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Alex Neale

Dr Alex Neale

Research Co-ordinator - Hardwick Group
Chemistry

Publications

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2024

Single Versus Blended Electrolyte Additives: Impact of a Sulfur‐Based Electrolyte Additive on Electrode Cross‐Talk and Electrochemical Performance of LiNiO<sub>2</sub>||Graphite Cells

Wölke, C., Benayad, A., Lai, T., Hanke, F., Baraldi, G., Echeverría, M., . . . Cekic‐Laskovic, I. (n.d.). Single Versus Blended Electrolyte Additives: Impact of a Sulfur‐Based Electrolyte Additive on Electrode Cross‐Talk and Electrochemical Performance of LiNiO<sub>2</sub>||Graphite Cells. Advanced Energy Materials. doi:10.1002/aenm.202402152

DOI
10.1002/aenm.202402152
Journal article

Materials for stable metal-oxygen battery cathodes: general discussion.

Attard, G. A., Calvo, E. J., Curtiss, L. A., Dewar, D., Ellison, J. H. J., Gao, X., . . . Ye, S. (2024). Materials for stable metal-oxygen battery cathodes: general discussion.. Faraday discussions, 248(0), 75-88. doi:10.1039/d3fd90059b

DOI
10.1039/d3fd90059b
Journal article

Metal anodes and protected interfaces: general discussion.

Gao, X., Grey, C. P., Hardwick, L. J., Horwitz, G., Johnson, L. R., Matsuda, S., . . . Wu, Y. (2024). Metal anodes and protected interfaces: general discussion.. Faraday discussions, 248(0), 298-304. doi:10.1039/d3fd90061d

DOI
10.1039/d3fd90061d
Journal article

2023

2022

Corrosion suppression of aluminium current collectors within Li-ion cells using 3-methoxypropionitrile-based electrolytes

Yen, C. -H., Neale, A. R., Lim, J., Bresser, D., Hardwick, L. J., & Hu, C. -C. (2022). Corrosion suppression of aluminium current collectors within Li-ion cells using 3-methoxypropionitrile-based electrolytes. ELECTROCHIMICA ACTA, 431. doi:10.1016/j.electacta.2022.141105

DOI
10.1016/j.electacta.2022.141105
Journal article

Atomic Layer Vs. Sol-Gel Deposited Coatings for Long Cycle-Life Li-Ion Battery Positive Electrodes

Powell, R., Lim, J., Neale, A. R., Chalker, P. R., & Hardwick, L. J. (2022). Atomic Layer Vs. Sol-Gel Deposited Coatings for Long Cycle-Life Li-Ion Battery Positive Electrodes. ECS Meeting Abstracts, MA2022-01(4), 515. doi:10.1149/ma2022-014515mtgabs

DOI
10.1149/ma2022-014515mtgabs
Journal article

Operando Surface Enhanced Infrared Spectroscopic Investigations of Interfacial Restructuring and Oxygen Electrochemistry in Ionic Liquid Electrolytes for Metal-Air Batteries

Walters, L. J., Neale, A. R., Nichols, R. J., & Hardwick, L. J. (2022). Operando Surface Enhanced Infrared Spectroscopic Investigations of Interfacial Restructuring and Oxygen Electrochemistry in Ionic Liquid Electrolytes for Metal-Air Batteries. ECS Meeting Abstracts, MA2022-01(4), 569. doi:10.1149/ma2022-014569mtgabs

DOI
10.1149/ma2022-014569mtgabs
Journal article

Operando electrochemical Kerr Gated Raman Spectroscopy to Probe the High States of Charge in Graphite Electrodes for Li-Ion Batteries

Neale, A. R., Milan, D. C., Braga, F., Sazanovich, I., & Hardwick, L. J. (2022). Operando electrochemical Kerr Gated Raman Spectroscopy to Probe the High States of Charge in Graphite Electrodes for Li-Ion Batteries. In ECS Meeting Abstracts Vol. MA2022-01 (pp. 2475). The Electrochemical Society. doi:10.1149/ma2022-0162475mtgabs

DOI
10.1149/ma2022-0162475mtgabs
Conference Paper

Stable Formulations for the Lithium and Sodium Metal Interfaces in Alkali Metal-Oxygen Batteries

