Publications
Selected publications
- Design Parameters for Ionic Liquid-Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li-O<sub>2</sub> Batteries (Journal article - 2021)
- Lithium Insertion into Graphitic Carbon Observed via Operando Kerr-Gated Raman Spectroscopy Enables High State of Charge Diagnostics (Journal article - 2022)
- A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode (Journal article - 2022)
- Simultaneous Surface-Enhanced Raman Scattering with a Kerr Gate for Fluorescence Suppression. (Journal article - 2024)
- Thermophysical and Electrochemical Properties of Ethereal Functionalised Cyclic Alkylammonium-based Ionic Liquids as Potential Electrolytes for Electrochemical Applications (Journal article - 2017)
2024
The Role of Surfactant in Electrocatalytic Carbon Dioxide Reduction in the Absence of Metal Cations
Jang, H., Gardner, A. M., Walters, L. J., Neale, A. R., Hardwick, L. J., & Cowan, A. J. (n.d.). The Role of Surfactant in Electrocatalytic Carbon Dioxide Reduction in the Absence of Metal Cations. ACS Electrochemistry. doi:10.1021/acselectrochem.4c00040
Single Versus Blended Electrolyte Additives: Impact of a Sulfur‐Based Electrolyte Additive on Electrode Cross‐Talk and Electrochemical Performance of LiNiO<sub>2</sub>||Graphite Cells
Wölke, C., Benayad, A., Lai, T., Hanke, F., Baraldi, G., Echeverría, M., . . . Cekic‐Laskovic, I. (n.d.). Single Versus Blended Electrolyte Additives: Impact of a Sulfur‐Based Electrolyte Additive on Electrode Cross‐Talk and Electrochemical Performance of LiNiO<sub>2</sub>||Graphite Cells. Advanced Energy Materials. doi:10.1002/aenm.202402152
Gating-out emission for fluorescence-free Raman spectra for the study of electrode interfaces
Neale, A. R., Sazanovich, I. V., & Hardwick, L. J. (2024). Gating-out emission for fluorescence-free Raman spectra for the study of electrode interfaces. Current Opinion in Electrochemistry, 45, 101480. doi:10.1016/j.coelec.2024.101480
Exploring carbon electrode parameters in Li–O<sub>2</sub> cells: Li<sub>2</sub>O<sub>2</sub> and Li<sub>2</sub>CO<sub>3</sub> formation
Sousa, B. P., Anchieta, C. G., Nepel, T. M. C., Neale, A. R., Hardwick, L. J., Filho, R. M., & Doubek, G. (n.d.). Exploring carbon electrode parameters in Li–O<sub>2</sub> cells: Li<sub>2</sub>O<sub>2</sub> and Li<sub>2</sub>CO<sub>3</sub> formation. Journal of Materials Chemistry A. doi:10.1039/d3ta07701b
Materials for stable metal-oxygen battery cathodes: general discussion.
Attard, G. A., Calvo, E. J., Curtiss, L. A., Dewar, D., Ellison, J. H. J., Gao, X., . . . Ye, S. (2024). Materials for stable metal-oxygen battery cathodes: general discussion.. Faraday discussions, 248(0), 75-88. doi:10.1039/d3fd90059b
Metal anodes and protected interfaces: general discussion.
Gao, X., Grey, C. P., Hardwick, L. J., Horwitz, G., Johnson, L. R., Matsuda, S., . . . Wu, Y. (2024). Metal anodes and protected interfaces: general discussion.. Faraday discussions, 248(0), 298-304. doi:10.1039/d3fd90061d
Simultaneous Surface-Enhanced Raman Scattering with a Kerr Gate for Fluorescence Suppression.
