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Frederic Blanc

Professor Frederic Blanc
MChem, MSci, PhD, FHEA

Publications

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2024

Enhancement of Low Temperature Superionic Conductivity by Suppression of Li Site Ordering in Li7Si2–xGexS7I

Han, G., Daniels, L. M., Vasylenko, A., Morrison, K. A., Corti, L., Collins, C. M., . . . Rosseinsky, M. J. (2024). Enhancement of Low Temperature Superionic Conductivity by Suppression of Li Site Ordering in Li<sub>7</sub>Si<sub>2-x</sub>Ge<sub>x</sub>S<sub>7</sub>I.. Angewandte Chemie (International ed. in English), 63(37), e202409372. doi:10.1002/anie.202409372

DOI
10.1002/anie.202409372
Journal article

2023

Toward Understanding of the Li-Ion Migration Pathways in the Lithium Aluminum Sulfides Li3AlS3 and Li4.3AlS3.3Cl0.7 via 6,7Li Solid-State Nuclear Magnetic Resonance Spectroscopy

Duff, B. B., Elliott, S. J., Gamon, J., Daniels, L. M., Rosseinsky, M. J., & Blanc, F. (2023). Toward Understanding of the Li-Ion Migration Pathways in the Lithium Aluminum Sulfides Li3AlS3 and Li4.3AlS3.3Cl0.7 via 6,7Li Solid- State Nuclear Magnetic Resonance Spectroscopy. CHEMISTRY OF MATERIALS, 35(1), 27-40. doi:10.1021/acs.chemmater.2c02101

DOI
10.1021/acs.chemmater.2c02101
Journal article

2022

Control of Ionic Conductivity by Lithium Distribution in Cubic Oxide Argyrodites Li6+xP1-xSixO5Cl.

Morscher, A., Duff, B. B., Han, G., Daniels, L. M., Dang, Y., Zanella, M., . . . Rosseinsky, M. J. (2022). Control of Ionic Conductivity by Lithium Distribution in Cubic Oxide Argyrodites Li<sub>6+<i>X</i></sub>P<sub>1-<i>X</i></sub>Si<i><sub>X</sub></i>O<sub>5</sub>Cl. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 144(48), 22178-22192. doi:10.1021/jacs.2c09863

DOI
10.1021/jacs.2c09863
Journal article

New Development in Understanding Drug-Polymer Interactions in Pharmaceutical Amorphous Solid Dispersions from Solid-State Nuclear Magnetic Resonance

Pugliese, A., Tobyn, M., Hawarden, L. E., Abraham, A., & Blanc, F. (2022). New Development in Understanding Drug-Polymer Interactions in Pharmaceutical Amorphous Solid Dispersions from Solid-State Nuclear Magnetic Resonance. MOLECULAR PHARMACEUTICS, 19(11), 3685-3699. doi:10.1021/acs.molpharmaceut.2c00479

DOI
10.1021/acs.molpharmaceut.2c00479
Journal article

Off-the-Shelf Gd(NO3)3 as an Efficient High-Spin Metal Ion Polarizing Agent for Magic Angle Spinning Dynamic Nuclear Polarization.

Elliott, S. J., Duff, B. B., Taylor-Hughes, A. R., Cheney, D. J., Corley, J. P., Paul, S., . . . Blanc, F. (2022). Off-the-Shelf Gd(NO<sub>3</sub>)<sub>3</sub> as an Efficient High-Spin Metal Ion Polarizing Agent for Magic Angle Spinning Dynamic Nuclear Polarization. JOURNAL OF PHYSICAL CHEMISTRY B, 126(33), 6281-6289. doi:10.1021/acs.jpcb.2c04184

DOI
10.1021/acs.jpcb.2c04184
Journal article

DNP NMR reveals the hidden surface C–C bond growth mechanism over ZnAlO during syngas conversion

Gao, P., Xiao, D., Zhao, Z., Paul, S., Blanc, F., Han, X., . . . Bao, X. (2022). DNP NMR reveals the hidden surface C-C bond growth mechanism over ZnAlO<i><sub>x</sub></i> during syngas conversion. JOURNAL OF ENERGY CHEMISTRY, 67, 640-644. doi:10.1016/j.jechem.2021.10.033

DOI
10.1016/j.jechem.2021.10.033
Journal article

2021

Li4.3AlS3.3Cl0.7: A Sulfide-Chloride Lithium Ion Conductor with Highly Disordered Structure and Increased Conductivity.

Gamon, J., Dyer, M. S., Duff, B. B., Vasylenko, A., Daniels, L. M., Zanella, M., . . . Rosseinsky, M. J. (2021). Li<sub>4.3</sub>AlS<sub>3.3</sub>Cl<sub>0.7</sub>: A Sulfide-Chloride Lithium Ion Conductor with Highly Disordered Structure and Increased Conductivity. CHEMISTRY OF MATERIALS, 33(22), 8733-8744. doi:10.1021/acs.chemmater.1c02751

DOI
10.1021/acs.chemmater.1c02751
Journal article

Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability

Han, G., Vasylenko, A., Neale, A. R., Duff, B. B., Chen, R., Dyer, M. S., . . . Rosseinsky, M. J. (2021). Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(43), 18216-18232. doi:10.1021/jacs.1c07874

DOI
10.1021/jacs.1c07874
Journal article

Drug–Polymer Interactions in Acetaminophen/Hydroxypropylmethylcellulose Acetyl Succinate Amorphous Solid Dispersions Revealed by Multidimensional Multinuclear Solid-State NMR Spectroscopy

Pugliese, A., Toresco, M., McNamara, D., Iuga, D., Abraham, A., Tobyn, M., . . . Blanc, F. (2021). Drug-Polymer Interactions in Acetaminophen/ Hydroxypropylmethylcellulose Acetyl Succinate Amorphous Solid Dispersions Revealed by Multidimensional Multinuclear Solid-State NMR Spectroscopy. MOLECULAR PHARMACEUTICS, 18(9), 3519-3531. doi:10.1021/acs.molpharmaceut.1c00427