Neale, A. R., & Hardwick, L. J. (2022). Stable Formulations for the Lithium and Sodium Metal Interfaces in Alkali Metal-Oxygen Batteries. In ECS Meeting Abstracts Vol. MA2022-01 (pp. 496). The Electrochemical Society. doi:10.1149/ma2022-013496mtgabs

DOI
10.1149/ma2022-013496mtgabs
Conference Paper

2021

Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability

Han, G., Vasylenko, A., Neale, A. R., Duff, B. B., Chen, R., Dyer, M. S., . . . Rosseinsky, M. J. (2021). Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(43), 18216-18232. doi:10.1021/jacs.1c07874

DOI
10.1021/jacs.1c07874
Journal article

Design Parameters for Ionic Liquid-Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li-O<sub>2</sub> Batteries

Neale, A. R., Sharpe, R., Yeandel, S. R., Yen, C. -H., Luzyanin, K. V., Goddard, P., . . . Hardwick, L. J. (2021). Design Parameters for Ionic Liquid-Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li-O<sub>2</sub> Batteries. ADVANCED FUNCTIONAL MATERIALS, 31(27). doi:10.1002/adfm.202010627

DOI
10.1002/adfm.202010627
Journal article

Ionic Liquids: Design Parameters for Ionic Liquid–Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li–O<sub>2</sub> Batteries (Adv. Funct. Mater. 27/2021)

Neale, A. R., Sharpe, R., Yeandel, S. R., Yen, C., Luzyanin, K. V., Goddard, P., . . . Hardwick, L. J. (2021). Ionic Liquids: Design Parameters for Ionic Liquid–Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li–O<sub>2</sub> Batteries (Adv. Funct. Mater. 27/2021). Advanced Functional Materials, 31(27). doi:10.1002/adfm.202170193

DOI
10.1002/adfm.202170193
Journal article

2020

(Invited) Kerr Gated Raman Spectroscopy to Investigate Aging Processes on Lithium-Ion Electrode Interfaces

Hardwick, L. J., Cabo-Fernandez, L., Neale, A. R., Braga, F., Kostecki, R., & Sazanovich, I. (2020). (Invited) Kerr Gated Raman Spectroscopy to Investigate Aging Processes on Lithium-Ion Electrode Interfaces. In ECS Meeting Abstracts Vol. MA2020-01 (pp. 190). The Electrochemical Society. doi:10.1149/ma2020-012190mtgabs

DOI
10.1149/ma2020-012190mtgabs
Conference Paper

Achieving Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries: Optimizing Solvation Environment in Ionic Liquid/Solvent Blend Formulations

Neale, A. R., Sharpe, R., Yeandel, S., Luzyanin, K., Iggo, J. A., Goddard, P., . . . Hardwick, L. J. (2020). Achieving Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries: Optimizing Solvation Environment in Ionic Liquid/Solvent Blend Formulations. In ECS Meeting Abstracts Vol. MA2020-01 (pp. 441). The Electrochemical Society. doi:10.1149/ma2020-012441mtgabs

DOI
10.1149/ma2020-012441mtgabs
Conference Paper

Physical and Electrochemical Investigations into Blended Electrolytes Containing a Glyme Solvent and Two Bis {(trifluoromethyl)sulfonyl}imide-Based Ionic Liquids (vol 164, H5124, 2017)

Neale, A. R., Goodrich, P., Hughes, T. -L., Hardacre, C., Ball, S. C., & Jacquemin, J. (2020). Physical and Electrochemical Investigations into Blended Electrolytes Containing a Glyme Solvent and Two Bis {(trifluoromethyl)sulfonyl}imide-Based Ionic Liquids (vol 164, H5124, 2017). JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 167(8). doi:10.1149/1945-7111/ab897d

DOI
10.1149/1945-7111/ab897d
Journal article

2019

Kerr gated Raman spectroscopy of LiPF<sub>6</sub> salt and LiPF<sub>6</sub>-based organic carbonate electrolyte for Li-ion batteries

Cabo-Fernandez, L., Neale, A. R., Braga, F., Sazanovich, I. V., Kostecki, R., & Hardwick, L. J. (2019). Kerr gated Raman spectroscopy of LiPF<sub>6</sub> salt and LiPF<sub>6</sub>-based organic carbonate electrolyte for Li-ion batteries. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 21(43), 23833-23842. doi:10.1039/c9cp02430a