Cabello, G., Sazanovich, I. V., Siachos, I., Bilton, M., Mehdi, B. L., Neale, A. R., & Hardwick, L. J. (2024). Simultaneous Surface-Enhanced Raman Scattering with a Kerr Gate for Fluorescence Suppression.. The journal of physical chemistry letters, 608-615. doi:10.1021/acs.jpclett.3c02926
2023
Raman analysis of inverse vulcanised polymers
Dodd, L. J., Lima, C., Costa-Milan, D., Neale, A. R., Saunders, B., Zhang, B., . . . Hasell, T. (2023). Raman analysis of inverse vulcanised polymers. POLYMER CHEMISTRY, 14(12), 1369-1386. doi:10.1039/d2py01408d
2022
Corrosion suppression of aluminium current collectors within Li-ion cells using 3-methoxypropionitrile-based electrolytes
Yen, C. -H., Neale, A. R., Lim, J., Bresser, D., Hardwick, L. J., & Hu, C. -C. (2022). Corrosion suppression of aluminium current collectors within Li-ion cells using 3-methoxypropionitrile-based electrolytes. ELECTROCHIMICA ACTA, 431. doi:10.1016/j.electacta.2022.141105
Oxygen heteroatom enhanced sulfur-rich polymers synthesized by inverse vulcanization for high-performance lithium-sulfur batteries
Wang, H., Zhang, B., Dop, R., Yan, P., Neale, A. R., Hardwick, L. J., & Hasell, T. (2022). Oxygen heteroatom enhanced sulfur-rich polymers synthesized by inverse vulcanization for high-performance lithium-sulfur batteries. JOURNAL OF POWER SOURCES, 545. doi:10.1016/j.jpowsour.2022.231921
Lithium Insertion into Graphitic Carbon Observed via Operando Kerr-Gated Raman Spectroscopy Enables High State of Charge Diagnostics
Neale, A. R., Milan, D. C., Braga, F., V. Sazanovich, I., & Hardwick, L. J. (2022). Lithium Insertion into Graphitic Carbon Observed via Operando Kerr-Gated Raman Spectroscopy Enables High State of Charge Diagnostics. ACS ENERGY LETTERS, 7(8), 2611-2618. doi:10.1021/acsenergylett.2c01120
Atomic Layer Vs. Sol-Gel Deposited Coatings for Long Cycle-Life Li-Ion Battery Positive Electrodes
Powell, R., Lim, J., Neale, A. R., Chalker, P. R., & Hardwick, L. J. (2022). Atomic Layer Vs. Sol-Gel Deposited Coatings for Long Cycle-Life Li-Ion Battery Positive Electrodes. ECS Meeting Abstracts, MA2022-01(4), 515. doi:10.1149/ma2022-014515mtgabs
Operando Surface Enhanced Infrared Spectroscopic Investigations of Interfacial Restructuring and Oxygen Electrochemistry in Ionic Liquid Electrolytes for Metal-Air Batteries
Walters, L. J., Neale, A. R., Nichols, R. J., & Hardwick, L. J. (2022). Operando Surface Enhanced Infrared Spectroscopic Investigations of Interfacial Restructuring and Oxygen Electrochemistry in Ionic Liquid Electrolytes for Metal-Air Batteries. ECS Meeting Abstracts, MA2022-01(4), 569. doi:10.1149/ma2022-014569mtgabs
Operando electrochemical Kerr Gated Raman Spectroscopy to Probe the High States of Charge in Graphite Electrodes for Li-Ion Batteries
Neale, A. R., Milan, D. C., Braga, F., Sazanovich, I., & Hardwick, L. J. (2022). Operando electrochemical Kerr Gated Raman Spectroscopy to Probe the High States of Charge in Graphite Electrodes for Li-Ion Batteries. In ECS Meeting Abstracts Vol. MA2022-01 (pp. 2475). The Electrochemical Society. doi:10.1149/ma2022-0162475mtgabs
Stable Formulations for the Lithium and Sodium Metal Interfaces in Alkali Metal-Oxygen Batteries
Neale, A. R., & Hardwick, L. J. (2022). Stable Formulations for the Lithium and Sodium Metal Interfaces in Alkali Metal-Oxygen Batteries. In ECS Meeting Abstracts Vol. MA2022-01 (pp. 496). The Electrochemical Society. doi:10.1149/ma2022-013496mtgabs
A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode
Gao, H., Neale, A. R., Zhu, Q., Bahri, M., Wang, X., Yang, H., . . . Cooper, A. I. (2022). A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 144(21), 9434-9442. doi:10.1021/jacs.2c02196
2021
Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability
Han, G., Vasylenko, A., Neale, A. R., Duff, B. B., Chen, R., Dyer, M. S., . . . Rosseinsky, M. J. (2021). Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(43), 18216-18232. doi:10.1021/jacs.1c07874