DOI
10.1021/acs.molpharmaceut.1c00427
Journal article

Dynamic Nuclear Polarisation Enhanced NMR

Brownbill, N. J., & Blanc, F. (2021). Dynamic Nuclear Polarisation Enhanced NMR. In NMR and MRI of Electrochemical Energy Storage Materials and Devices (pp. 130-158). The Royal Society of Chemistry. doi:10.1039/9781839160097-00130

DOI
10.1039/9781839160097-00130
Chapter

Li4.3AlS3.3Cl0.7: A Sulfide-Chloride Lithium Ion Conductor with a Highly Disordered Structure

DOI
10.26434/chemrxiv.14454627
Preprint

Bottom-up wet-chemical synthesis of a two-dimensional porous carbon material with high supercapacitance using a cascade coupling/cyclization route

Xu, Y., Sprick, R. S., Brownbill, N. J., Blanc, F., Li, Q., Ward, J. W., . . . Cooper, A. I. (n.d.). Bottom-up wet-chemical synthesis of a two-dimensional porous carbon material with high supercapacitance using a cascade coupling/cyclization route. Journal of Materials Chemistry A, 9(6), 3303-3308. doi:10.1039/d0ta11649a

DOI
10.1039/d0ta11649a
Journal article

Dynamic Nuclear Polarisation Enhanced NMR

Brownbill, N. J., & Blanc, F. (2021). Dynamic Nuclear Polarisation Enhanced NMR. In NMR AND MRI OF ELECTROCHEMICAL ENERGY STORAGE MATERIALS AND DEVICES (Vol. 25, pp. 130-158). Retrieved from https://www.webofscience.com/

Chapter

2020

Solid state nuclear magnetic resonance studies of hydroxypropylmethylcellulose acetyl succinate polymer, a useful carrier in pharmaceutical solid dispersions

Pugliese, A., Hawarden, L. E., Abraham, A., Tobyn, M., & Blanc, F. (2020). Solid state nuclear magnetic resonance studies of hydroxypropylmethylcellulose acetyl succinate polymer, a useful carrier in pharmaceutical solid dispersions. MAGNETIC RESONANCE IN CHEMISTRY, 58(11), 1036-1048. doi:10.1002/mrc.4984

DOI
10.1002/mrc.4984
Journal article

2019

Computationally Guided Discovery of the Sulfide Li<sub>3</sub>AlS<sub>3</sub> in the Li-Al-S Phase Field: Structure and Lithium Conductivity.

Gamon, J., Duff, B. B., Dyer, M. S., Collins, C., Daniels, L. M., Surta, T. W., . . . Rosseinsky, M. J. (2019). Computationally Guided Discovery of the Sulfide Li<sub>3</sub>AlS<sub>3</sub> in the Li-Al-S Phase Field: Structure and Lithium Conductivity. CHEMISTRY OF MATERIALS, 31(23), 9699-9714. doi:10.1021/acs.chemmater.9b03230

DOI
10.1021/acs.chemmater.9b03230
Journal article

2018

Lithium Transport in Li4.4M0.4M′0.6S4 (M = Al3+, Ga3+, and M′ = Ge4+, Sn4+): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies

Leube, B. T., Inglis, K. K., Carrington, E. J., Sharp, P. M., Shin, J. F., Neale, A. R., . . . Rosseinsky, M. J. (2018). Lithium Transport in Li<sub>4.4</sub><i>M</i><sub>0.4</sub><i>M</i>′<sub>0.6</sub>S<sub>4</sub> (M = Al<SUP>3+</SUP>, Ga<SUP>3+</SUP>, and <i>M</i>′ = Ge<SUP>4+</SUP>, Sn<SUP>4+</SUP>): Combined Crystallographic, Conductivity, Solid State NMR, and Computational Studies. CHEMISTRY OF MATERIALS, 30(20), 7183-7200. doi:10.1021/acs.chemmater.8b03175

DOI
10.1021/acs.chemmater.8b03175
Journal article

Understanding Hydrogen Evolution Activity of Linear Organic Photocatalysts

Sachs, M., Cooper, A. I., Pearce, D., Hillman, S. J., Monti, A., Guilbert, A. A. Y., . . . Brownbill, N. J. (2018, October 22). Understanding Hydrogen Evolution Activity of Linear Organic Photocatalysts. In Proceedings of the nanoGe Fall Meeting 2018. Fundació Scito. doi:10.29363/nanoge.fallmeeting.2018.142

DOI
10.29363/nanoge.fallmeeting.2018.142
Conference Paper

Understanding Hydrogen Evolution Activity of Linear Organic Photocatalysts

Sachs, M., Cooper, A. I., Pearce, D., Hillman, S. J., Monti, A., Guilbert, A. A. Y., . . . Brownbill, N. J. (2018, October 22). Understanding Hydrogen Evolution Activity of Linear Organic Photocatalysts. In Proceedings of the nanoGe Fall Meeting 2018. Fundació Scito. doi:10.29363/nanoge.nfm.2018.142

DOI
10.29363/nanoge.nfm.2018.142
Conference Paper

Berichtigung: Visible‐Light‐Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts

Sprick, R. S., Bonillo, B., Clowes, R., Guiglion, P., Brownbill, N. J., Slater, B. J., . . . Cooper, A. I. (2018). Berichtigung: Visible‐Light‐Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts. Angewandte Chemie, 130(10), 2546. doi:10.1002/ange.201800571

DOI
10.1002/ange.201800571
Journal article

<SUP>17</SUP>O solid-state NMR spectroscopy of A<sub>2</sub>B<sub>2</sub>O<sub>7</sub> oxides: quantitative isotopic enrichment and spectral acquisition?

Fernandes, A., Moran, R. F., Sneddon, S., Dawson, D. M., McKay, D., Bignami, G. P. M., . . . Ashbrook, S. E. (2018). <SUP>17</SUP>O solid-state NMR spectroscopy of A<sub>2</sub>B<sub>2</sub>O<sub>7</sub> oxides: quantitative isotopic enrichment and spectral acquisition?. RSC ADVANCES, 8(13), 7089-7101. doi:10.1039/c8ra00596f

DOI
10.1039/c8ra00596f
Journal article

2017

Ultra-Fast Molecular Rotors within Porous Organic Cages.