DOI
10.1039/c9cp02430a
Journal article

Exploring Ionic Liquid-Solvent Blend Formulations for the Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries

Neale, A. R., Sharpe, R., Yeandel, S., Goddard, P., Petrucco, E., & Hardwick, L. J. (2019). Exploring Ionic Liquid-Solvent Blend Formulations for the Stable Cycling of Li-Metal Anodes in Li-O<sub>2</sub> Batteries. In ECS Meeting Abstracts Vol. MA2019-02 (pp. 521). The Electrochemical Society. doi:10.1149/ma2019-02/6/521

DOI
10.1149/ma2019-02/6/521
Conference Paper

2018

Lithium Transport in Li<sub>4.4</sub><i>M</i><sub>0.4</sub><i>M</i>′<sub>0.6</sub>S<sub>4</sub> (M = Al<SUP>3+</SUP>, Ga<SUP>3+</SUP>, and <i>M</i>′ = Ge<SUP>4+</SUP>, Sn<SUP>4+</SUP>): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies

Leube, B. T., Inglis, K. K., Carrington, E. J., Sharp, P. M., Shin, J. F., Neale, A. R., . . . Rosseinsky, M. J. (2018). Lithium Transport in Li<sub>4.4</sub><i>M</i><sub>0.4</sub><i>M</i>′<sub>0.6</sub>S<sub>4</sub> (M = Al<SUP>3+</SUP>, Ga<SUP>3+</SUP>, and <i>M</i>′ = Ge<SUP>4+</SUP>, Sn<SUP>4+</SUP>): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies. CHEMISTRY OF MATERIALS, 30(20), 7183-7200. doi:10.1021/acs.chemmater.8b03175

DOI
10.1021/acs.chemmater.8b03175
Journal article

Electrolytes for<scp>Li</scp>–<scp>O<sub>2</sub></scp>Batteries

Neale, A. R., Goodrich, P., Hardacre, C., & Jacquemin, J. (2018). Electrolytes for<scp>Li</scp>–<scp>O<sub>2</sub></scp>Batteries. In Unknown Book (pp. 65-94). Wiley. doi:10.1002/9783527807666.ch4

DOI
10.1002/9783527807666.ch4
Chapter

Acyclic and Cyclic Alkyl and Ether-Functionalised Sulfonium Ionic Liquids Based on the [TFSI]<SUP>-</SUP> and [FSI]<SUP>-</SUP> Anions as Potential Electrolytes for Electrochemical Applications

Murphy, S., Ivol, F., Neale, A. R., Goodrich, P., Ghamouss, F., Hardacre, C., & Jacquemin, J. (2018). Acyclic and Cyclic Alkyl and Ether-Functionalised Sulfonium Ionic Liquids Based on the [TFSI]<SUP>-</SUP> and [FSI]<SUP>-</SUP> Anions as Potential Electrolytes for Electrochemical Applications. CHEMPHYSCHEM, 19(23), 3226-3236. doi:10.1002/cphc.201800804

DOI
10.1002/cphc.201800804
Journal article

2017

Thermophysical and Electrochemical Properties of Ethereal Functionalised Cyclic Alkylammonium-based Ionic Liquids as Potential Electrolytes for Electrochemical Applications

Neale, A. R., Murphy, S., Goodrich, P., Hardacre, C., & Jacquemin, J. (2017). Thermophysical and Electrochemical Properties of Ethereal Functionalised Cyclic Alkylammonium-based Ionic Liquids as Potential Electrolytes for Electrochemical Applications. CHEMPHYSCHEM, 18(15), 2040-2057. doi:10.1002/cphc.201700246

DOI
10.1002/cphc.201700246
Journal article

Physical-Chemical Characterization of Binary Mixtures of 1-Butyl-1-methylpyrrolidinium Bis{(trifluoromethyl)sulfonyl}imide and Aliphatic Nitrile Solvents as Potential Electrolytes for Electrochemical Energy Storage Applications

Neale, A. R., Schuetter, C., Wilde, P., Goodrich, P., Hardacre, C., Passerini, S., . . . Jacquemin, J. (2017). Physical-Chemical Characterization of Binary Mixtures of 1-Butyl-1-methylpyrrolidinium Bis{(trifluoromethyl)sulfonyl}imide and Aliphatic Nitrile Solvents as Potential Electrolytes for Electrochemical Energy Storage Applications. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 62(1), 376-390. doi:10.1021/acs.jced.6b00718