Integrated Covalent Organic Framework/Carbon Nanotube Composite as Li-Ion Positive Electrode with Ultra-High Rate Performance
Gao, H., Zhu, Q., Neale, A. R., Bahri, M., Wang, X., Yang, H., . . . Cooper, A. I. (2021). Integrated Covalent Organic Framework/Carbon Nanotube Composite as Li-Ion Positive Electrode with Ultra-High Rate Performance. ADVANCED ENERGY MATERIALS, 11(39). doi:10.1002/aenm.202101880
Element selection for crystalline inorganic solid discovery guided by unsupervised machine learning of experimentally explored chemistry
Vasylenko, A., Gamon, J., Duff, B. B., Gusev, V. V., Daniels, L. M., Zanella, M., . . . Rosseinsky, M. J. (2021). Element selection for crystalline inorganic solid discovery guided by unsupervised machine learning of experimentally explored chemistry. NATURE COMMUNICATIONS, 12(1). doi:10.1038/s41467-021-25343-7
Design Parameters for Ionic Liquid-Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li-O<sub>2</sub> Batteries
Neale, A. R., Sharpe, R., Yeandel, S. R., Yen, C. -H., Luzyanin, K. V., Goddard, P., . . . Hardwick, L. J. (2021). Design Parameters for Ionic Liquid-Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li-O<sub>2</sub> Batteries. ADVANCED FUNCTIONAL MATERIALS, 31(27). doi:10.1002/adfm.202010627
Ionic Liquids: Design Parameters for Ionic Liquid–Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li–O<sub>2</sub> Batteries (Adv. Funct. Mater. 27/2021)
Neale, A. R., Sharpe, R., Yeandel, S. R., Yen, C., Luzyanin, K. V., Goddard, P., . . . Hardwick, L. J. (2021). Ionic Liquids: Design Parameters for Ionic Liquid–Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li–O<sub>2</sub> Batteries (Adv. Funct. Mater. 27/2021). Advanced Functional Materials, 31(27). doi:10.1002/adfm.202170193
Trapped interfacial redox introduces reversibility in the oxygen reduction reaction in a non-aqueous Ca<SUP>2+</SUP> electrolyte
Lu, Y. -T., Neale, A. R., Hu, C. -C., & Hardwick, L. J. (2021). Trapped interfacial redox introduces reversibility in the oxygen reduction reaction in a non-aqueous Ca<SUP>2+</SUP> electrolyte. CHEMICAL SCIENCE. doi:10.1039/d0sc06991d
Divalent Nonaqueous Metal-Air Batteries
Lu, Y. -T., Neale, A. R., Hu, C. -C., & Hardwick, L. J. (n.d.). Divalent Nonaqueous Metal-Air Batteries. Frontiers in Energy Research, 8. doi:10.3389/fenrg.2020.602918
2020
Crosslinked Polyimide and Reduced Graphene Oxide Composites as Long Cycle Life Positive Electrode for Lithium-Ion Cells
Gao, H., Tian, B., Yang, H., Neale, A. R., Little, M. A., Sprick, R. S., . . . Cooper, A. I. (2020). Crosslinked Polyimide and Reduced Graphene Oxide Composites as Long Cycle Life Positive Electrode for Lithium-Ion Cells. CHEMSUSCHEM, 13(20), 5571-5579. doi:10.1002/cssc.202001389
(Invited) Kerr Gated Raman Spectroscopy to Investigate Aging Processes on Lithium-Ion Electrode Interfaces
Hardwick, L. J., Cabo-Fernandez, L., Neale, A. R., Braga, F., Kostecki, R., & Sazanovich, I. (2020). (Invited) Kerr Gated Raman Spectroscopy to Investigate Aging Processes on Lithium-Ion Electrode Interfaces. In ECS Meeting Abstracts Vol. MA2020-01 (pp. 190). The Electrochemical Society. doi:10.1149/ma2020-012190mtgabs
Achieving Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries: Optimizing Solvation Environment in Ionic Liquid/Solvent Blend Formulations
Neale, A. R., Sharpe, R., Yeandel, S., Luzyanin, K., Iggo, J. A., Goddard, P., . . . Hardwick, L. J. (2020). Achieving Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries: Optimizing Solvation Environment in Ionic Liquid/Solvent Blend Formulations. In ECS Meeting Abstracts Vol. MA2020-01 (pp. 441). The Electrochemical Society. doi:10.1149/ma2020-012441mtgabs
Physical and Electrochemical Investigations into Blended Electrolytes Containing a Glyme Solvent and Two Bis {(trifluoromethyl)sulfonyl}imide-Based Ionic Liquids (vol 164, H5124, 2017)