Hughes, A. R., Brownbill, N. J., Lalek, R. C., Briggs, M. E., Slater, A. G., Cooper, A. I., & Blanc, F. (2017). Ultra-Fast Molecular Rotors within Porous Organic Cages. CHEMISTRY-A EUROPEAN JOURNAL, 23(68), 17217-17221. doi:10.1002/chem.201704964

DOI
10.1002/chem.201704964
Journal article

Direct structural identification of carbenium ions and investigation of host–guest interaction in the methanol to olefins reaction obtained by multinuclear NMR correlations

Xiao, D., Xu, S., Han, X., Bao, X., Liu, Z., & Blanc, F. (2017). Direct structural identification of carbenium ions and investigation of host-guest interaction in the methanol to olefins reaction obtained by multinuclear NMR correlations. CHEMICAL SCIENCE, 8(12), 8309-8314. doi:10.1039/c7sc03657d

DOI
10.1039/C7SC03657D
Journal article

Investigation of Catalytic Surfaces with Surface‐Enhanced Solid‐State<scp>NMR</scp>Spectroscopy

Blanc, F. (2017). Investigation of Catalytic Surfaces with Surface‐Enhanced Solid‐State<scp>NMR</scp>Spectroscopy. In Unknown Book (pp. 1003-1028). Wiley. doi:10.1002/9783527699827.ch38

DOI
10.1002/9783527699827.ch38
Chapter

2016

La<sub>3</sub>Li<sub>3</sub>W<sub>2</sub>O<sub>12</sub>: Ionic Diffusion in a Perovskite with Lithium on both A- and 6-Sites

Santibanez-Mendieta, A. B., Didier, C., Inglis, K. K., Corkett, A. J., Pitcher, M. J., Zanella, M., . . . Rosseinsky, M. J. (2016). La<sub>3</sub>Li<sub>3</sub>W<sub>2</sub>O<sub>12</sub>: Ionic Diffusion in a Perovskite with Lithium on both A- and 6-Sites. CHEMISTRY OF MATERIALS, 28(21), 7833-7851. doi:10.1021/acs.chemmater.6b03220

DOI
10.1021/acs.chemmater.6b03220
Journal article

Probing Oxide-Ion Mobility in the Mixed Ionic-Electronic Conductor La2NiO4+δ by Solid-State 17O MAS NMR Spectroscopy

Halat, D. M., Dervişoğlu, R., Kim, G., Dunstan, M. T., Blanc, F., Middlemiss, D. S., & Grey, C. P. (2016). Probing Oxide-Ion Mobility in the Mixed Ionic-Electronic Conductor La2NiO4+δ by Solid-State 17O MAS NMR Spectroscopy. Journal of the American Chemical Society, 138(36), 11958-11969. doi:10.1021/jacs.6b07348

DOI
10.1021/jacs.6b07348
Journal article

Structure and Sodium Ion Dynamics in Sodium Strontium Silicate Investigated by Multinuclear Solid-State NMR

Inglis, K. K., Corley, J. P., Florian, P., Cabana, J., Bayliss, R. D., & Blanc, F. (2016). Structure and Sodium Ion Dynamics in Sodium Strontium Silicate Investigated by Multinuclear Solid-State NMR. CHEMISTRY OF MATERIALS, 28(11), 3850-3861. doi:10.1021/acs.chemmater.6b00941

DOI
10.1021/acs.chemmater.6b00941
Journal article

Crystal structure and proton conductivity of BaSn0.6Sc0.4O3-δ: Insights from neutron powder diffraction and solid-state NMR spectroscopy

Kinyanjui, F. G., Norberg, S. T., Knee, C. S., Ahmed, I., Hull, S., Buannic, L., . . . Eriksson, S. G. (2016). Crystal structure and proton conductivity of BaSn<sub>0.6</sub>Sc<sub>0.4</sub>O<sub>3-δ</sub>: insights from neutron powder diffraction and solid-state NMR spectroscopy. JOURNAL OF MATERIALS CHEMISTRY A, 4(14), 5088-5101. doi:10.1039/c5ta09744d

DOI
10.1039/c5ta09744d
Journal article

Melt-Quenched Glasses of Metal-Organic Frameworks

Bennett, T. D., Yue, Y., Li, P., Qiao, A., Tao, H., Greaves, N. G., . . . Keen, D. A. (2016). Melt-Quenched Glasses of Metal-Organic Frameworks. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(10), 3484-3492. doi:10.1021/jacs.5b13220

DOI
10.1021/jacs.5b13220
Journal article

A comparison of the amorphization of zeolitic imidazolate frameworks (ZIFs) and aluminosilicate zeolites by ball-milling

Baxter, E. F., Bennett, T. D., Cairns, A. B., Brownbill, N. J., Goodwin, A. L., Keen, D. A., . . . Cheetham, A. K. (2016). A comparison of the amorphization of zeolitic imidazolate frameworks (ZIFs) and aluminosilicate zeolites by ball-milling. DALTON TRANSACTIONS, 45(10), 4258-4268. doi:10.1039/c5dt03477a

DOI
10.1039/c5dt03477a
Journal article

Visible‐Light‐Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts

Sprick, R. S., Bonillo, B., Clowes, R., Guiglion, P., Brownbill, N. J., Slater, B. J., . . . Cooper, A. I. (2016). Visible‐Light‐Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts. Angewandte Chemie International Edition, 55(5), 1792-1796. doi:10.1002/anie.201510542

DOI
10.1002/anie.201510542
Journal article

2015

Ion Dynamics in Li2CO3 Studied by Solid-State NMR and First-Principles Calculations

Dunstan, M. T., Griffin, J. M., Blanc, F., Leskes, M., & Grey, C. P. (2015). Ion Dynamics in Li<sub>2</sub>CO<sub>3</sub> Studied by Solid-State NMR and First-Principles Calculations. JOURNAL OF PHYSICAL CHEMISTRY C, 119(43), 24255-24264. doi:10.1021/acs.jpcc.5b06647

