cleavage by Direct Insertion of Iridium into the Aromatic Ring. Angewandte Chemie, 129(12), 3314-3317. doi:10.1002/ange.201611409
Selective arene cleavage by direct insertion of iridium into the aromatic ring
Jakoobi, M., Halcovitch, N., Whitehead, G., & Sergeev, A. (2017). Selective arene cleavage by direct insertion of iridium into the aromatic ring. Angewandte Chemie (International Edition), 56(12), 3266-3269. doi:10.1002/anie.201611409
2014
Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes
Bair, J. S., Schramm, Y., Sergeev, A., Clot, E., Eisenstein, O., & Hartwig, J. F. (2014). Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes. Journal of the American Chemical Society, 136(38), 13098-13101. doi:10.1021/ja505579f
2012
A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation
Sergeev, A. G., Webb, J. D., & Hartwig, J. F. (2012). A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(50), 20226-20229. doi:10.1021/ja3085912
2011
Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers
Sergeev, A. G., & Hartwig, J. F. (2011). Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers. SCIENCE, 332(6028), 439-443. doi:10.1126/science.1200437
2010
A General and Efficient Catalyst for Palladium-Catalyzed C-O Coupling Reactions of Aryl Halides with Primary Alcohols
Gowrisankar, S., Sergeev, A. G., Anbarasan, P., Spannenberg, A., Neumann, H., & Beller, M. (2010). A General and Efficient Catalyst for Palladium-Catalyzed C-O Coupling Reactions of Aryl Halides with Primary Alcohols. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(33), 11592-11598. doi:10.1021/ja103248d
Synthesis and Catalytic Applications of Stable Palladium Dioxygen Complexes
Sergeev, A. G., Neumann, H., Spannenberg, A., & Beller, M. (2010). Synthesis and Catalytic Applications of Stable Palladium Dioxygen Complexes. ORGANOMETALLICS, 29(15), 3368-3373. doi:10.1021/om1003418
2009
Palladium-Catalyzed Hydroxylation of Aryl Halides under Ambient Conditions
Sergeev, A. G., Schulz, T., Torborg, C., Spannenberg, A., Neumann, H., & Beller, M. (2009). Palladium-Catalyzed Hydroxylation of Aryl Halides under Ambient Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 48(41), 7595-7599. doi:10.1002/anie.200902148
2008
Palladium-Catalyzed Formylation of Aryl Bromides: Elucidation of the Catalytic Cycle of an Industrially Applied Coupling Reaction
Sergeev, A. G., Spannenberg, A., & Beller, M. (2008). Palladium-Catalyzed Formylation of Aryl Bromides: Elucidation of the Catalytic Cycle of an Industrially Applied Coupling Reaction. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(46), 15549-15563. doi:10.1021/ja804997z
Palladium catalysts for the formylation of vinyl triflates to form α,β-unsaturated aldehydes
Neumann, H., Sergeev, A., & Beller, M. (2008). Palladium catalysts for the formylation of vinyl triflates to form α,β-unsaturated aldehydes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 47(26), 4887-4891. doi:10.1002/anie.200800994
Synthesis- and crystal structure of palladium(0) and arylpalladium(II) bromide complexes of Cata<i>CXium</i> A
Sergeev, A. G., Zapf, A., Spannenberg, A., & Beller, M. (2008). Synthesis- and crystal structure of palladium(0) and arylpalladium(II) bromide complexes of Cata<i>CXium</i> A. ORGANOMETALLICS, 27(2), 297-300. doi:10.1021/om700889b
2007
Arylamidate palladium complexes containing deprotonated phthalimide and <i>p</i>-methylbenzamide:: possibility of their participation in reductive elimination
Sergeev, A. G., Artamkina, G. A., Khrustalev, V. N., Antipin, M. Y., & Beletskaya, I. P. (2007). Arylamidate palladium complexes containing deprotonated phthalimide and <i>p</i>-methylbenzamide:: possibility of their participation in reductive elimination. MENDELEEV COMMUNICATIONS, 17(3), 142-144. doi:10.1016/j.mencom.2007.05.003
2006
Urea as ammonia equivalent in aryl halides amination catalyzed by palladium complexes
Artamkina, G. A., Sergeev, A. G., Shtern, M. M., & Beletskaya, I. P. (2006). Urea as ammonia equivalent in aryl halides amination catalyzed by palladium complexes. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 42(11), 1683-1689. doi:10.1134/S1070428006110133
One-Pot synthesis of symmetrical Di- and triarylamines using urea as the source of the amino group
Artamkina, G. A., Sergeev, A. G., Stern, M. M., & Beletskaya, I. P. (2006). One-Pot synthesis of symmetrical Di- and triarylamines using urea as the source of the amino group. SYNLETT, (2), 235-238. doi:10.1055/s-2005-923596
2005
Palladium-catalyzed amination and amidation of benzo-fused bromine-containing heterocycles
Sergeev, A. G., Artamkina, G. A., Velezheva, V. S., Fedorova, I. N., & Beletskaya, I. P. (2005). Palladium-catalyzed amination and amidation of benzo-fused bromine-containing heterocycles. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 41(6), 860-874. doi:10.1007/s11178-005-0257-0
2003
Variation of xantphos-based ligands in the palladium-catalyzed reaction of aryl halides with ureas
Sergeev, A. G., Artamkina, G. A., & Beletskaya, I. P. (2003). Variation of xantphos-based ligands in the palladium-catalyzed reaction of aryl halides with ureas. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 39(12), 1741-1752. doi:10.1023/B:RUJO.0000019738.50339.e8
Variation of xanthene-based bidentate ligands in the palladium-catalyzed arylation of ureas
Sergeev, A. G., Artamkina, G. A., & Beletskaya, I. P. (2003). Variation of xanthene-based bidentate ligands in the palladium-catalyzed arylation of ureas. TETRAHEDRON LETTERS, 44(25), 4719-4723. doi:10.1016/S0040-4039(03)01051-7
Variation of Xanthphos-Based Bidentate Ligands in the Palladium-Catalyzed Reaction Aryl Halides with Ureas (Engl. Transl.)
Sergeev, A. G., Artamkina, G. A., & Beletskaya, I. P. (2003). Variation of Xanthphos-Based Bidentate Ligands in the Palladium-Catalyzed Reaction Aryl Halides with Ureas (Engl. Transl.). Russ. J. Org. Chem., 39, 860-874.
2002
Palladium-catalyzed arylation of ureas
Artamkina, G. A., Sergeev, A. G., & Beletskaya, I. P. (2002). Palladium-catalyzed arylation of ureas. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 38(4), 538-545. doi:10.1023/A:1016503307552
Palladium-Catalyzed Arylation of Ureas (Engl. Transl.)
Sergeev, A. G., Artamkina, G. A., & Beletskaya, I. P. (2002). Palladium-Catalyzed Arylation of Ureas (Engl. Transl.). Russ. J. Org. Chem., 38, 538-545.
2001
Palladium-catalyzed reaction of aryl halides with ureas
Artamkina, G. A., Sergeev, A. G., & Beletskaya, I. P. (2001). Palladium-catalyzed reaction of aryl halides with ureas. TETRAHEDRON LETTERS, 42(26), 4381-4384. doi:10.1016/S0040-4039(01)00716-X