Neale, A. R., Goodrich, P., Hughes, T. -L., Hardacre, C., Ball, S. C., & Jacquemin, J. (2020). Physical and Electrochemical Investigations into Blended Electrolytes Containing a Glyme Solvent and Two Bis {(trifluoromethyl)sulfonyl}imide-Based Ionic Liquids (vol 164, H5124, 2017). JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 167(8). doi:10.1149/1945-7111/ab897d
2019
Kerr gated Raman spectroscopy of LiPF<sub>6</sub> salt and LiPF<sub>6</sub>-based organic carbonate electrolyte for Li-ion batteries
Cabo-Fernandez, L., Neale, A. R., Braga, F., Sazanovich, I. V., Kostecki, R., & Hardwick, L. J. (2019). Kerr gated Raman spectroscopy of LiPF<sub>6</sub> salt and LiPF<sub>6</sub>-based organic carbonate electrolyte for Li-ion batteries. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 21(43), 23833-23842. doi:10.1039/c9cp02430a
Exploring Ionic Liquid-Solvent Blend Formulations for the Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries
Neale, A. R., Sharpe, R., Yeandel, S., Goddard, P., Petrucco, E., & Hardwick, L. J. (2019). Exploring Ionic Liquid-Solvent Blend Formulations for the Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries. In ECS Meeting Abstracts Vol. MA2019-02 (pp. 521). The Electrochemical Society. doi:10.1149/ma2019-02/6/521
2018
Lithium Transport in Li<sub>4.4</sub><i>M</i><sub>0.4</sub><i>M</i>′<sub>0.6</sub>S<sub>4</sub> (M = Al<SUP>3+</SUP>, Ga<SUP>3+</SUP>, and <i>M</i>′ = Ge<SUP>4+</SUP>, Sn<SUP>4+</SUP>): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies
Leube, B. T., Inglis, K. K., Carrington, E. J., Sharp, P. M., Shin, J. F., Neale, A. R., . . . Rosseinsky, M. J. (2018). Lithium Transport in Li<sub>4.4</sub><i>M</i><sub>0.4</sub><i>M</i>′<sub>0.6</sub>S<sub>4</sub> (M = Al<SUP>3+</SUP>, Ga<SUP>3+</SUP>, and <i>M</i>′ = Ge<SUP>4+</SUP>, Sn<SUP>4+</SUP>): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies. CHEMISTRY OF MATERIALS, 30(20), 7183-7200. doi:10.1021/acs.chemmater.8b03175
Electrolytes for<scp>Li</scp>–<scp>O<sub>2</sub></scp>Batteries
Neale, A. R., Goodrich, P., Hardacre, C., & Jacquemin, J. (2018). Electrolytes for<scp>Li</scp>–<scp>O<sub>2</sub></scp>Batteries. In Unknown Book (pp. 65-94). Wiley. doi:10.1002/9783527807666.ch4
Acyclic and Cyclic Alkyl and Ether-Functionalised Sulfonium Ionic Liquids Based on the [TFSI]<SUP>-</SUP> and [FSI]<SUP>-</SUP> Anions as Potential Electrolytes for Electrochemical Applications
Murphy, S., Ivol, F., Neale, A. R., Goodrich, P., Ghamouss, F., Hardacre, C., & Jacquemin, J. (2018). Acyclic and Cyclic Alkyl and Ether-Functionalised Sulfonium Ionic Liquids Based on the [TFSI]<SUP>-</SUP> and [FSI]<SUP>-</SUP> Anions as Potential Electrolytes for Electrochemical Applications. CHEMPHYSCHEM, 19(23), 3226-3236. doi:10.1002/cphc.201800804
2017
Thermophysical and Electrochemical Properties of Ethereal Functionalised Cyclic Alkylammonium-based Ionic Liquids as Potential Electrolytes for Electrochemical Applications
Neale, A. R., Murphy, S., Goodrich, P., Hardacre, C., & Jacquemin, J. (2017). Thermophysical and Electrochemical Properties of Ethereal Functionalised Cyclic Alkylammonium-based Ionic Liquids as Potential Electrolytes for Electrochemical Applications. CHEMPHYSCHEM, 18(15), 2040-2057. doi:10.1002/cphc.201700246
Physical-Chemical Characterization of Binary Mixtures of 1-Butyl-1-methylpyrrolidinium Bis{(trifluoromethyl)sulfonyl}imide and Aliphatic Nitrile Solvents as Potential Electrolytes for Electrochemical Energy Storage Applications
Neale, A. R., Schuetter, C., Wilde, P., Goodrich, P., Hardacre, C., Passerini, S., . . . Jacquemin, J. (2017). Physical-Chemical Characterization of Binary Mixtures of 1-Butyl-1-methylpyrrolidinium Bis{(trifluoromethyl)sulfonyl}imide and Aliphatic Nitrile Solvents as Potential Electrolytes for Electrochemical Energy Storage Applications. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 62(1), 376-390. doi:10.1021/acs.jced.6b00718