DOI
10.1021/acs.jpcc.5b06647
Journal article

Influence of Functionalization of Nanocontainers on Self-Healing Anticorrosive Coatings

Zheng, Z., Schenderlein, M., Huang, X., Brownbill, N., Blanc, F., & Shchukin, D. (2015). Influence of Functionalization of Nanocontainers on Self-Healing Anticorrosive Coatings. ACS Applied Materials & Interfaces, 7(41), 22756-22766. doi:10.1021/acsami.5b08028

DOI
10.1021/acsami.5b08028
Journal article

Joint Experimental and Computational 17O and 1H Solid State NMR Study of Ba2In2O4(OH)2 Structure and Dynamics

Dervisoglu, R., Middlemiss, D. S., Blanc, F., Lee, Y. -L., Morgan, D., & Grey, C. P. (2015). Joint Experimental and Computational <SUP>17</SUP>O and <SUP>1</SUP>H Solid State NMR Study of Ba<sub>2</sub>In<sub>2</sub>O<sub>4</sub>(OH)<sub>2</sub> Structure and Dynamics. CHEMISTRY OF MATERIALS, 27(11), 3861-3873. doi:10.1021/acs.chemmater.5b00328

DOI
10.1021/acs.chemmater.5b00328
Journal article

Characterization of the Dynamics in the Protonic Conductor CsH2PO4 by 17O Solid-State NMRSpectroscopy and First-Principles Calculations: Correlating Phosphate and Protonic Motion.

Kim, G., Griffin, J. M., Blanc, F., Haile, S. M., & Grey, C. P. (2015). Characterization of the Dynamics in the Protonic Conductor CsH<sub>2</sub>PO<sub>4</sub> by <SUP>17</SUP>O Solid-State NMR Spectroscopy and First-Principles Calculations: Correlating Phosphate and Protonic Motion. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(11), 3867-3876. doi:10.1021/jacs.5b00280

DOI
10.1021/jacs.5b00280
Journal article

2014

Dynamic Nuclear Polarization NMR of Low Gamma Nuclei: Structural Insights into Hydrated Yttrium-doped BaZrO3.

Blanc, F., Sperrin, L., Lee, D., Dervisoglu, R., Yamazaki, Y., Haile, S. M., . . . Grey, C. P. (2014). Dynamic Nuclear Polarization NMR of Low Gamma Nuclei: Structural Insights into Hydrated Yttrium-doped BaZrO3.. Journal of Physical Chemistry Letters, 5(14), 2431-2436. doi:10.1021/jz5007669

DOI
10.1021/jz5007669
Journal article

Swellable, Water- and Acid-Tolerant Polymer Sponges for Chemoselective Carbon Dioxide Capture

Woodward, R. T., Stevens, L. A., Dawson, R., Vijayaraghavan, M., Hasell, T., Silverwood, I. P., . . . Cooper, A. I. (2014). Swellable, Water- and Acid-Tolerant Polymer Sponges for Chemoselective Carbon Dioxide Capture. Journal of the American Chemical Society, 136(25), 9028-9035. doi:10.1021/ja5031968

DOI
10.1021/ja5031968
Journal article

Investigating Local Structure in Layered Double Hydroxides with 17O NMR Spectroscopy.

Zhao, L., Qi, Z., Blanc, F., Yu, G., Wang, M., Xue, N., . . . Peng, L. (2014). Investigating Local Structure in Layered Double Hydroxides with <SUP>17</SUP>O NMR Spectroscopy. ADVANCED FUNCTIONAL MATERIALS, 24(12), 1696-1702. doi:10.1002/adfm.201301157

DOI
10.1002/adfm.201301157
Journal article

Supramolecular Materials: Investigating Local Structure in Layered Double Hydroxides with <sup>17</sup>O NMR Spectroscopy (Adv. Funct. Mater. 12/2014)

Zhao, L., Qi, Z., Blanc, F., Yu, G., Wang, M., Xue, N., . . . Peng, L. (2014). Supramolecular Materials: Investigating Local Structure in Layered Double Hydroxides with <sup>17</sup>O NMR Spectroscopy (Adv. Funct. Mater. 12/2014). Advanced Functional Materials, 24(12), 1695. doi:10.1002/adfm.201470078

DOI
10.1002/adfm.201470078
Journal article

Joint experimental and computational <SUP>17</SUP>O solid state NMR study of Brownmillerite Ba<sub>2</sub>In<sub>2</sub>O<sub>5</sub>

Dervisoglu, R., Middlemiss, D. S., Blanc, F., Holmes, L. A., Lee, Y. -L., Morgan, D., & Grey, C. P. (2014). Joint experimental and computational <SUP>17</SUP>O solid state NMR study of Brownmillerite Ba<sub>2</sub>In<sub>2</sub>O<sub>5</sub>. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 16(6), 2597-2606. doi:10.1039/c3cp53642d

DOI
10.1039/c3cp53642d
Journal article

Guest Adaptable and Water Stable Peptide Based Porous Materials by Imidazolate Sidechain Control

Katsoulidis, A. P., Park, K. S., Antypov, D., Marti-Gastaldo, C., Miller, G. P., Warren, J. E., . . . Rosseinsky, M. J. (2014). Guest Adaptable and Water Stable Peptide Based Porous Materials by Imidazolate Sidechain Control. Angew. Chem. Int. Ed., 53, 193-198.

Journal article

Guest‐Adaptable and Water‐Stable Peptide‐Based Porous Materials by Imidazolate Side Chain Control

Katsoulidis, A. P., Park, K. S., Antypov, D., Martí‐Gastaldo, C., Miller, G. J., Warren, J. E., . . . Rosseinsky, M. J. (2014). Guest‐Adaptable and Water‐Stable Peptide‐Based Porous Materials by Imidazolate Side Chain Control. Angewandte Chemie, 126(1), 197-202. doi:10.1002/ange.201307074

DOI
10.1002/ange.201307074
Journal article

'Dry bases': carbon dioxide capture using alkaline dry water

Dawson, R., Stevens, L. A., Williams, O. S. A., Wang, W., Carter, B. O., Sutton, S., . . . Cooper, A. I. (2014). 'Dry bases': carbon dioxide capture using alkaline dry water. ENERGY & ENVIRONMENTAL SCIENCE, 7(5), 1786-1791. doi:10.1039/c3ee44124e

DOI
10.1039/c3ee44124e
Journal article

Guest Adaptable and Water Stable Peptide Based Porous Materials by Imidazolate Sidechain Control.