DOI
10.1021/acs.jced.6b00718
Journal article

Physical and Electrochemical Investigations into Blended Electrolytes Containing a Glyme Solvent and Two Bis{(trifluoromethyl)sulfonyl}imide-Based Ionic Liquids

Neale, A. R., Goodrich, P., Hughes, T. -L., Hardacre, C., Ball, S. C., & Jacquemin, J. (2017). Physical and Electrochemical Investigations into Blended Electrolytes Containing a Glyme Solvent and Two Bis{(trifluoromethyl)sulfonyl}imide-Based Ionic Liquids. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 164(8), H5124-H5134. doi:10.1149/2.0141708jes

DOI
10.1149/2.0141708jes
Journal article

2016

Synthesis and Thermophysical Properties of Ether-Functionalized Sulfonium Ionic Liquids as Potential Electrolytes for Electrochemical Applications

Coadou, E., Goodrich, P., Neale, A. R., Timperman, L., Hardacre, C., Jacquemin, J., & Anouti, M. (2016). Synthesis and Thermophysical Properties of Ether-Functionalized Sulfonium Ionic Liquids as Potential Electrolytes for Electrochemical Applications. CHEMPHYSCHEM, 17(23), 3992-4002. doi:10.1002/cphc.201600882

DOI
10.1002/cphc.201600882
Journal article

The use of binary mixtures of 1-butyl-l-methylpyrrolidinium bis {(trifluoromethyl)sulfonyl}imide and aliphatic nitrile solvents as electrolyte for supercapacitors

Schuetter, C., Neale, A. R., Wilde, P., Goodrich, P., Hardacre, C., Passerini, S., . . . Balducci, A. (2016). The use of binary mixtures of 1-butyl-l-methylpyrrolidinium bis {(trifluoromethyl)sulfonyl}imide and aliphatic nitrile solvents as electrolyte for supercapacitors. ELECTROCHIMICA ACTA, 220, 146-155. doi:10.1016/j.electacta.2016.10.088

DOI
10.1016/j.electacta.2016.10.088
Journal article

(Invited) Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Bis{(trifluoromethyl)Sulfonyl}Imide and Aliphatic Nitrile Solvents As Electrolyte for Electrochemical Double Layer Capacitors

Schütter, C., Neale, A. R., Wilde, P., Goodrich, P., Hardacre, C., Passerini, S., . . . Balducci, A. (2016). (Invited) Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Bis{(trifluoromethyl)Sulfonyl}Imide and Aliphatic Nitrile Solvents As Electrolyte for Electrochemical Double Layer Capacitors. In ECS Meeting Abstracts Vol. MA2016-02 (pp. 960). The Electrochemical Society. doi:10.1149/ma2016-02/7/960

DOI
10.1149/ma2016-02/7/960
Conference Paper

Effect of cation structure on the oxygen solubility and diffusivity in a range of bis{(trifluoromethyl) sulfonyl}imide anion based ionic liquids for lithium-air battery electrolytes

Neale, A. R., Li, P., Jacquemin, J., Goodrich, P., Ball, S. C., Compton, R. G., & Hardacre, C. (2016). Effect of cation structure on the oxygen solubility and diffusivity in a range of bis{(trifluoromethyl) sulfonyl}imide anion based ionic liquids for lithium-air battery electrolytes. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 18(16), 11251-11262. doi:10.1039/c5cp07160g

DOI
10.1039/c5cp07160g
Journal article

Electrochemical Investigations into Blended Electrolytes Containing Ionic Liquids and a Glyme Solvent for Li-O­<sub>2 </sub>batteries

Neale, A. R., Goodrich, P., Jacquemin, J., Ball, S., & Hardacre, C. (2016). Electrochemical Investigations into Blended Electrolytes Containing Ionic Liquids and a Glyme Solvent for Li-O­<sub>2 </sub>batteries. In ECS Meeting Abstracts Vol. MA2016-01 (pp. 84). The Electrochemical Society. doi:10.1149/ma2016-01/1/84

DOI
10.1149/ma2016-01/1/84
Conference Paper

2014