Physical and Electrochemical Investigations into Blended Electrolytes Containing a Glyme Solvent and Two Bis{(trifluoromethyl)sulfonyl}imide-Based Ionic Liquids
Neale, A. R., Goodrich, P., Hughes, T. -L., Hardacre, C., Ball, S. C., & Jacquemin, J. (2017). Physical and Electrochemical Investigations into Blended Electrolytes Containing a Glyme Solvent and Two Bis{(trifluoromethyl)sulfonyl}imide-Based Ionic Liquids. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 164(8), H5124-H5134. doi:10.1149/2.0141708jes
2016
Synthesis and Thermophysical Properties of Ether-Functionalized Sulfonium Ionic Liquids as Potential Electrolytes for Electrochemical Applications
Coadou, E., Goodrich, P., Neale, A. R., Timperman, L., Hardacre, C., Jacquemin, J., & Anouti, M. (2016). Synthesis and Thermophysical Properties of Ether-Functionalized Sulfonium Ionic Liquids as Potential Electrolytes for Electrochemical Applications. CHEMPHYSCHEM, 17(23), 3992-4002. doi:10.1002/cphc.201600882
The use of binary mixtures of 1-butyl-l-methylpyrrolidinium bis {(trifluoromethyl)sulfonyl}imide and aliphatic nitrile solvents as electrolyte for supercapacitors
Schuetter, C., Neale, A. R., Wilde, P., Goodrich, P., Hardacre, C., Passerini, S., . . . Balducci, A. (2016). The use of binary mixtures of 1-butyl-l-methylpyrrolidinium bis {(trifluoromethyl)sulfonyl}imide and aliphatic nitrile solvents as electrolyte for supercapacitors. ELECTROCHIMICA ACTA, 220, 146-155. doi:10.1016/j.electacta.2016.10.088
An ether-functionalised cyclic sulfonium based ionic liquid as an electrolyte for electrochemical double layer capacitors
Neale, A. R., Murphy, S., Goodrich, P., Schuetter, C., Hardacre, C., Passerini, S., . . . Jacquemin, J. (2016). An ether-functionalised cyclic sulfonium based ionic liquid as an electrolyte for electrochemical double layer capacitors. JOURNAL OF POWER SOURCES, 326, 549-559. doi:10.1016/j.jpowsour.2016.06.085
(Invited) Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Bis{(trifluoromethyl)Sulfonyl}Imide and Aliphatic Nitrile Solvents As Electrolyte for Electrochemical Double Layer Capacitors
Schütter, C., Neale, A. R., Wilde, P., Goodrich, P., Hardacre, C., Passerini, S., . . . Balducci, A. (2016). (Invited) Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Bis{(trifluoromethyl)Sulfonyl}Imide and Aliphatic Nitrile Solvents As Electrolyte for Electrochemical Double Layer Capacitors. In ECS Meeting Abstracts Vol. MA2016-02 (pp. 960). The Electrochemical Society. doi:10.1149/ma2016-02/7/960
Effect of cation structure on the oxygen solubility and diffusivity in a range of bis{(trifluoromethyl) sulfonyl}imide anion based ionic liquids for lithium-air battery electrolytes
Neale, A. R., Li, P., Jacquemin, J., Goodrich, P., Ball, S. C., Compton, R. G., & Hardacre, C. (2016). Effect of cation structure on the oxygen solubility and diffusivity in a range of bis{(trifluoromethyl) sulfonyl}imide anion based ionic liquids for lithium-air battery electrolytes. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 18(16), 11251-11262. doi:10.1039/c5cp07160g
Electrochemical Investigations into Blended Electrolytes Containing Ionic Liquids and a Glyme Solvent for Li-O<sub>2 </sub>batteries
Neale, A. R., Goodrich, P., Jacquemin, J., Ball, S., & Hardacre, C. (2016). Electrochemical Investigations into Blended Electrolytes Containing Ionic Liquids and a Glyme Solvent for Li-O<sub>2 </sub>batteries. In ECS Meeting Abstracts Vol. MA2016-01 (pp. 84). The Electrochemical Society. doi:10.1149/ma2016-01/1/84
2014
Electrochemical performance of laser micro-structured nickel oxyhydroxide cathodes
Neale, A. R., Jin, Y., Ouyang, J., Hughes, S., Hesp, D., Dhanak, V., . . . Hardwick, L. J. (2014). Electrochemical performance of laser micro-structured nickel oxyhydroxide cathodes. Journal of Power Sources, 271, 42-47. doi:10.1016/j.jpowsour.2014.07.167