Katsoulidis, A. P., Sung Park, K., Antypov, D., Martí-Gastaldo, C., Miller, G. J., Warren, J. E., . . . Rosseinsky, M. J. (2014). Guest Adaptable and Water Stable Peptide Based Porous Materials by Imidazolate Sidechain Control.. Angew. Chem. Int. Ed., 125, 1-7.

Journal article

2013

Dynamic Nuclear Polarization NMR Spectroscopy Allows High-Throughput Characterization of Microporous Organic Polymers

Blanc, F., Chong, S. Y., McDonald, T. O., Adams, D. J., Pawsey, S., Caporini, M. A., & Cooper, A. I. (2013). Dynamic Nuclear Polarization NMR Spectroscopy Allows High-Throughput Characterization of Microporous Organic Polymers. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(41), 15290-15293. doi:10.1021/ja408074v

DOI
10.1021/ja408074v
Journal article

Shedding Light on Structure-Property Relationships for Conjugated Microporous Polymers: The Importance of Rings and Strain

Zwijnenburg, M. A., Cheng, G., McDonald, T. O., Jelfs, K. E., Jiang, J. -X., Ren, S., . . . Adams, D. J. (2013). Shedding Light on Structure-Property Relationships for Conjugated Microporous Polymers: The Importance of Rings and Strain. MACROMOLECULES, 46(19), 7696-7704. doi:10.1021/ma401311s

DOI
10.1021/ma401311s
Journal article

<i>In Situ</i> Solid-State NMR Spectroscopy of Electrochemical Cells: Batteries, Supercapacitors, and Fuel Cells

Blanc, F., Leskes, M., & Grey, C. P. (2013). <i>In Situ</i> Solid-State NMR Spectroscopy of Electrochemical Cells: Batteries, Supercapacitors, and Fuel Cells. ACCOUNTS OF CHEMICAL RESEARCH, 46(9), 1952-1963. doi:10.1021/ar400022u

DOI
10.1021/ar400022u
Journal article

Long-range ordered coexistence of 4, 5 and 6-coordinate niobium in the mixed ionic-electronic conductor γ-Ba4Nb2O9

Dunstan, M. T., Blanc, F., Avdeev, M., McIntyre, G. J., Grey, C. P., & Ling, C. D. (2013). Long-Range-Ordered Coexistence of 4-, 5-, and 6-Coordinate Niobium in the Mixed Ionic-Electronic Conductor γ-Ba<sub>4</sub>Nb<sub>2</sub>O<sub>9</sub>. CHEMISTRY OF MATERIALS, 25(15), 3154-3161. doi:10.1021/cm4014656

DOI
10.1021/cm4014656
Journal article

Proton trapping in yttrium-doped barium zirconate

Yamazaki, Y., Blanc, F., Okuyama, Y., Buannic, L., Lucio-Vega, J. C., Grey, C. P., & Haile, S. M. (2013). Proton trapping in yttrium-doped barium zirconate. NATURE MATERIALS, 12(7), 647-651. doi:10.1038/NMAT3638

DOI
10.1038/NMAT3638
Journal article

Understanding the conduction mechanism of the protonic conductor CsH2PO4 by solid state NMR spectroscopy.

Kim, G., Blanc, F., Hu, Y. -Y., & Grey, C. P. (2013). Understanding the Conduction Mechanism of the Protonic Conductor CsH<sub>2</sub>PO<sub>4</sub> by Solid-State NMR Spectroscopy. JOURNAL OF PHYSICAL CHEMISTRY C, 117(13), 6504-6515. doi:10.1021/jp312410t

DOI
10.1021/jp312410t
Journal article

Dynamic nuclear polarization enhanced natural abundance 17O spectroscopy

Blanc, F., Sperrin, L., Jefferson, D. A., Pawsey, S., Rosay, M., & Grey, C. P. (2013). Dynamic Nuclear Polarization Enhanced Natural Abundance <SUP>17</SUP>O Spectroscopy. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(8), 2975-2978. doi:10.1021/ja4004377

DOI
10.1021/ja4004377
Journal article

A structural study of La1-xYxScO3, combining neutron diffraction, solid-state NMR and first-principles DFT calculations.

Johnston, K. E., Mitchell, M. R., Blanc, F., Lightfoot, P., & Ashbrook, S. E. (2013). Structural Study of La<sub>1-<i>x</i></sub>Y<i><sub>x</sub></i>ScO<sub>3</sub>, Combining Neutron Diffraction, Solid-State NMR, and First-Principles DFT Calculations. JOURNAL OF PHYSICAL CHEMISTRY C, 117(5), 2252-2265. doi:10.1021/jp310878b

DOI
10.1021/jp310878b
Journal article

Shedding Light on Structure - Property Relationships for Conjugated Microporous Polymers: The Importance of Rings and Strain.

Zwijnenburg, M. A., Cheng, G., McDonald, T. O., Jelfs, K. E., Jiang, J. -X., Ren, S., . . . Adams, D. J. (2013). Shedding Light on Structure - Property Relationships for Conjugated Microporous Polymers: The Importance of Rings and Strain.. Macromolecules, 46, 7696-7704.

Journal article

2012

Probing cation and vacancy ordering in the dry and hydrated yttrium substituted BaSnO3 perovskite by NMR spectroscopy and first principles calculations: implications for proton mobility.

