TiO2 (Rutile)

see Housecroft and Constable 3rd Edition p 283

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Unit cell of rutile

Extended structure

The rutile structure can be considered as a distorted hcp array of O2- ions with the Ti4+ ions occupying the octahedral holes.

The O2- ions have slightly distorted trigonal planar coordination. This can be seen in the extended structure below.

The unit cell contains:

[1+{8x(1/8)}] = 2 Ti4+ ions and

[2+{4x(1/2)}] = 4 O2- ions

Extended structure

unit cell

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