Buannic, L., Blanc, F., Middlemiss, D. S., & Grey, C. P. (2012). Probing Cation and Vacancy Ordering in the Dry and Hydrated Yttrium-Substituted BaSnO<sub>3</sub> Perovskite by NMR Spectroscopy and First Principles Calculations: Implications for Proton Mobility. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(35), 14483-14498. doi:10.1021/ja304712v

DOI
10.1021/ja304712v
Journal article

Identification of Cation Clustering in Mg-Al Layered Double Hydroxides Using Multinuclear Solid State Nuclear Magnetic Resonance Spectroscopy

Sideris, P. J., Blanc, F., Gan, Z., & Grey, C. P. (2012). Identification of Cation Clustering in Mg-Al Layered Double Hydroxides Using Multinuclear Solid State Nuclear Magnetic Resonance Spectroscopy. CHEMISTRY OF MATERIALS, 24(13), 2449-2461. doi:10.1021/cm300386d

DOI
10.1021/cm300386d
Journal article

Thermal phase transformations in LaGaO<sub>3</sub> and LaAlO<sub>3</sub> perovskites: An experimental and computational solid-state NMR study

Blanc, F., Middlemiss, D. S., Buannic, L., Palumbo, J. L., Farnan, I., & Grey, C. P. (2012). Thermal phase transformations in LaGaO<sub>3</sub> and LaAlO<sub>3</sub> perovskites: An experimental and computational solid-state NMR study. SOLID STATE NUCLEAR MAGNETIC RESONANCE, 42, 87-97. doi:10.1016/j.ssnmr.2012.01.003

DOI
10.1016/j.ssnmr.2012.01.003
Journal article

2011

Defects in doped LaGaO3 anionic conductors: linking NMR spectral features, local environments and defect thermodynamics.

Blanc, F., Middlemiss, D. S., Gan, Z., & Grey, C. P. (2011). Defects in Doped LaGaO<sub>3</sub> Anionic Conductors: Linking NMR Spectral Features, Local Environments, and Defect Thermodynamics. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(44), 17662-17672. doi:10.1021/ja2053557

DOI
10.1021/ja2053557
Journal article

2010

Solid-state NMR calculations for metal oxides and gallates: Shielding and quadrupolar parameters for perovskites and related phases

Middlemiss, D. S., Blanc, F., Pickard, C. J., & Grey, C. P. (2010). Solid-state NMR calculations for metal oxides and gallates: Shielding and quadrupolar parameters for perovskites and related phases. JOURNAL OF MAGNETIC RESONANCE, 204(1), 1-10. doi:10.1016/j.jmr.2010.01.004

DOI
10.1016/j.jmr.2010.01.004
Journal article

Experimental and Theoretical NMR Spectroscopic Studies of Doped Lanthanum Gallate Anionic Conductors: Ion Mobility and Trapped Defects

Blanc, F., Middlemiss, D. S., & P. Grey, C. (2010). Experimental and Theoretical NMR Spectroscopic Studies of Doped Lanthanum Gallate Anionic Conductors: Ion Mobility and Trapped Defects. ECS Meeting Abstracts, MA2010-01(11), 661. doi:10.1149/ma2010-01/11/661

DOI
10.1149/ma2010-01/11/661
Journal article

Solid State NMR Studies of Doped BaSnO<sub>3</sub> and BaZrO<sub>3</sub> Protonic Conductors: Defect Trapping and Ionic Mobility

Buannic, L., Blanc, F., & Grey, C. (2010). Solid State NMR Studies of Doped BaSnO<sub>3</sub> and BaZrO<sub>3</sub> Protonic Conductors: Defect Trapping and Ionic Mobility. ECS Meeting Abstracts, MA2010-01(11), 677. doi:10.1149/ma2010-01/11/677

DOI
10.1149/ma2010-01/11/677
Journal article

Probing the local structures and protonic conduction pathways in scandium substituted BaZrO<sub>3</sub> by multinuclear solid-state NMR spectroscopy

Buannic, L., Blanc, F., Hung, I., Gan, Z., & Grey, C. P. (2010). Probing the local structures and protonic conduction pathways in scandium substituted BaZrO<sub>3</sub> by multinuclear solid-state NMR spectroscopy. JOURNAL OF MATERIALS CHEMISTRY, 20(30), 6322-6332. doi:10.1039/c0jm00155d

DOI
10.1039/c0jm00155d
Journal article

2009

Complementarity of Experimental and Theoretical Nuclear Magnetic Resonance Spectroscopic Studies for the Study of Candidate ITSOFC Electrolytes

Middlemiss, D. S., Blanc, F., & Grey, C. P. (2009). Complementarity of Experimental and Theoretical Nuclear Magnetic Resonance Spectroscopic Studies for the Study of Candidate ITSOFC Electrolytes. SOLID OXIDE FUEL CELLS 11 (SOFC-XI), 25(2), 1709-1715. doi:10.1149/1.3205709

DOI
10.1149/1.3205709
Journal article

Metal fragment isomerisation upon grafting a d<SUP>2</SUP> ML<sub>4</sub> perhydrocarbyl Os complex on a silica surface: origin and consequence

Berthoud, R., Rendon, N., Blanc, F., Solans-Monfort, X., Coperet, C., & Eisenstein, O. (2009). Metal fragment isomerisation upon grafting a d<SUP>2</SUP> ML<sub>4</sub> perhydrocarbyl Os complex on a silica surface: origin and consequence. DALTON TRANSACTIONS, (30), 5879-5886. doi:10.1039/b901669d

DOI
10.1039/b901669d
Journal article

Well-defined silica supported metallocarbenes: Formation and reactivity

Rendon, N., Blanc, F., & Coperet, C. (2009). Well-defined silica supported metallocarbenes: Formation and reactivity. COORDINATION CHEMISTRY REVIEWS, 253(15-16), 2015-2020. doi:10.1016/j.ccr.2008.11.018

DOI
10.1016/j.ccr.2008.11.018
Journal article

Solid State NMR Studies of Defect Structures and Mobility in Doped Perovskites

Blanc, F., Middlemass, D., Buannic, L., Holmes, L., Dervisoglu, R., Morgan, D., & Grey, C. P. (2009). Solid State NMR Studies of Defect Structures and Mobility in Doped Perovskites. ECS Meeting Abstracts, MA2009-02(12), 1310. doi:10.1149/ma2009-02/12/1310

DOI
10.1149/ma2009-02/12/1310
Journal article

Well-Defined Silica-Supported Mo-Alkylidene Catalyst Precursors Containing One OR Substituent: Methods of Preparation and Structure-Reactivity Relationship in Alkene Metathesis

Rendon, N., Berthoud, R., Blanc, F., Gajan, D., Maishal, T., Basset, J. -M., . . . Schrock, R. R. (2009). Well-Defined Silica-Supported Mo-Alkylidene Catalyst Precursors Containing One OR Substituent: Methods of Preparation and Structure-Reactivity Relationship in Alkene Metathesis. CHEMISTRY-A EUROPEAN JOURNAL, 15(20), 5083-5089. doi:10.1002/chem.200802465

DOI
10.1002/chem.200802465
Journal article

2008

Structure-Reactivity Relationship in Alkane Metathesis Using Well-Defined Silica-Supported Alkene Metathesis Catalyst Precursors

Blanc, F., Thivolle-Cazat, J., Basset, J. -M., & Coperet, C. (2008). Structure-Reactivity Relationship in Alkane Metathesis Using Well-Defined Silica-Supported Alkene Metathesis Catalyst Precursors. CHEMISTRY-A EUROPEAN JOURNAL, 14(29), 9030-9037. doi:10.1002/chem.200800864

DOI
10.1002/chem.200800864
Journal article

Direct observation of reaction intermediates for a well defined heterogeneous alkene metathesis catalyst

Blanc, F., Berthoud, R., Coperet, C., Lesage, A., Emsley, L., Singh, R., . . . Schrock, R. R. (2008). Direct observation of reaction intermediates for a well defined heterogeneous alkene metathesis catalyst. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 105(34), 12123-12127. doi:10.1073/pnas.0802147105

DOI
10.1073/pnas.0802147105
Journal article

Dramatic enhancement of the alkene metathesis activity of Mo imido alkylidene complexes upon replacement of one tBuO by a surface siloxy ligand

Blanc, F., Rendon, N., Berthoud, R., Basset, J. -M., Coperet, C., Tonzetich, Z. J., & Schrock, R. R. (2008). Dramatic enhancement of the alkene metathesis activity of Mo imido alkylidene complexes upon replacement of one tBuO by a surface siloxy ligand. DALTON TRANSACTIONS, (24), 3156-3158. doi:10.1039/b805686m

DOI
10.1039/b805686m
Journal article

ChemInform Abstract: High Resolution Solid State NMR Spectroscopy in Surface Organometallic Chemistry: Access to Molecular Understanding of Active Sites of Well‐Defined Heterogeneous Catalysts

Blanc, F., Coperet, C., Lesage, A., & Emsley, L. (2008). ChemInform Abstract: High Resolution Solid State NMR Spectroscopy in Surface Organometallic Chemistry: Access to Molecular Understanding of Active Sites of Well‐Defined Heterogeneous Catalysts. ChemInform, 39(23). doi:10.1002/chin.200823279

DOI
10.1002/chin.200823279
Journal article

Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations

Blanc, F., Basset, J. -M., Coperet, C., Sinha, A., Tonzetich, Z. J., Schrock, R. R., . . . Emsley, L. (2008). Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(18), 5886-5900. doi:10.1021/ja077749v

DOI
10.1021/ja077749v
Journal article

High resolution solid state NMR spectroscopy in surface organometallic chemistry:: access to molecular understanding of active sites of well-defined heterogeneous catalysts

Blanc, F., Coperet, C., Lesage, A., & Emsley, L. (2008). High resolution solid state NMR spectroscopy in surface organometallic chemistry:: access to molecular understanding of active sites of well-defined heterogeneous catalysts. CHEMICAL SOCIETY REVIEWS, 37(3), 518-526. doi:10.1039/b612793m

DOI
10.1039/b612793m
Journal article

Grafting mechanism and olefin metathesis activity of well-defined silica-supported Mo imido alkyl alkylidene complexes

Blanc, F., Salameh, A., Thivolle-Cazat, J., Basset, J. -M., Coperet, C., Sinha, A., & Schrock, R. R. (2008). Grafting mechanism and olefin metathesis activity of well-defined silica-supported Mo imido alkyl alkylidene complexes. COMPTES RENDUS CHIMIE, 11(1-2), 137-146. doi:10.1016/j.crci.2007.02.017

DOI
10.1016/j.crci.2007.02.017
Journal article

2007

Dramatic improvements of well-defined silica supported mo-based olefin metathesis catalysts by tuning the N-containing ligands

Blanc, F., Berthoud, R., Salameh, A., Basset, J. -M., Coperet, C., Singh, R., & Schrock, R. R. (2007). Dramatic improvements of well-defined silica supported mo-based olefin metathesis catalysts by tuning the N-containing ligands. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(27), 8434-+. doi:10.1021/ja073095e

DOI
10.1021/ja073095e
Journal article

Synthesis, characterization, and catalytic properties of γ-Al<sub>2</sub>O<sub>3</sub>-supported zirconium hydrides through a combined use of surface organometallic chemistry and periodic calculations

Joubert, J., Delbecq, F., Thieuleux, C., Taoufik, M., Blanc, F., Coperet, C., . . . Sautet, P. (2007). Synthesis, characterization, and catalytic properties of γ-Al<sub>2</sub>O<sub>3</sub>-supported zirconium hydrides through a combined use of surface organometallic chemistry and periodic calculations. ORGANOMETALLICS, 26(14), 3329-3335. doi:10.1021/om070145f

DOI
10.1021/om070145f
Journal article

Highly active, stable, and selective well-defined silica supported mo imido olefin metathesis catalysts (vol 129, pg 1044, 2007)

Blanc, F., Thivolle-Cazat, J., Basset, J. -M., Coperet, C., Hock, A. S., Tonzetich, Z. J., . . . Schrock, R. R. (2007). Highly active, stable, and selective well-defined silica supported mo imido olefin metathesis catalysts (vol 129, pg 1044, 2007). JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(17), 5779. doi:10.1021/ja071561u

DOI
10.1021/ja071561u
Journal article

Highly active, stable, and selective well-defined silica supported Mo imido olefin metathesis catalysts

Blanc, F., Thivolle-Cazat, J., Basset, J. -M., Coperet, C., Hock, A. S., Tonzetich, Z. J., & Schrock, R. R. (2007). Highly active, stable, and selective well-defined silica supported Mo imido olefin metathesis catalysts. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(5), 1044-1045. doi:10.1021/ja068249p

DOI
10.1021/ja068249p
Journal article

2006

Better characterization of surface organometallic catalysts through resolution enhancement in proton solid state NMR spectra

Blanc, F., Coperet, C., Thivolle-Cazat, J., Basset, J. -M., Lesage, A., Emsley, L., . . . Schrock, R. R. (2006). Better characterization of surface organometallic catalysts through resolution enhancement in proton solid state NMR spectra. INORGANIC CHEMISTRY, 45(23), 9587-9592. doi:10.1021/ic061222m

DOI
10.1021/ic061222m
Journal article

Alkane Metathesis Catalyzed by a Well‐Defined Silica‐Supported Mo Imido Alkylidene Complex: [(SiO)Mo(NAr)(CH<i>t</i>Bu)(CH<sub>2</sub><i>t</i>Bu)]

Blanc, F., Copéret, C., Thivolle‐Cazat, J., & Basset, J. (2006). Alkane Metathesis Catalyzed by a Well‐Defined Silica‐Supported Mo Imido Alkylidene Complex: [(SiO)Mo(NAr)(CH<i>t</i>Bu)(CH<sub>2</sub><i>t</i>Bu)]. Angewandte Chemie, 118(37), 6347-6349. doi:10.1002/ange.200602171

DOI
10.1002/ange.200602171
Journal article

Alkane metathesis catalyzed by a well-defined silica-supported mo imido alkylidene complex:: [(SiO)Mo(=NAr)(=CHtBu)(CH<sub>2</sub><i>t</i>Bu)]

Blanc, F., Coperet, C., Thivolle-Cazat, J., & Basset, J. -M. (2006). Alkane metathesis catalyzed by a well-defined silica-supported mo imido alkylidene complex:: [(SiO)Mo(=NAr)(=CHtBu)(CH<sub>2</sub><i>t</i>Bu)]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 45(37), 6201-6203. doi:10.1002/anie.200602171

DOI
10.1002/anie.200602171
Journal article

Molecular understanding of alumina supported single-site catalysts by a combination of experiment and theory

Joubert, J., Delbecq, F., Sautet, P., Le Roux, E., Taoufik, M., Thieuleux, C., . . . Basset, J. -M. (2006). Molecular understanding of alumina supported single-site catalysts by a combination of experiment and theory. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(28), 9157-9169. doi:10.1021/ja0616736

DOI
10.1021/ja0616736
Journal article

Surface versus Molecular Siloxy Ligands in Well‐Defined Olefin Metathesis Catalysts: [{(RO)<sub>3</sub>SiO}Mo(NAr)(CH<i>t</i>Bu)(CH<sub>2</sub><i>t</i>Bu)]

Blanc, F., Copéret, C., Thivolle‐Cazat, J., Basset, J., Lesage, A., Emsley, L., . . . Schrock, R. R. (2006). Surface versus Molecular Siloxy Ligands in Well‐Defined Olefin Metathesis Catalysts: [{(RO)<sub>3</sub>SiO}Mo(NAr)(CH<i>t</i>Bu)(CH<sub>2</sub><i>t</i>Bu)]. Angewandte Chemie, 118(8), 1238-1242. doi:10.1002/ange.200503205

DOI
10.1002/ange.200503205
Journal article

Surface versus molecular siloxy ligands in well-defined olefin metathesis catalysts:: [{(RO)<sub>3</sub>SiO}Mo(=NAr)(=CH<i>t</i>Bu)(CH<sub>2</sub><i>t</i>Bu)]

Blanc, F., Copéret, C., Thivolle-Cazat, J., Basset, J. M., Lesage, A., Emsley, L., . . . Schrock, R. R. (2006). Surface versus molecular siloxy ligands in well-defined olefin metathesis catalysts:: [{(RO)<sub>3</sub>SiO}Mo(=NAr)(=CH<i>t</i>Bu)(CH<sub>2</sub><i>t</i>Bu)]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 45(8), 1216-1220. doi:10.1002/anie.200503205

DOI
10.1002/anie.200503205
Journal article

Molecular understanding of the structure of active sites of alumina supported polymerisation and alkane metathesis catalysts through a combined use of experimental and theoretical data.

Joubert, J., Delbecq, F., Sautet, P., Roux, E. L., Taoufik, M., Thieuleux, C., . . . Basset, J. -M. (2006). Molecular understanding of the structure of active sites of alumina supported polymerisation and alkane metathesis catalysts through a combined use of experimental and theoretical data.. J. Am. Chem. Soc., 128, 9157-9169.

Journal article

2005

Reactivity differences between molecular and surface silanols in the preparation of homogeneous and heterogeneous olefin metathesis catalysts

Blanc, F., Chabanas, M., Copéret, C., Fenet, B., & Herdweck, E. (2005). Reactivity differences between molecular and surface silanols in the preparation of homogeneous and heterogeneous olefin metathesis catalysts. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690(23), 5014-5026. doi:10.1016/j.jorganchem.2005.04.028

DOI
10.1016/j.jorganchem.2005.04.028
Journal article

2004

Adhesion promoting compound and composition incorporating same.

Tulloch, A. A. D., Duncan, R. H., & Blanc, F. (2004). Adhesion promoting compound and composition incorporating same.. PCT Int. Appl., WO 2004053003 A1.

Journal article

1996

Quadrupolar NMR of Ionic Conductors, Batteries, and Other Energy-related Materials

Blanc, F., Spencer, L., & Goward, G. R. (1996). Quadrupolar NMR of Ionic Conductors, Batteries, and Other Energy-related Materials. doi:10.1002/9780470034590.emrstm1215

DOI
10.1002/9780470034590.emrstm1215
Journal article